Literature DB >> 21264370

Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2].

Daniel Kratzert1, Dirk Leusser, Daniel Stern, Jens Meyer, Frank Breher, Dietmar Stalke.   

Abstract

In this communication we present the experimental charge density distribution in [Mg{(pz*)(3)C}(2)] (1), (pz* = 3,5-dimethylpyrazolyl), containing two non-coordinating sp(3) carbanionic lone-pairs.

Entities:  

Year:  2011        PMID： 21264370     DOI： 10.1039/c0cc04688d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Electronic nature of zwitterionic alkali metal methanides, silanides and germanides - a combined experimental and computational approach.

Authors:  H Li; A J A Aquino; D B Cordes; W L Hase; C Krempner
Journal:  Chem Sci       Date:  2016-10-07       Impact factor: 9.825

2.  Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [TismPriBenz]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field.

Authors:  Serge Ruccolo; Michael Rauch; Gerard Parkin
Journal:  Chem Sci       Date:  2017-05-02       Impact factor: 9.825
  2 in total

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