Literature DB >> 21265523

Palladium-catalyzed carboiodination of alkenes: carbon-carbon bond formation with retention of reactive functionality.

Stephen G Newman1, Mark Lautens.   

Abstract

We report a palladium-catalyzed carbon-carbon bond-forming reaction between aryl iodides and alkenes. In contrast to traditional cross-coupling reactions, two new bonds are formed, and all of the atoms in the starting materials are incorporated into the product. The use of a palladium catalyst with bulky phosphine ligands is found to be crucial for reactivity.

Entities:  

Mesh:

Substances:

Year:  2011        PMID: 21265523     DOI: 10.1021/ja110377q

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  10 in total

1.  Development and Elucidation of a Pd-Based Cyclization-Oxygenation Sequence for Natural Product Synthesis.

Authors:  Heng Yi; Pengfei Hu; Scott A Snyder
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-08       Impact factor: 15.336

2.  Formal Asymmetric Hydrobromination of Styrenes via Copper-Catalyzed 1,3-Halogen Migration.

Authors:  R J Van Hoveln; S C Schmid; M Tretbar; C T Buttke; J M Schomaker
Journal:  Chem Sci       Date:  2014-12-01       Impact factor: 9.825

3.  Reversible C-C bond formation using palladium catalysis.

Authors:  Austin D Marchese; Bijan Mirabi; Colton E Johnson; Mark Lautens
Journal:  Nat Chem       Date:  2022-03-17       Impact factor: 24.274

4.  Intramolecular radical cyclization approach to access highly substituted indolines and 2,3-dihydrobenzofurans under visible-light.

Authors:  Clarice A D Caiuby; Akbar Ali; Vinicius T Santana; Francisco W de S Lucas; Marilia S Santos; Arlene G Corrêa; Otaciro R Nascimento; Hao Jiang; Márcio W Paixão
Journal:  RSC Adv       Date:  2018-04-05       Impact factor: 4.036

5.  Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration.

Authors:  R David Grigg; Ryan Van Hoveln; Jennifer M Schomaker
Journal:  J Am Chem Soc       Date:  2012-09-19       Impact factor: 15.419

6.  Palladium-Catalyzed Atom-Transfer Radical Cyclization at Remote Unactivated C(sp3 )-H Sites: Hydrogen-Atom Transfer of Hybrid Vinyl Palladium Radical Intermediates.

Authors:  Maxim Ratushnyy; Marvin Parasram; Yang Wang; Vladimir Gevorgyan
Journal:  Angew Chem Int Ed Engl       Date:  2018-02-06       Impact factor: 15.336

7.  Mechanistic insights on the Pd-catalyzed addition of C-X bonds across alkynes - a combined experimental and computational study.

Authors:  Theresa Sperger; Christine M Le; Mark Lautens; Franziska Schoenebeck
Journal:  Chem Sci       Date:  2017-01-27       Impact factor: 9.825

8.  A palladium-catalyzed carbo-oxygenation: the bielschowskysin case.

Authors:  Martin Himmelbauer; Jean-Baptiste Farcet; Julien Gagnepain; Johann Mulzer
Journal:  Org Lett       Date:  2013-05-31       Impact factor: 6.005

9.  Activating group recycling in action: a rhodium-catalyzed carbothiolation route to substituted isoquinolines.

Authors:  Milan Arambasic; Joel F Hooper; Michael C Willis
Journal:  Org Lett       Date:  2013-10-01       Impact factor: 6.005

10.  Multilayer 3D Chirality and Its Synthetic Assembly.

Authors:  Guanzhao Wu; Yangxue Liu; Zhen Yang; Nandakumar Katakam; Hossein Rouh; Sultan Ahmed; Daniel Unruh; Kazimierz Surowiec; Guigen Li
Journal:  Research (Wash D C)       Date:  2019-06-27
  10 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.