Literature DB >> 21253635

Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule.

Revathy Kulasekharan1, Rajib Choudhury, Rajeev Prabhakar, V Ramamurthy.   

Abstract

The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones.

Entities:  

Year:  2011        PMID： 21253635     DOI： 10.1039/c0cc05337f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Water-soluble cavitands promote hydrolyses of long-chain diesters.

Authors:  Qixun Shi; Matthew P Mower; Donna G Blackmond; Julius Rebek
Journal:  Proc Natl Acad Sci U S A       Date:  2016-08-01       Impact factor: 11.205

2.  Preparative scale and convenient synthesis of a water-soluble, deep cavitand.

Authors:  Simone Mosca; Yang Yu; Julius Rebek
Journal:  Nat Protoc       Date:  2016-07-07       Impact factor: 13.491

3.  Induced selectivity in the photochemistry of estrone derivatives in sustainable and micellar environment: preparative and mechanistic studies.

Authors:  Matías I Quindt; Gabriel F Gola; J A Ramirez; Sergio M Bonesi
Journal:  Photochem Photobiol Sci       Date:  2021-10-01       Impact factor: 4.328

4.  Recognition and sequestration of ω-fatty acids by a cavitand receptor.

Authors:  Simone Mosca; Dariush Ajami; Julius Rebek
Journal:  Proc Natl Acad Sci U S A       Date:  2015-08-24       Impact factor: 11.205
  4 in total

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