Literature DB >> 21207935

Microwave-assisted cyanation of an aryl bromide directly on a metal-organic framework.

Min Kim1, Sergio J Garibay, Seth M Cohen.   

Abstract

A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr(4+)-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.

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Year:  2011        PMID： 21207935      PMCID： PMC3076622          DOI： 10.1021/ic102436b

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  23 in total

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Authors:  Nathan W Ockwig; Olaf Delgado-Friedrichs; Michael O'Keeffe; Omar M Yaghi
Journal:  Acc Chem Res       Date:  2005-03       Impact factor: 22.384

2.  Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis.

Authors:  Zheng Ni; Richard I Masel
Journal:  J Am Chem Soc       Date:  2006-09-27       Impact factor: 15.419

3.  Isoreticular synthesis and modification of frameworks with the UiO-66 topology.

Authors:  Sergio J Garibay; Seth M Cohen
Journal:  Chem Commun (Camb)       Date:  2010-09-27       Impact factor: 6.222

4.  Postsynthetic covalent modification of a neutral metal-organic framework.

Authors:  Zhenqiang Wang; Seth M Cohen
Journal:  J Am Chem Soc       Date:  2007-09-20       Impact factor: 15.419

5.  The pervasive chemistry of metal-organic frameworks.

Authors:  Jeffrey R Long; Omar M Yaghi
Journal:  Chem Soc Rev       Date:  2009-04-01       Impact factor: 54.564

6.  Postsynthetic modification of metal-organic frameworks.

Authors:  Zhenqiang Wang; Seth M Cohen
Journal:  Chem Soc Rev       Date:  2009-01-20       Impact factor: 54.564

7.  Framework functionalisation triggers metal complex binding.

Authors:  Michael J Ingleson; Jorge Perez Barrio; Jean-Baptiste Guilbaud; Yaroslav Z Khimyak; Matthew J Rosseinsky
Journal:  Chem Commun (Camb)       Date:  2008-05-09       Impact factor: 6.222

8.  Engineering a metal-organic framework catalyst by using postsynthetic modification.

Authors:  Kristine K Tanabe; Seth M Cohen
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

9.  Tuning hydrogen sorption properties of metal-organic frameworks by postsynthetic covalent modification.

Authors:  Zhenqiang Wang; Kristine K Tanabe; Seth M Cohen
Journal:  Chemistry       Date:  2010-01-04       Impact factor: 5.236

10.  Postsynthetic modifications of iron-carboxylate nanoscale metal-organic frameworks for imaging and drug delivery.

Authors:  Kathryn M L Taylor-Pashow; Joseph Della Rocca; Zhigang Xie; Sylvie Tran; Wenbin Lin
Journal:  J Am Chem Soc       Date:  2009-10-14       Impact factor: 15.419
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  3 in total

Review 1.  Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

Authors:  Timothy R Cook; Yao-Rong Zheng; Peter J Stang
Journal:  Chem Rev       Date:  2012-11-02       Impact factor: 60.622

2.  Post-Synthetic Mannich Chemistry on Metal-Organic Frameworks: System-Specific Reactivity and Functionality-Triggered Dissolution.

Authors:  Harina Amer Hamzah; William J Gee; Paul R Raithby; Simon J Teat; Mary F Mahon; Andrew D Burrows
Journal:  Chemistry       Date:  2018-06-26       Impact factor: 5.236

3.  Tailoring of the electronic property of Zn-BTC metal-organic framework via ligand functionalization: an ab initio investigation.

Authors:  Gemechis D Degaga; Ravindra Pandey; Chansi Gupta; Lalit Bharadwaj
Journal:  RSC Adv       Date:  2019-05-07       Impact factor: 4.036
  3 in total

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