9,9-Dioctyl-2,7-bis-(4,4,5,5-tetra-methyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene.

In the title mol-ecule, C(41)H(64)B(2)O(4), the fluorene unit is essentially planar and the two octyl chains attached to the central C atom inhibit the mol-ecule from engaging in inter-molecular aromatic inter-actions. One of the octyl chains adopts a fully extended conformation, whereas the second incorporates a single gauche conformation. Of the two pinacolatoboronate groups attached at the 2,7-positions, one is partly disordered; one ring C atom and all four methyl groups are disordered equally over two positions.

Related literature

For related literature, see: Cho et al. (2007 ▶); Scherf & List (2002 ▶).

Experimental

Crystal data

C41H64B2O4

M = 642.54

Triclinic,

a = 12.6694 (12) Å

b = 13.3457 (11) Å

c = 14.0819 (11) Å

α = 68.944 (3)°

β = 89.834 (4)°

γ = 64.306 (4)°

V = 1968.9 (3) Å3

Z = 2

Cu Kα radiation

μ = 0.51 mm−1

T = 150 K

0.10 × 0.10 × 0.05 mm

Data collection

Bruker Microstar diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 2007 ▶) T min = 0.840, T max = 0.975

30971 measured reflections

6210 independent reflections

5656 reflections with I > 2σ(I)

R int = 0.054

Refinement

R[F 2 > 2σ(F 2)] = 0.039

wR(F 2) = 0.104

S = 1.04

6210 reflections

476 parameters

66 restraints

H-atom parameters constrained

Δρmax = 0.24 e Å−3

Δρmin = −0.18 e Å−3

Data collection: APEX2 (Bruker, 2006 ▶); cell refinement: SAINT (Bruker, 2006 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶) and Materials Studio (Accelrys, 2005 ▶); software used to prepare material for publication: UdMX (Maris, 2004 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808022496/lh2661sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808022496/lh2661Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C41H64B2O4	Z = 2
Mr = 642.54	F000 = 704
Triclinic, P1	Dx = 1.084 Mg m−3
Hall symbol: -P 1	Cu Kα radiation λ = 1.54178 Å
a = 12.6694 (12) Å	Cell parameters from 17842 reflections
b = 13.3457 (11) Å	θ = 3.4–68.2º
c = 14.0819 (11) Å	µ = 0.51 mm−1
α = 68.944 (3)º	T = 150 K
β = 89.834 (4)º	Needle, colorless
γ = 64.306 (4)º	0.10 × 0.10 × 0.05 mm
V = 1968.9 (3) Å3

Bruker Microstar diffractometer	6210 independent reflections
Radiation source: Rotating anode	5656 reflections with I > 2σ(I)
Monochromator: Helios optics	Rint = 0.054
Detector resolution: 8.3 pixels mm-1	θmax = 68.4º
T = 150 K	θmin = 3.4º
ω scans	h = −14→14
Absorption correction: multi-scan(SADABS; Sheldrick, 2007)	k = −16→16
Tmin = 0.840, Tmax = 0.975	l = −16→16
30971 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.039	H-atom parameters constrained
wR(F2) = 0.104	w = 1/[σ2(Fo2) + (0.0516P)2 + 0.5043P] where P = (Fo2 + 2Fc2)/3
S = 1.05	(Δ/σ)max = 0.001
6210 reflections	Δρmax = 0.24 e Å−3
476 parameters	Δρmin = −0.18 e Å−3
66 restraints	Extinction correction: none
Primary atom site location: structure-invariant direct methods

