Literature DB >> 21221441

Oxygenic polyoxometalates: a new class of molecular propellers.

Andrea Sartorel1, Melissa Truccolo, Serena Berardi, Martino Gardan, Mauro Carraro, Francesca Maria Toma, Gianfranco Scorrano, Maurizio Prato, Marcella Bonchio.   

Abstract

The oxygen evolving catalyst [Ru(4)(μ-OH)(2)(μ-O)(4)(H(2)O)(4)(γ-SiW(10)O(36))(2)](10-) effects H(2)O(2) dismutation at rates (k = 36.8 ± 1.4 M(-1) s(-1)), one/two order of magnitude higher compared to related tetra-substituted Cu, Fe, Mn, Ni and even Co polyoxometalates, thus providing localised oxygen gas bursts to power nano-propulsion of composite materials.

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Year:  2011        PMID: 21221441     DOI: 10.1039/c0cc04366d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Hybrid Materials Based on the Embedding of Organically Modified Transition Metal Oxoclusters or Polyoxometalates into Polymers for Functional Applications: A Review.

Authors:  Mauro Carraro; Silvia Gross
Journal:  Materials (Basel)       Date:  2014-05-20       Impact factor: 3.623

2.  Catalytic processing in ruthenium-based polyoxometalate coacervate protocells.

Authors:  Pierangelo Gobbo; Liangfei Tian; B V V S Pavan Kumar; Samuel Turvey; Mattia Cattelan; Avinash J Patil; Mauro Carraro; Marcella Bonchio; Stephen Mann
Journal:  Nat Commun       Date:  2020-01-03       Impact factor: 14.919

  2 in total

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