Literature DB >> 21225045

The frustrated Lewis pair induced formation of a pentafulvene [6 + 4] cycloaddition product.

Cornelia M Mömming1, Gerald Kehr, Roland Fröhlich, Gerhard Erker.   

Abstract

The frustrated Lewis pair Mes(2)P-CH(2)CH(2)-B(C(6)F(5))(2) reacts with excess 6,6-dimethylpentafulvene to yield a P/B-Lewis pair addition product to an elusive pentafulvene [6 + 4] cycloaddition dimer. This observation may open a new field of utilization of frustrated Lewis pair chemistry.

Entities:  

Year:  2011        PMID: 21225045     DOI: 10.1039/c0cc04567e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Crystal structures of a series of 6-aryl-1,3-diphenyl-fulvenes.

Authors:  Andrew J Peloquin; Sonya K Adas; Scott T Iacono; Gary J Balaich
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2019-05-21

Review 2.  An overview of the cycloaddition chemistry of fulvenes and emerging applications.

Authors:  Ellen Swan; Kirsten Platts; Anton Blencowe
Journal:  Beilstein J Org Chem       Date:  2019-09-06       Impact factor: 2.883

  2 in total

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