Experimental. X-ray crystallographic data for the title compound were collected from a single-crystal sample, which was mounted on a loop fiber. Data were collected using a Bruker Microstar diffractometer equiped with a platinum-135 CCD detector, Helios optics and a Kappa goniometer. The crystal-to-detector distance was 4.0 cm, and the data collection was carried out in 512 x 512 pixel mode. The initial unit-cell parameters were determined by a least-squares fit of the angular setting of strong reflections, collected by a 10.0 degree scan in 33 frames over three different parts of the reciprocal space (99 frames total).Due to geometrical constraints of the instrument and the use of copper radiation, we consistently obtain a data completeness lower than 100% depending on the crystal system and the orientation of the mounted crystal, even with appropriate data collection routines. Typical values for data completeness range from 83–92% for triclinic systems, 85–97% for monoclinic systems and 85–98% for all other crystal systems.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsional angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness-of-fit S are based on F2 and conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors (gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.56768 (12)	0.24345 (11)	0.09947 (8)	0.0236 (3)
H1	0.5210	0.3146	0.0396	0.028*
C2	0.53181 (12)	0.15288 (11)	0.13794 (9)	0.0250 (3)
C3	0.60214 (12)	0.04909 (11)	0.22662 (9)	0.0257 (3)
H3	0.5784	−0.0127	0.2533	0.031*
C4	0.70461 (12)	0.03441 (11)	0.27598 (8)	0.0241 (3)
H4	0.7510	−0.0362	0.3363	0.029*
C5	0.93575 (12)	0.05491 (10)	0.35318 (8)	0.0233 (3)
H5	0.9415	−0.0209	0.3977	0.028*
C6	1.02058 (12)	0.08874 (11)	0.36965 (8)	0.0240 (3)
H6	1.0849	0.0352	0.4264	0.029*
C7	1.01437 (12)	0.19971 (11)	0.30503 (8)	0.0232 (3)
C8	0.92079 (12)	0.27689 (10)	0.22061 (8)	0.0227 (3)
H8	0.9161	0.3518	0.1750	0.027*
C9	0.72596 (11)	0.31471 (10)	0.11887 (8)	0.0215 (3)
C10	0.67001 (11)	0.22972 (10)	0.14792 (8)	0.0207 (3)
C11	0.73907 (11)	0.12504 (10)	0.23588 (8)	0.0207 (3)
C12	0.83515 (11)	0.24465 (10)	0.20331 (8)	0.0203 (3)
C13	0.84225 (12)	0.13397 (10)	0.27035 (8)	0.0205 (3)
C14	0.64303 (12)	0.43903 (10)	0.11943 (8)	0.0239 (3)
H14A	0.6833	0.4906	0.0972	0.029*
H14B	0.5704	0.4770	0.0670	0.029*
C15	0.60497 (13)	0.44029 (11)	0.22170 (9)	0.0298 (3)
H15A	0.5603	0.3931	0.2431	0.036*
H15B	0.6767	0.4008	0.2756	0.036*
C16	0.52763 (13)	0.56797 (12)	0.21393 (9)	0.0314 (3)
H16A	0.4526	0.6040	0.1650	0.038*
H16B	0.5692	0.6171	0.1848	0.038*
C17	0.49743 (14)	0.57588 (12)	0.31602 (10)	0.0342 (3)
H17A	0.5721	0.5316	0.3674	0.041*
H17B	0.4478	0.5348	0.3412	0.041*
C18	0.43181 (14)	0.70437 (12)	0.31007 (10)	0.0340 (3)
H18A	0.3536	0.7466	0.2637	0.041*
H18B	0.4780	0.7479	0.2792	0.041*
C19	0.41195 (13)	0.71020 (12)	0.41468 (10)	0.0317 (3)
H19A	0.3615	0.6711	0.4434	0.038*
H19B	0.4898	0.6631	0.4623	0.038*
C20	0.35339 (14)	0.83778 (12)	0.41154 (10)	0.0332 (3)
H20A	0.2751	0.8850	0.3646	0.040*
H20B	0.4035	0.8774	0.3829	0.040*
C21	0.33548 (15)	0.84006 (13)	0.51746 (10)	0.0375 (3)
H21A	0.2807	0.8070	0.5438	0.056*
H21B	0.3019	0.9237	0.5120	0.056*
H21C	0.4123	0.7909	0.5651	0.056*
C22	0.75963 (12)	0.33564 (11)	0.01037 (8)	0.0235 (3)
H22A	0.6853	0.3884	−0.0418	0.028*
H22B	0.8066	0.3805	0.0002	0.028*
C23	0.82984 (12)	0.22350 (11)	−0.01143 (9)	0.0265 (3)
H23A	0.7803	0.1827	−0.0099	0.032*
