Literature DB >> 21283839

Transition metal catalysed ammonia-borane dehydrogenation in ionic liquids.

William R H Wright1, Emily R Berkeley, L R Alden, R Tom Baker, Larry G Sneddon.   

Abstract

Significant advantages result from combining the disparate hydrogen release pathways for ammonia-borane (AB) dehydrogenation using ionic liquids (ILs) and transition metal catalysts. With the RuCl(2)(PMe(3))(4) catalyst precursor, AB dehydrogenation selectivity and extent are maximized in an IL with a moderately coordinating ethylsulfate anion.

Entities:  

Year:  2011        PMID： 21283839     DOI： 10.1039/c0cc05408a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Dehydrogenation of ammonia borane through the third equivalent of hydrogen.

Authors:  Xingyue Zhang; Lisa Kam; Travis J Williams
Journal:  Dalton Trans       Date:  2016-05-04       Impact factor: 4.390

2.  A robust, air-stable, reusable ruthenium catalyst for dehydrogenation of ammonia borane.

Authors:  Brian L Conley; Denver Guess; Travis J Williams
Journal:  J Am Chem Soc       Date:  2011-08-18       Impact factor: 15.419

3.  A Three-Stage Mechanistic Model for Ammonia Borane Dehydrogenation by Shvo's Catalyst.

Authors:  Zhiyao Lu; Brian L Conley; Travis J Williams
Journal:  Organometallics       Date:  2012-08-30       Impact factor: 3.876

4.  A comparison of hydrogen release kinetics from 5- and 6-membered 1,2-BN-cycloalkanes.

Authors:  Zachary X Giustra; Gang Chen; Monica Vasiliu; Abhijeet Karkamkar; Tom Autrey; David A Dixon; Shih-Yuan Liu
Journal:  RSC Adv       Date:  2021-10-20       Impact factor: 4.036

5.  Effect of the phosphine steric and electronic profile on the Rh-promoted dehydrocoupling of phosphine-boranes.

Authors:  Thomas N Hooper; Miguel A Huertos; Titel Jurca; Sebastian D Pike; Andrew S Weller; Ian Manners
Journal:  Inorg Chem       Date:  2014-03-11       Impact factor: 5.165

6.  Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane.

Authors:  Hassan A Kalviri; Felix Gärtner; Gang Ye; Ilia Korobkov; R Tom Baker
Journal:  Chem Sci       Date:  2014-10-30       Impact factor: 9.825

7.  Amine-Borane Dehydropolymerization: Challenges and Opportunities.

Authors:  Annie L Colebatch; Andrew S Weller
Journal:  Chemistry       Date:  2018-12-27       Impact factor: 5.236
  7 in total

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