| Literature DB >> 21250677 |
Amit Paul1, Jonathan F Hull, Michael R Norris, Zuofeng Chen, Daniel H Ess, Javier J Concepcion, Thomas J Meyer.
Abstract
Significant rate enhancements are found for benzyl alcohol oxidation by the Ru(V)═O(3+) form of the water oxidation catalyst [Ru(Mebimpy)(bpy)(OH(2))](2+) [Mebimpy = 2,6-bis(1-methylbenzimidazol-2-yl)pyridine; bpy = 2,2'-bipyridine] compared to Ru(IV)═O(2+) and for the Ru(IV)═O(2+) form with added bases due to a new pathway, concerted hydride proton transfer (HPT).Entities:
Year: 2011 PMID： 21250677 DOI： 10.1021/ic1024923
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165