H23B	0.9013	0.1665	0.0434	0.032*
C24	0.86801 (13)	0.25496 (11)	−0.11621 (9)	0.0286 (3)
H24A	0.7957	0.3114	−0.1703	0.034*
H24B	0.9151	0.2983	−0.1176	0.034*
C25	0.94119 (14)	0.14749 (12)	−0.14342 (10)	0.0321 (3)
H25A	0.8905	0.1109	−0.1521	0.038*
H25B	1.0078	0.0857	−0.0851	0.038*
C26	0.99199 (13)	0.18016 (13)	−0.24185 (10)	0.0327 (3)
H26A	1.0332	0.2269	−0.2368	0.039*
H26B	1.0524	0.1043	−0.2457	0.039*
C27	0.90085 (13)	0.25322 (13)	−0.34141 (10)	0.0316 (3)
H27A	0.8338	0.3226	−0.3337	0.038*
H27B	0.8689	0.2017	−0.3526	0.038*
C28	0.95019 (14)	0.30120 (13)	−0.43650 (10)	0.0356 (3)
H28A	0.9824	0.3525	−0.4255	0.043*
H28B	1.0168	0.2320	−0.4447	0.043*
C29	0.85806 (17)	0.37435 (17)	−0.53490 (11)	0.0515 (4)
H29A	0.8287	0.3229	−0.5483	0.077*
H29B	0.8942	0.4046	−0.5929	0.077*
H29C	0.7916	0.4429	−0.5273	0.077*
B1	1.10946 (14)	0.23555 (12)	0.32833 (10)	0.0240 (3)
O1	1.18801 (8)	0.17591 (8)	0.41961 (6)	0.0272 (2)
O2	1.12260 (8)	0.33030 (8)	0.25940 (6)	0.0298 (2)
C30	1.27671 (12)	0.21973 (11)	0.40392 (9)	0.0276 (3)
C31	1.20716 (13)	0.34677 (11)	0.31416 (9)	0.0285 (3)
C32	1.37874 (14)	0.13171 (13)	0.37341 (11)	0.0365 (3)
H32A	1.4093	0.0500	0.4277	0.055*
H32B	1.4424	0.1555	0.3645	0.055*
H32C	1.3508	0.1325	0.3082	0.055*
C33	1.31708 (15)	0.22104 (14)	0.50430 (10)	0.0392 (4)
H33A	1.2473	0.2646	0.5304	0.059*
H33B	1.3673	0.2617	0.4921	0.059*
H33C	1.3628	0.1376	0.5554	0.059*
C34	1.13448 (15)	0.44551 (13)	0.35113 (12)	0.0420 (4)
H34A	1.0804	0.5190	0.2918	0.063*
H34B	1.1880	0.4629	0.3851	0.063*
H34C	1.0879	0.4185	0.4004	0.063*
C35	1.28192 (15)	0.38512 (14)	0.23982 (11)	0.0406 (4)
H35A	1.3204	0.3251	0.2099	0.061*
H35B	1.3429	0.3909	0.2770	0.061*
H35C	1.2309	0.4642	0.1844	0.061*
B2	0.41847 (15)	0.16668 (14)	0.08183 (11)	0.0293 (3)
O3	0.34863 (9)	0.26417 (9)	−0.00506 (7)	0.0386 (3)
O4	0.38022 (11)	0.08195 (11)	0.11362 (8)	0.0570 (4)
C40	0.27486 (13)	0.12168 (13)	0.04290 (10)	0.0342 (3)
C41	0.2640 (4)	0.2354 (5)	−0.0494 (4)	0.0418 (13)	0.50
C42	0.1873 (4)	0.1423 (5)	0.1132 (4)	0.0574 (13)	0.50
H42A	0.2108	0.0668	0.1741	0.086*	0.50
H42B	0.1081	0.1689	0.0767	0.086*	0.50
H42C	0.1854	0.2049	0.1351	0.086*	0.50
C43	0.2789 (4)	0.0205 (4)	0.0104 (3)	0.0477 (10)	0.50
H43A	0.3469	−0.0050	−0.0244	0.072*	0.50
H43B	0.2050	0.0517	−0.0370	0.072*	0.50
H43C	0.2874	−0.0490	0.0720	0.072*	0.50
C44	0.3127 (4)	0.2093 (4)	−0.1412 (2)	0.0567 (10)	0.50
H44A	0.2627	0.1858	−0.1721	0.085*	0.50
H44B	0.3944	0.1432	−0.1180	0.085*	0.50
H44C	0.3123	0.2822	−0.1927	0.085*	0.50
C45	0.1452 (3)	0.3420 (3)	−0.0827 (2)	0.0726 (13)	0.50
H45A	0.1174	0.3591	−0.0226	0.109*	0.50
H45B	0.0892	0.3255	−0.1145	0.109*	0.50
H45C	0.1502	0.4123	−0.1332	0.109*	0.50
C51	0.2427 (3)	0.2582 (3)	−0.0269 (3)	0.0366 (14)	0.50
C52	0.3241 (3)	0.0379 (3)	−0.0098 (3)	0.0570 (11)	0.50
H52A	0.3883	0.0493	−0.0433	0.085*	0.50
H52B	0.2611	0.0547	−0.0621	0.085*	0.50
H52C	0.3557	−0.0458	0.0410	0.085*	0.50
C53	0.1733 (4)	0.1101 (4)	0.0946 (3)	0.0471 (10)	0.50
H53A	0.2000	0.0254	0.1416	0.071*	0.50
H53B	0.1063	0.1359	0.0418	0.071*	0.50
H53C	0.1481	0.1613	0.1341	0.071*	0.50
C54	0.2145 (4)	0.2935 (4)	−0.1432 (2)	0.0562 (10)	0.50
H54A	0.1456	0.2829	−0.1588	0.084*	0.50
H54B	0.2834	0.2419	−0.1649	0.084*	0.50
H54C	0.1963	0.3785	−0.1804	0.084*	0.50
C55	0.1435 (3)	0.3527 (3)	0.0019 (3)	0.0493 (8)	0.50
H55A	0.1373	0.4328	−0.0379	0.074*	0.50
H55B	0.1616	0.3326	0.0760	0.074*	0.50
H55C	0.0678	0.3535	−0.0139	0.074*	0.50

