Literature DB >> 21250717

Palladium-catalyzed selective acyloxylation using sodium perborate as oxidant.

Lukasz T Pilarski1, Pär G Janson, Kálmán J Szabó.   

Abstract

Sodium perborate (SPB), a principal component of washing powders, was employed as an inexpensive and eco-friendly oxidant in the palladium-catalyzed C-H acyloxylation of alkenes in excellent regio- and stereochemistry. The reactions used anhydrides as acyloxy sources. The method applies to both terminal and internal alkenes, and even benzylic C-H oxidation.

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Year:  2011        PMID： 21250717     DOI： 10.1021/jo1024199

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)2/4,5-Diazafluoren-9-one.

Authors:  Jonathan N Jaworski; Caitlin V Kozack; Stephen J Tereniak; Spring Melody M Knapp; Clark R Landis; Jeffrey T Miller; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2019-06-25       Impact factor: 15.419

2.  Benzoquinone Cocatalyst Contributions to DAF/Pd(OAc)2-Catalyzed Aerobic Allylic Acetoxylation in the Absence and Presence of a Co(salophen) Cocatalyst.

Authors:  Caitlin V Kozack; Stephen J Tereniak; Jonathan N Jaworski; Bao Li; David L Bruns; Spring M M Knapp; Clark R Landis; Shannon S Stahl
Journal:  ACS Catal       Date:  2021-05-13       Impact factor: 13.700

3.  Catalyst- and solvent-free ipso-hydroxylation of arylboronic acids to phenols.

Authors:  Xiufang Yang; Xulu Jiang; Weitao Wang; Qi Yang; Yangmin Ma; Kuan Wang
Journal:  RSC Adv       Date:  2019-10-25       Impact factor: 4.036
  3 in total

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