9-Ethyl-3,6-diformyl-9H-carbazole.

The structure of the title compound, C(16)H(13)NO(2), was determined as a part of a project on the synthesis of new compounds which can make two-photon absorptions. In the crystal structure, both aldehyde groups are located within the carbazole plane. One of these groups is disordered and was refined using a split model with site-occupation factors for each position of 0.5.

Related literature

For the synthesis of 9-ethyicarbazole, see: Li et al. (2001 ▶).

Experimental

Crystal data

C16H13NO2

M = 251.27

Monoclinic,

a = 13.5475 (3) Å

b = 6.69540 (10) Å

c = 14.1840 (2) Å

β = 100.5100 (10)°

V = 1264.99 (4) Å3

Z = 4

Mo Kα radiation

μ = 0.09 mm−1

T = 293 (2) K

0.46 × 0.32 × 0.28 mm

Data collection

Bruker APEX2 CCD area-detector diffractometer

Absorption correction: multi-scan (APEX2; Bruker, 2005 ▶) T min = 0.962, T max = 0.978

7890 measured reflections

2810 independent reflections

2123 reflections with I > 2σ(I)

R int = 0.016

Refinement

R[F 2 > 2σ(F 2)] = 0.038

wR(F 2) = 0.112

S = 1.05

2810 reflections

183 parameters

H-atom parameters constrained

Δρmax = 0.17 e Å−3

Δρmin = −0.16 e Å−3

Data collection: APEX2 (Bruker, 2005 ▶); cell refinement: APEX2; data reduction: APEX2; program(s) used to solve structure: SIR97 (Altomare et al., 1999 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808017923/nc2104sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808017923/nc2104Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C16H13NO2	F000 = 528
Mr = 251.27	Dx = 1.319 Mg m−3
Monoclinic, P2(1)/n	Mo Kα radiation λ = 0.71073 Å
a = 13.5475 (3) Å	Cell parameters from 3121 reflections
b = 6.69540 (10) Å	θ = 2.9–27.0º
c = 14.1840 (2) Å	µ = 0.09 mm−1
β = 100.5100 (10)º	T = 293 (2) K
V = 1264.99 (4) Å3	Block, colourless
Z = 4	0.46 × 0.32 × 0.28 mm

Bruker APEX2 CCD area-detector diffractometer	2810 independent reflections
Radiation source: fine-focus sealed tube	2123 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.016
T = 293(2) K	θmax = 27.5º
φ and ω scans	θmin = 1.9º
Absorption correction: multi-scan(APEX2; Bruker, 2005)	h = −15→17
Tmin = 0.962, Tmax = 0.978	k = −8→8
7890 measured reflections	l = −18→18

Refinement on F2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F2 > 2σ(F2)] = 0.038	w = 1/[σ2(Fo2) + (0.0515P)2 + 0.1926P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.112	(Δ/σ)max = 0.001
S = 1.05	Δρmax = 0.17 e Å−3
2810 reflections	Δρmin = −0.16 e Å−3
183 parameters	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.020 (3)
Secondary atom site location: difference Fourier map

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
O1	1.02612 (11)	0.7739 (2)	0.65681 (10)	0.1009 (5)
O2	0.8577 (2)	−0.1440 (4)	1.19028 (19)	0.0963 (8)	0.50
O2'	0.9276 (2)	−0.1336 (4)	1.1217 (2)	0.0830 (8)	0.50
N1	0.73234 (8)	0.68042 (17)	0.96028 (7)	0.0500 (3)
C1	0.55071 (11)	0.7452 (3)	0.91838 (13)	0.0713 (4)
H1A	0.5513	0.7464	0.8508	0.107*
H1B	0.4989	0.8327	0.9318	0.107*
H1C	0.5381	0.6119	0.9381	0.107*
C2	0.65035 (10)	0.8149 (2)	0.97202 (11)	0.0573 (4)
H2A	0.6642	0.9470	0.9495	0.069*
H2B	0.6473	0.8252	1.0396	0.069*
C3	0.79421 (9)	0.69945 (19)	0.89373 (9)	0.0459 (3)
C4	0.79749 (10)	0.8498 (2)	0.82587 (10)	0.0557 (3)
H4	0.7532	0.9571	0.8198	0.067*
C5	0.86839 (11)	0.8333 (2)	0.76856 (10)	0.0585 (4)
H5	0.8715	0.9308	0.7225	0.070*
C6	0.93648 (10)	0.6734 (2)	0.77748 (9)	0.0523 (3)
C7	0.93244 (9)	0.5240 (2)	0.84424 (8)	0.0485 (3)
H7	0.9774	0.4178	0.8501	0.058*
C8	0.86064 (9)	0.53478 (19)	0.90209 (8)	0.0440 (3)
C9	0.83555 (9)	0.40894 (19)	0.97708 (8)	0.0452 (3)
C10	0.75611 (9)	0.5055 (2)	1.01106 (8)	0.0473 (3)
C11	0.71439 (11)	0.4259 (2)	1.08601 (10)	0.0582 (4)
H11	0.6627	0.4907	1.1088	0.070*
C12	0.75280 (12)	0.2485 (2)	1.12461 (10)	0.0626 (4)
H12	0.7263	0.1923	1.1745	0.075*
C13	0.83086 (11)	0.1487 (2)	1.09134 (9)	0.0573 (4)
C14	0.87244 (10)	0.2299 (2)	1.01732 (9)	0.0510 (3)
H14	0.9244	0.1646	0.9952	0.061*
C15	1.01501 (12)	0.6612 (3)	0.71893 (11)	0.0666 (4)
H15	1.0603	0.5559	0.7315	0.080*
C16	0.87062 (18)	−0.0411 (3)	1.13397 (14)	0.0825 (6)
H16A	0.9220	−0.0876	1.1043	0.099*	0.50
H16B	0.8377	−0.0871	1.1818	0.099*	0.50