	U11	U22	U33	U12	U13	U23
C1	0.0205 (9)	0.0247 (6)	0.0235 (5)	−0.0087 (6)	0.0025 (5)	−0.0095 (5)
C2	0.0217 (9)	0.0297 (6)	0.0270 (6)	−0.0125 (6)	0.0066 (5)	−0.0141 (5)
C3	0.0251 (9)	0.0273 (6)	0.0287 (6)	−0.0149 (6)	0.0074 (5)	−0.0119 (5)
C4	0.0233 (9)	0.0231 (6)	0.0234 (5)	−0.0101 (6)	0.0043 (5)	−0.0077 (4)
C5	0.0232 (9)	0.0217 (6)	0.0216 (5)	−0.0088 (6)	0.0031 (5)	−0.0073 (4)
C6	0.0185 (8)	0.0260 (6)	0.0222 (5)	−0.0063 (6)	0.0000 (5)	−0.0088 (5)
C7	0.0196 (9)	0.0268 (6)	0.0245 (5)	−0.0096 (6)	0.0052 (5)	−0.0130 (5)
C8	0.0214 (9)	0.0229 (6)	0.0237 (5)	−0.0102 (6)	0.0044 (5)	−0.0092 (4)
C9	0.0193 (8)	0.0226 (6)	0.0219 (5)	−0.0096 (6)	0.0011 (5)	−0.0082 (4)
C10	0.0188 (8)	0.0222 (6)	0.0216 (5)	−0.0084 (6)	0.0046 (5)	−0.0108 (4)
C11	0.0176 (8)	0.0229 (6)	0.0217 (5)	−0.0076 (6)	0.0053 (5)	−0.0113 (4)
C12	0.0173 (8)	0.0212 (6)	0.0204 (5)	−0.0065 (6)	0.0036 (4)	−0.0092 (4)
C13	0.0185 (8)	0.0223 (6)	0.0212 (5)	−0.0081 (6)	0.0054 (5)	−0.0109 (4)
C14	0.0210 (9)	0.0215 (6)	0.0249 (5)	−0.0078 (6)	−0.0007 (5)	−0.0072 (4)
C15	0.0295 (10)	0.0273 (6)	0.0282 (6)	−0.0092 (7)	0.0042 (5)	−0.0113 (5)
C16	0.0303 (10)	0.0291 (7)	0.0314 (6)	−0.0094 (7)	0.0041 (5)	−0.0137 (5)
C17	0.0331 (10)	0.0311 (7)	0.0328 (7)	−0.0087 (7)	0.0051 (6)	−0.0145 (5)
C18	0.0335 (10)	0.0319 (7)	0.0352 (7)	−0.0118 (7)	0.0078 (6)	−0.0159 (5)
C19	0.0289 (10)	0.0318 (7)	0.0338 (6)	−0.0119 (7)	0.0051 (6)	−0.0152 (5)
C20	0.0315 (10)	0.0324 (7)	0.0365 (7)	−0.0134 (7)	0.0073 (6)	−0.0165 (5)
C21	0.0364 (11)	0.0381 (7)	0.0406 (7)	−0.0149 (8)	0.0090 (6)	−0.0213 (6)
C22	0.0226 (9)	0.0247 (6)	0.0211 (5)	−0.0113 (6)	0.0013 (5)	−0.0064 (4)
C23	0.0267 (9)	0.0276 (6)	0.0264 (6)	−0.0136 (6)	0.0061 (5)	−0.0106 (5)
C24	0.0294 (9)	0.0286 (6)	0.0278 (6)	−0.0133 (7)	0.0069 (5)	−0.0115 (5)
C25	0.0323 (10)	0.0300 (7)	0.0331 (6)	−0.0128 (7)	0.0072 (6)	−0.0138 (5)
C26	0.0263 (10)	0.0363 (7)	0.0386 (7)	−0.0124 (7)	0.0104 (6)	−0.0210 (6)
C27	0.0291 (10)	0.0383 (7)	0.0358 (7)	−0.0178 (7)	0.0118 (6)	−0.0209 (6)
C28	0.0365 (10)	0.0407 (8)	0.0377 (7)	−0.0202 (8)	0.0149 (6)	−0.0213 (6)
C29	0.0543 (13)	0.0691 (11)	0.0356 (8)	−0.0324 (10)	0.0137 (7)	−0.0207 (7)
B1	0.0188 (10)	0.0247 (7)	0.0265 (6)	−0.0073 (7)	0.0037 (5)	−0.0114 (5)
O1	0.0236 (6)	0.0306 (4)	0.0277 (4)	−0.0162 (5)	0.0006 (3)	−0.0074 (3)
O2	0.0279 (6)	0.0305 (5)	0.0287 (4)	−0.0156 (5)	−0.0011 (4)	−0.0066 (3)
C30	0.0235 (9)	0.0320 (7)	0.0304 (6)	−0.0174 (7)	0.0021 (5)	−0.0100 (5)
C31	0.0256 (9)	0.0297 (6)	0.0328 (6)	−0.0157 (7)	0.0030 (5)	−0.0112 (5)
C32	0.0249 (10)	0.0343 (7)	0.0475 (8)	−0.0123 (7)	0.0028 (6)	−0.0149 (6)
C33	0.0393 (11)	0.0523 (9)	0.0341 (7)	−0.0302 (8)	0.0022 (6)	−0.0146 (6)
C34	0.0408 (11)	0.0331 (7)	0.0560 (9)	−0.0175 (8)	0.0090 (7)	−0.0214 (7)
C35	0.0439 (11)	0.0407 (8)	0.0404 (7)	−0.0273 (8)	0.0093 (6)	−0.0099 (6)
B2	0.0267 (11)	0.0344 (8)	0.0309 (7)	−0.0167 (8)	0.0060 (6)	−0.0142 (6)
O3	0.0326 (7)	0.0420 (5)	0.0403 (5)	−0.0225 (5)	−0.0063 (4)	−0.0089 (4)
O4	0.0524 (9)	0.0579 (7)	0.0546 (6)	−0.0432 (7)	−0.0193 (5)	0.0065 (5)
C40	0.0263 (10)	0.0481 (8)	0.0398 (7)	−0.0229 (8)	0.0056 (6)	−0.0228 (6)
C41	0.039 (3)	0.049 (2)	0.042 (3)	−0.027 (2)	−0.007 (2)	−0.014 (2)
C42	0.042 (3)	0.094 (4)	0.066 (2)	−0.041 (3)	0.0252 (19)	−0.052 (2)
C43	0.050 (3)	0.057 (2)	0.056 (2)	−0.034 (2)	0.0127 (18)	−0.0325 (17)
C44	0.072 (3)	0.082 (3)	0.0359 (16)	−0.054 (3)	0.0092 (16)	−0.0217 (17)
C45	0.046 (3)	0.055 (2)	0.102 (3)	−0.020 (2)	−0.024 (3)	−0.020 (2)
C51	0.032 (3)	0.057 (3)	0.027 (2)	−0.029 (2)	−0.0033 (17)	−0.0129 (16)
C52	0.042 (3)	0.074 (3)	0.080 (3)	−0.030 (3)	0.014 (2)	−0.053 (2)
C53	0.038 (3)	0.063 (3)	0.053 (2)	−0.033 (2)	0.0109 (17)	−0.0237 (18)
C54	0.046 (3)	0.090 (3)	0.0381 (18)	−0.037 (3)	0.0048 (16)	−0.0247 (18)
C55	0.034 (2)	0.0430 (17)	0.065 (2)	−0.0124 (17)	0.0016 (16)	−0.0215 (15)

