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Literature DB >> 21268638

Toward the second generation synthesis of aplyronine A: stereocontrolled assembly of the C1-C19 segment by using an asymmetric Nozaki-Hiyama-Kishi coupling.

Kenichi Kobayashi¹, Yusuke Fujii, Ichiro Hayakawa, Hideo Kigoshi.

Abstract

An efficient synthesis of the C1-C19 segment of aplyronine A is described. Stereoselective construction of the C14-C15 (E)-trisubstituted double bond and the C13 stereocenter was achieved by using an asymmetric Nozaki-Hiyama-Kishi coupling.

Entities: Chemical Disease

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Year: 2011 PMID： 21268638 DOI： 10.1021/ol1029657

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

2 in total

1. Total synthesis of nahuoic acid A via a putative biogenetic intramolecular Diels-Alder (IMDA) reaction.

Authors: Lucía Guillade; Paula Mora; Pedro Villar; Rosana Alvarez; Angel R de Lera
Journal: Chem Sci Date: 2021-10-27 Impact factor: 9.825

2. Total synthesis of aplyronine C.

Authors: Ian Paterson; Sarah J Fink; Lydia Y W Lee; Stephen J Atkinson; Simon B Blakey
Journal: Org Lett Date: 2013-06-03 Impact factor: 6.005

2 in total