Literature DB >> 21204540

Coordination-insertion copolymerization of allyl monomers with ethylene.

Shingo Ito1, Masafumi Kanazawa, Kagehiro Munakata, Jun-ichi Kuroda, Yoshikuni Okumura, Kyoko Nozaki.   

Abstract

Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH(2)CH(CH(2)FG)- units.

Entities:  

Year:  2011        PMID: 21204540     DOI: 10.1021/ja1092216

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  2 in total

1.  Precision design of ethylene- and polar-monomer-based copolymers by organometallic-mediated radical polymerization.

Authors:  Anthony Kermagoret; Antoine Debuigne; Christine Jérôme; Christophe Detrembleur
Journal:  Nat Chem       Date:  2014-01-26       Impact factor: 24.427

2.  Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide-palladium catalysts.

Authors:  Yusuke Mitsushige; Brad P Carrow; Shingo Ito; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-03       Impact factor: 9.825

  2 in total

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