C1—C10	1.3744 (17)	C28—C29	1.512 (2)
C1—C2	1.4020 (16)	C28—H28a	0.99
C1—H1	0.95	C28—H28b	0.99
C2—C3	1.4019 (17)	C29—H29a	0.98
C2—B2	1.547 (2)	C29—H29b	0.98
C3—C4	1.3761 (18)	C29—H29c	0.98
C3—H3	0.95	B1—O1	1.3644 (16)
C4—C11	1.3921 (16)	B1—O2	1.3670 (16)
C4—H4	0.95	O1—C30	1.4591 (14)
C5—C6	1.3821 (17)	O2—C31	1.4564 (14)
C5—C13	1.3845 (17)	C30—C32	1.509 (2)
C5—H5	0.95	C30—C33	1.5132 (17)
C6—C7	1.3996 (16)	C30—C31	1.5555 (17)
C6—H6	0.95	C31—C35	1.5115 (18)
C7—C8	1.3961 (17)	C31—C34	1.5145 (19)
C7—B1	1.5500 (18)	C32—H32a	0.98
C8—C12	1.3796 (16)	C32—H32b	0.98
C8—H8	0.95	C32—H32c	0.98
C9—C12	1.5136 (16)	C33—H33a	0.98
C9—C10	1.5226 (15)	C33—H33b	0.98
C9—C14	1.5344 (17)	C33—H33c	0.98
C9—C22	1.5451 (15)	C34—H34a	0.98
C10—C11	1.3981 (16)	C34—H34b	0.98
C11—C13	1.4625 (17)	C34—H34c	0.98
C12—C13	1.4016 (15)	C35—H35a	0.98
C14—C15	1.5208 (16)	C35—H35b	0.98
C14—H14a	0.99	C35—H35c	0.98
C14—H14b	0.99	B2—O4	1.3505 (17)
C15—C16	1.5148 (18)	B2—O3	1.3554 (18)
C15—H15a	0.99	O3—C51	1.420 (4)
C15—H15b	0.99	O3—C41	1.490 (5)
C16—C17	1.5149 (17)	O4—C40	1.4385 (17)
C16—H16a	0.99	C40—C52	1.476 (3)
C16—H16b	0.99	C40—C42	1.486 (4)
C17—C18	1.5165 (18)	C40—C53	1.515 (4)
C17—H17a	0.99	C40—C41	1.553 (6)
C17—H17b	0.99	C40—C43	1.555 (4)
C18—C19	1.5175 (17)	C40—C51	1.588 (5)
C18—H18a	0.99	C41—C45	1.476 (6)
C18—H18b	0.99	C41—C44	1.518 (6)
C19—C20	1.5173 (18)	C42—H42a	0.98
C19—H19a	0.99	C42—H42b	0.98
C19—H19b	0.99	C42—H42c	0.98
C20—C21	1.5173 (18)	C43—H43a	0.98
C20—H20a	0.99	C43—H43b	0.98
C20—H20b	0.99	C43—H43c	0.98
C21—H21a	0.98	C44—H44a	0.98
C21—H21b	0.98	C44—H44b	0.98
C21—H21c	0.98	C44—H44c	0.98
C22—C23	1.5163 (17)	C45—H45a	0.98
C22—H22a	0.99	C45—H45b	0.98
C22—H22b	0.99	C45—H45c	0.98
C23—C24	1.5213 (16)	C51—C55	1.525 (4)
C23—H23a	0.99	C51—C54	1.527 (4)
C23—H23b	0.99	C52—H52a	0.98
C24—C25	1.5176 (18)	C52—H52b	0.98
C24—H24a	0.99	C52—H52c	0.98
C24—H24b	0.99	C53—H53a	0.98
C25—C26	1.5263 (18)	C53—H53b	0.98
C25—H25a	0.99	C53—H53c	0.98
C25—H25b	0.99	C54—H54a	0.98
C26—C27	1.5167 (19)	C54—H54b	0.98
C26—H26a	0.99	C54—H54c	0.98
C26—H26b	0.99	C55—H55a	0.98
C27—C28	1.5232 (17)	C55—H55b	0.98
C27—H27a	0.99	C55—H55c	0.98
C27—H27b	0.99
C10—C1—C2	120.31 (11)	C26—C27—H27B	108.8
C10—C1—H1	119.8	C28—C27—H27B	108.8
C2—C1—H1	119.8	H27A—C27—H27B	107.7
C3—C2—C1	118.56 (11)	C29—C28—C27	113.15 (13)
C3—C2—B2	121.07 (11)	C29—C28—H28A	108.9
C1—C2—B2	120.36 (11)	C27—C28—H28A	108.9
C4—C3—C2	121.69 (11)	C29—C28—H28B	108.9
C4—C3—H3	119.2	C27—C28—H28B	108.9
C2—C3—H3	119.2	H28A—C28—H28B	107.8
C3—C4—C11	118.76 (11)	C28—C29—H29A	109.5
C3—C4—H4	120.6	C28—C29—H29B	109.5
