Photo-hydrogen-evolving molecular devices driving visible-light-induced water reduction into molecular hydrogen: structure-activity relationship and reaction mechanism.

This article summarizes the ongoing studies on the photo-hydrogen-evolving molecular devices (PHEMDs) made up of polypyridyl Ru(II) photosensitizers and Pt(II)-based molecular catalysts, carried out in the authors' group in the last two decades. The H(2)-evolving activities of Pt(II)-based molecular catalysts demonstrated by various experimental evidences are first described. Then the structure-activity relationship, some important factors required for the higher catalytic activity, and several important insights into the mechanism of photochemical H(2) evolution catalyzed by the Ru(II)Pt(II)-based PHEMDs will be discussed in detail.