Literature DB >> 21244085

Mild transition-metal-free amination of fluoroarenes catalyzed by fluoride ions.

Daniel Dehe1, Isabel Munstein, Andreas Reis, Werner R Thiel.   

Abstract

Trimethylsilyl-protected heterocycles undergo N-C bond formation with a variety of electron-deficient fluoroarenes catalyzed by fluoride ions. This reaction avoids stoichiometric amounts of base and thus makes N-arylheterocycles accessible in a very mild and transition-metal-free way.
© 2011 American Chemical Society

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Year:  2011        PMID: 21244085     DOI: 10.1021/jo102063s

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  1 in total

1.  Synthesis and stability of strongly acidic benzamide derivatives.

Authors:  Frederik Diness; Niels J Bjerrum; Mikael Begtrup
Journal:  Beilstein J Org Chem       Date:  2018-02-27       Impact factor: 2.883

  1 in total

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