C11—C4—H4	120.6	H29A—C29—H29B	109.5
C6—C5—C13	118.51 (10)	C28—C29—H29C	109.5
C6—C5—H5	120.7	H29A—C29—H29C	109.5
C13—C5—H5	120.7	H29B—C29—H29C	109.5
C5—C6—C7	121.84 (11)	O1—B1—O2	113.40 (11)
C5—C6—H6	119.1	O1—B1—C7	123.37 (11)
C7—C6—H6	119.1	O2—B1—C7	123.22 (11)
C8—C7—C6	118.70 (11)	B1—O1—C30	106.64 (9)
C8—C7—B1	121.23 (10)	B1—O2—C31	107.00 (9)
C6—C7—B1	120.07 (11)	O1—C30—C32	106.27 (10)
C12—C8—C7	120.16 (10)	O1—C30—C33	108.77 (10)
C12—C8—H8	119.9	C32—C30—C33	110.82 (12)
C7—C8—H8	119.9	O1—C30—C31	102.2 (1)
C12—C9—C10	101.25 (9)	C32—C30—C31	113.08 (11)
C12—C9—C14	112.05 (9)	C33—C30—C31	114.90 (11)
C10—C9—C14	112.33 (10)	O2—C31—C35	108.7 (1)
C12—C9—C22	111.71 (10)	O2—C31—C34	106.72 (11)
C10—C9—C22	111.77 (8)	C35—C31—C34	110.49 (11)
C14—C9—C22	107.75 (9)	O2—C31—C30	102.19 (9)
C1—C10—C11	120.07 (10)	C35—C31—C30	114.80 (12)
C1—C10—C9	129.04 (10)	C34—C31—C30	113.20 (11)
C11—C10—C9	110.88 (10)	C30—C32—H32A	109.5
C4—C11—C10	120.61 (11)	C30—C32—H32B	109.5
C4—C11—C13	130.94 (11)	H32A—C32—H32B	109.5
C10—C11—C13	108.45 (10)	C30—C32—H32C	109.5
C8—C12—C13	119.99 (11)	H32A—C32—H32C	109.5
C8—C12—C9	128.97 (10)	H32B—C32—H32C	109.5
C13—C12—C9	111.03 (10)	C30—C33—H33A	109.5
C5—C13—C12	120.78 (11)	C30—C33—H33B	109.5
C5—C13—C11	130.84 (10)	H33A—C33—H33B	109.5
C12—C13—C11	108.38 (10)	C30—C33—H33C	109.5
C15—C14—C9	116.62 (9)	H33A—C33—H33C	109.5
C15—C14—H14A	108.1	H33B—C33—H33C	109.5
C9—C14—H14A	108.1	C31—C34—H34A	109.5
C15—C14—H14B	108.1	C31—C34—H34B	109.5
C9—C14—H14B	108.1	H34A—C34—H34B	109.5
H14A—C14—H14B	107.3	C31—C34—H34C	109.5
C16—C15—C14	111.84 (10)	H34A—C34—H34C	109.5
C16—C15—H15A	109.2	H34B—C34—H34C	109.5
C14—C15—H15A	109.2	C31—C35—H35A	109.5
C16—C15—H15B	109.2	C31—C35—H35B	109.5
C14—C15—H15B	109.2	H35A—C35—H35B	109.5
H15A—C15—H15B	107.9	C31—C35—H35C	109.5
C15—C16—C17	114.23 (10)	H35A—C35—H35C	109.5
C15—C16—H16A	108.7	H35B—C35—H35C	109.5
C17—C16—H16A	108.7	O4—B2—O3	113.26 (12)
C15—C16—H16B	108.7	O4—B2—C2	123.36 (12)
C17—C16—H16B	108.7	O3—B2—C2	123.36 (11)
H16A—C16—H16B	107.6	B2—O3—C51	109.1 (2)
C16—C17—C18	114.02 (11)	B2—O3—C41	108.4 (2)
C16—C17—H17A	108.7	B2—O4—C40	109.04 (11)
C18—C17—H17A	108.7	O4—C40—C52	99.86 (16)
C16—C17—H17B	108.7	O4—C40—C42	98.5 (2)
C18—C17—H17B	108.7	C52—C40—C42	136.4 (2)
H17A—C17—H17B	107.6	O4—C40—C53	114.34 (19)
C17—C18—C19	113.18 (11)	C52—C40—C53	112.0 (2)
C17—C18—H18A	108.9	O4—C40—C41	105.2 (2)
C19—C18—H18A	108.9	C52—C40—C41	95.6 (3)
C17—C18—H18B	108.9	C42—C40—C41	117.0 (3)
C19—C18—H18B	108.9	C53—C40—C41	125.6 (3)
H18A—C18—H18B	107.8	O4—C40—C43	112.7 (2)
C20—C19—C18	114.10 (11)	C42—C40—C43	108.9 (2)