	U11	U22	U33	U12	U13	U23
O1	0.1167 (11)	0.1034 (10)	0.1002 (9)	−0.0055 (8)	0.0663 (9)	0.0204 (8)
O2	0.128 (2)	0.0828 (17)	0.0829 (16)	−0.0009 (16)	0.0324 (16)	0.0299 (14)
O2'	0.0887 (18)	0.0589 (14)	0.1029 (18)	0.0237 (13)	0.0213 (14)	0.0161 (13)
N1	0.0436 (6)	0.0549 (7)	0.0544 (6)	0.0046 (5)	0.0166 (5)	0.0001 (5)
C1	0.0504 (8)	0.0671 (10)	0.0958 (11)	0.0074 (7)	0.0122 (8)	−0.0025 (9)
C2	0.0514 (8)	0.0556 (8)	0.0688 (8)	0.0064 (6)	0.0212 (6)	−0.0073 (7)
C3	0.0385 (6)	0.0522 (7)	0.0475 (6)	−0.0009 (5)	0.0090 (5)	−0.0009 (5)
C4	0.0505 (7)	0.0547 (8)	0.0619 (8)	0.0052 (6)	0.0103 (6)	0.0085 (6)
C5	0.0575 (8)	0.0622 (9)	0.0573 (7)	−0.0046 (7)	0.0142 (6)	0.0120 (7)
C6	0.0461 (7)	0.0622 (8)	0.0505 (7)	−0.0081 (6)	0.0140 (5)	−0.0001 (6)
C7	0.0404 (6)	0.0550 (8)	0.0509 (6)	−0.0004 (5)	0.0103 (5)	−0.0014 (6)
C8	0.0386 (6)	0.0494 (7)	0.0440 (6)	−0.0013 (5)	0.0078 (5)	−0.0001 (5)
C9	0.0405 (6)	0.0512 (7)	0.0441 (6)	−0.0021 (5)	0.0078 (5)	−0.0012 (5)
C10	0.0429 (6)	0.0535 (7)	0.0461 (6)	−0.0024 (5)	0.0102 (5)	−0.0035 (5)
C11	0.0570 (8)	0.0691 (9)	0.0531 (7)	−0.0048 (7)	0.0218 (6)	−0.0034 (7)
C12	0.0695 (9)	0.0721 (10)	0.0492 (7)	−0.0153 (8)	0.0189 (7)	0.0023 (7)
C13	0.0637 (9)	0.0550 (8)	0.0507 (7)	−0.0098 (7)	0.0040 (6)	0.0046 (6)
C14	0.0483 (7)	0.0521 (8)	0.0519 (7)	−0.0001 (6)	0.0074 (5)	0.0003 (6)
C15	0.0654 (9)	0.0742 (10)	0.0657 (9)	−0.0152 (8)	0.0268 (7)	−0.0035 (8)
C16	0.1016 (15)	0.0660 (11)	0.0722 (11)	−0.0161 (11)	−0.0043 (10)	0.0172 (10)