C20—C19—H19A	108.7	C53—C40—C43	84.3 (2)
C18—C19—H19A	108.7	C41—C40—C43	113.6 (3)
C20—C19—H19B	108.7	O4—C40—C51	102.82 (14)
C18—C19—H19B	108.7	C52—C40—C51	114.2 (2)
H19A—C19—H19B	107.6	C42—C40—C51	99.5 (3)
C19—C20—C21	112.63 (11)	C53—C40—C51	112.7 (3)
C19—C20—H20A	109.1	C43—C40—C51	129.56 (19)
C21—C20—H20A	109.1	C45—C41—O3	108.5 (4)
C19—C20—H20B	109.1	C45—C41—C44	111.1 (4)
C21—C20—H20B	109.1	O3—C41—C44	105.3 (4)
H20A—C20—H20B	107.8	C45—C41—C40	115.5 (4)
C20—C21—H21A	109.5	O3—C41—C40	101.6 (3)
C20—C21—H21B	109.5	C44—C41—C40	113.8 (4)
H21A—C21—H21B	109.5	C40—C42—H42A	109.5
C20—C21—H21C	109.5	C40—C42—H42B	109.5
H21A—C21—H21C	109.5	C40—C42—H42C	109.5
H21B—C21—H21C	109.5	C40—C43—H43A	109.5
C23—C22—C9	116.57 (9)	C40—C43—H43B	109.5
C23—C22—H22A	108.2	C40—C43—H43C	109.5
C9—C22—H22A	108.2	O3—C51—C55	106.6 (2)
C23—C22—H22B	108.2	O3—C51—C54	108.4 (4)
C9—C22—H22B	108.2	C55—C51—C54	108.5 (3)
H22A—C22—H22B	107.3	O3—C51—C40	103.10 (18)
C22—C23—C24	111.51 (9)	C55—C51—C40	114.9 (4)
C22—C23—H23A	109.3	C54—C51—C40	114.7 (2)
C24—C23—H23A	109.3	C40—C52—H52A	109.5
C22—C23—H23B	109.3	C40—C52—H52B	109.5
C24—C23—H23B	109.3	H52A—C52—H52B	109.5
H23A—C23—H23B	108	C40—C52—H52C	109.5
C25—C24—C23	115.06 (10)	H52A—C52—H52C	109.5
C25—C24—H24A	108.5	H52B—C52—H52C	109.5
C23—C24—H24A	108.5	C40—C53—H53A	109.5
C25—C24—H24B	108.5	C40—C53—H53B	109.5
C23—C24—H24B	108.5	H53A—C53—H53B	109.5
H24A—C24—H24B	107.5	C40—C53—H53C	109.5
C24—C25—C26	113.59 (10)	H53A—C53—H53C	109.5
C24—C25—H25A	108.8	H53B—C53—H53C	109.5
C26—C25—H25A	108.8	C51—C54—H54A	109.5
C24—C25—H25B	108.8	C51—C54—H54B	109.5
C26—C25—H25B	108.8	H54A—C54—H54B	109.5
H25A—C25—H25B	107.7	C51—C54—H54C	109.5
C27—C26—C25	114.93 (12)	H54A—C54—H54C	109.5
C27—C26—H26A	108.5	H54B—C54—H54C	109.5
C25—C26—H26A	108.5	C51—C55—H55A	109.5
C27—C26—H26B	108.5	C51—C55—H55B	109.5
C25—C26—H26B	108.5	H55A—C55—H55B	109.5
H26A—C26—H26B	107.5	C51—C55—H55C	109.5
C26—C27—C28	113.84 (12)	H55A—C55—H55C	109.5
C26—C27—H27A	108.8	H55B—C55—H55C	109.5
C28—C27—H27A	108.8
C10—C1—C2—C3	0.29 (18)	C8—C7—B1—O2	−13.26 (19)
C10—C1—C2—B2	−178.38 (11)	C6—C7—B1—O2	167.36 (12)
C1—C2—C3—C4	−0.13 (18)	O2—B1—O1—C30	−11.48 (15)
B2—C2—C3—C4	178.53 (12)	C7—B1—O1—C30	168.66 (12)
C2—C3—C4—C11	−0.43 (18)	O1—B1—O2—C31	−8.34 (15)
C13—C5—C6—C7	−0.20 (18)	C7—B1—O2—C31	171.52 (12)
C5—C6—C7—C8	−1.21 (18)	B1—O1—C30—C32	−94.09 (12)
C5—C6—C7—B1	178.19 (11)	B1—O1—C30—C33	146.55 (12)
C6—C7—C8—C12	1.43 (18)	B1—O1—C30—C31	24.66 (12)
B1—C7—C8—C12	−177.97 (11)	B1—O2—C31—C35	144.65 (12)
C2—C1—C10—C11	0.11 (18)	B1—O2—C31—C34	−96.17 (12)
C2—C1—C10—C9	179.01 (11)	B1—O2—C31—C30	22.90 (13)
C12—C9—C10—C1	−179.77 (12)	O1—C30—C31—O2	−28.65 (12)
C14—C9—C10—C1	60.54 (15)	C32—C30—C31—O2	85.16 (12)
C22—C9—C10—C1	−60.72 (16)	C33—C30—C31—O2	−146.25 (11)
C12—C9—C10—C11	−0.78 (12)	O1—C30—C31—C35	−146.12 (10)
C14—C9—C10—C11	−120.48 (11)	C32—C30—C31—C35	−32.31 (14)
C22—C9—C10—C11	118.26 (11)	C33—C30—C31—C35	96.28 (14)
C3—C4—C11—C10	0.83 (17)	O1—C30—C31—C34	85.74 (12)
C3—C4—C11—C13	−179.31 (12)	C32—C30—C31—C34	−160.45 (11)
C1—C10—C11—C4	−0.68 (17)	C33—C30—C31—C34	−31.86 (16)
C9—C10—C11—C4	−179.77 (10)	C3—C2—B2—O4	0.1 (2)
C1—C10—C11—C13	179.43 (10)	C1—C2—B2—O4	178.73 (13)
C9—C10—C11—C13	0.34 (13)	C3—C2—B2—O3	−178.85 (13)
C7—C8—C12—C13	−0.25 (17)	C1—C2—B2—O3	−0.2 (2)
C7—C8—C12—C9	178.66 (11)	O4—B2—O3—C51	10.4 (2)
C10—C9—C12—C8	−178.02 (12)	C2—B2—O3—C51	−170.52 (17)
C14—C9—C12—C8	−58.12 (16)	O4—B2—O3—C41	−10.8 (3)
C22—C9—C12—C8	62.89 (15)	C2—B2—O3—C41	168.2 (2)
C10—C9—C12—C13	0.97 (12)	O3—B2—O4—C40	0.63 (18)
C14—C9—C12—C13	120.87 (11)	C2—B2—O4—C40	−178.41 (12)
C22—C9—C12—C13	−118.12 (10)	B2—O4—C40—C52	107.9 (2)
C6—C5—C13—C12	1.41 (17)	B2—O4—C40—C42	−111.8 (2)
C6—C5—C13—C11	−177.92 (11)	B2—O4—C40—C53	−132.4 (2)
C8—C12—C13—C5	−1.20 (17)	B2—O4—C40—C41	9.2 (3)
C9—C12—C13—C5	179.7 (1)	B2—O4—C40—C43	133.48 (19)
C8—C12—C13—C11	178.26 (10)	B2—O4—C40—C51	−9.9 (2)
C9—C12—C13—C11	−0.83 (13)	B2—O3—C41—C45	137.4 (4)
C4—C11—C13—C5	−0.2 (2)	B2—O3—C41—C44	−103.6 (3)
C10—C11—C13—C5	179.69 (12)	B2—O3—C41—C40	15.2 (3)
C4—C11—C13—C12	−179.57 (12)	O4—C40—C41—C45	−131.7 (3)
C10—C11—C13—C12	0.30 (13)	C42—C40—C41—C45	−23.6 (5)
C12—C9—C14—C15	−52.93 (14)	C43—C40—C41—C45	104.7 (4)
C10—C9—C14—C15	60.26 (13)	O4—C40—C41—O3	−14.5 (3)
C22—C9—C14—C15	−176.21 (10)	C42—C40—C41—O3	93.6 (3)
C9—C14—C15—C16	177.66 (11)	C43—C40—C41—O3	−138.2 (3)
C14—C15—C16—C17	−174.02 (11)	O4—C40—C41—C44	98.2 (3)
C15—C16—C17—C18	173.52 (12)	C42—C40—C41—C44	−153.8 (3)
C16—C17—C18—C19	−174.97 (12)	C43—C40—C41—C44	−25.5 (5)
C17—C18—C19—C20	176.35 (12)	B2—O3—C51—C55	105.8 (3)
C18—C19—C20—C21	−179.74 (12)	B2—O3—C51—C54	−137.6 (3)
C12—C9—C22—C23	63.47 (13)	B2—O3—C51—C40	−15.6 (2)
C10—C9—C22—C23	−49.18 (15)	O4—C40—C51—O3	15.3 (2)
C14—C9—C22—C23	−173.05 (10)	C52—C40—C51—O3	−91.9 (2)
C9—C22—C23—C24	−174.33 (10)	C53—C40—C51—O3	138.9 (2)
C22—C23—C24—C25	178.76 (11)	O4—C40—C51—C55	−100.3 (2)
C23—C24—C25—C26	−172.19 (11)	C52—C40—C51—C55	152.57 (18)
C24—C25—C26—C27	−70.95 (15)	C53—C40—C51—C55	23.3 (3)
C25—C26—C27—C28	171.05 (11)	O4—C40—C51—C54	132.9 (3)
C26—C27—C28—C29	−179.67 (12)	C52—C40—C51—C54	25.8 (5)
C8—C7—B1—O1	166.59 (12)	C53—C40—C51—C54	−103.5 (4)
C6—C7—B1—O1	−12.80 (19)