O1—C15	1.1902 (19)	C6—C7	1.3852 (18)
O2—C16	1.093 (3)	C6—C15	1.466 (2)
O2—H16B	0.4697	C7—C8	1.3842 (17)
O2'—C16	1.029 (3)	C7—H7	0.9300
N1—C3	1.3778 (16)	C8—C9	1.4453 (17)
N1—C10	1.3818 (17)	C9—C14	1.3816 (18)
N1—C2	1.4628 (16)	C9—C10	1.4134 (17)
C1—C2	1.498 (2)	C10—C11	1.3974 (18)
C1—H1A	0.9600	C11—C12	1.370 (2)
C1—H1B	0.9600	C11—H11	0.9300
C1—H1C	0.9600	C12—C13	1.403 (2)
C2—H2A	0.9700	C12—H12	0.9300
C2—H2B	0.9700	C13—C14	1.3896 (19)
C3—C4	1.3990 (18)	C13—C16	1.467 (2)
C3—C8	1.4144 (17)	C14—H14	0.9300
C4—C5	1.371 (2)	C15—H15	0.9300
C4—H4	0.9300	C16—H16A	0.9300
C5—C6	1.404 (2)	C16—H16B	0.9300
C5—H5	0.9300
C3—N1—C10	108.81 (10)	C7—C8—C9	133.70 (12)
C3—N1—C2	126.20 (11)	C3—C8—C9	106.54 (11)
C10—N1—C2	124.89 (11)	C14—C9—C10	119.79 (11)
C2—C1—H1A	109.5	C14—C9—C8	133.94 (12)
C2—C1—H1B	109.5	C10—C9—C8	106.27 (11)
H1A—C1—H1B	109.5	N1—C10—C11	129.17 (12)
C2—C1—H1C	109.5	N1—C10—C9	109.24 (11)
H1A—C1—H1C	109.5	C11—C10—C9	121.58 (13)
H1B—C1—H1C	109.5	C12—C11—C10	117.24 (13)
N1—C2—C1	112.52 (12)	C12—C11—H11	121.4
N1—C2—H2A	109.1	C10—C11—H11	121.4
C1—C2—H2A	109.1	C11—C12—C13	122.20 (13)
N1—C2—H2B	109.1	C11—C12—H12	118.9
C1—C2—H2B	109.1	C13—C12—H12	118.9
H2A—C2—H2B	107.8	C14—C13—C12	120.13 (13)
N1—C3—C4	129.60 (12)	C14—C13—C16	118.77 (16)
N1—C3—C8	109.13 (11)	C12—C13—C16	121.09 (15)
C4—C3—C8	121.26 (12)	C9—C14—C13	119.05 (13)
C5—C4—C3	117.61 (13)	C9—C14—H14	120.5
C5—C4—H4	121.2	C13—C14—H14	120.4
C3—C4—H4	121.2	O1—C15—C6	125.94 (17)
C4—C5—C6	121.85 (13)	O1—C15—H15	117.0
C4—C5—H5	119.1	C6—C15—H15	117.0
C6—C5—H5	119.1	O2'—C16—C13	133.0 (3)
C7—C6—C5	120.34 (12)	O2—C16—C13	138.7 (3)
C7—C6—C15	118.06 (13)	O2—C16—H16A	110.6
C5—C6—C15	121.58 (13)	C13—C16—H16A	110.6
C8—C7—C6	119.15 (12)	O2'—C16—H16B	113.5
C8—C7—H7	120.4	C13—C16—H16B	113.5
C6—C7—H7	120.4	H16A—C16—H16B	135.8
C7—C8—C3	119.75 (11)
C3—N1—C2—C1	94.54 (16)	C3—N1—C10—C11	179.12 (13)
C10—N1—C2—C1	−81.23 (17)	C2—N1—C10—C11	−4.5 (2)
C10—N1—C3—C4	179.26 (13)	C3—N1—C10—C9	0.26 (14)
C2—N1—C3—C4	2.9 (2)	C2—N1—C10—C9	176.66 (11)
C10—N1—C3—C8	−0.76 (13)	C14—C9—C10—N1	−179.99 (11)
C2—N1—C3—C8	−177.10 (12)	C8—C9—C10—N1	0.34 (13)
N1—C3—C4—C5	179.09 (13)	C14—C9—C10—C11	1.04 (18)
C8—C3—C4—C5	−0.88 (19)	C8—C9—C10—C11	−178.63 (11)
C3—C4—C5—C6	−0.7 (2)	N1—C10—C11—C12	−179.57 (12)
C4—C5—C6—C7	1.2 (2)	C9—C10—C11—C12	−0.83 (19)
C4—C5—C6—C15	−177.23 (13)	C10—C11—C12—C13	0.1 (2)
C5—C6—C7—C8	−0.16 (19)	C11—C12—C13—C14	0.5 (2)
C15—C6—C7—C8	178.34 (12)	C11—C12—C13—C16	179.97 (14)
C6—C7—C8—C3	−1.36 (17)	C10—C9—C14—C13	−0.47 (18)
C6—C7—C8—C9	179.95 (13)	C8—C9—C14—C13	179.09 (13)
N1—C3—C8—C7	−178.05 (11)	C12—C13—C14—C9	−0.2 (2)
C4—C3—C8—C7	1.92 (18)	C16—C13—C14—C9	−179.78 (12)
N1—C3—C8—C9	0.96 (13)	C7—C6—C15—O1	177.41 (16)
C4—C3—C8—C9	−179.07 (12)	C5—C6—C15—O1	−4.1 (2)
C7—C8—C9—C14	−1.6 (2)	C14—C13—C16—O2'	1.6 (4)
C3—C8—C9—C14	179.62 (13)	C12—C13—C16—O2'	−177.9 (3)
C7—C8—C9—C10	178.03 (13)	C14—C13—C16—O2	179.8 (3)
C3—C8—C9—C10	−0.78 (13)	C12—C13—C16—O2	0.3 (4)