Trichlorido(N,N'-di-tert-butyl-benzamidinato-κN,N')silicon.

In the title mol-ecule, C(15)H(23)Cl(3)N(2)Si, the Si atom is penta-coordinated by two N atoms [Si-N = 1.780 (3) and 1.931 (3) Å] from the benzamidinate ligand and three chloride anions [Si-Cl = 2.0711 (14)-2.1449 (14) Å] in a distorted trigonal-bipyramidal geometry.

Related literature

For the geometric parameters of related silicon complexes, see: So et al. (2006 ▶); Hargittai et al. (1983 ▶); Koe et al. (1998 ▶); Karsch et al. (1998 ▶); Jones et al. (2002 ▶).

Experimental

Crystal data

C15H23Cl3N2Si

M = 365.80

Triclinic,

a = 6.372 (3) Å

b = 10.278 (4) Å

c = 14.229 (6) Å

α = 83.222 (6)°

β = 83.227 (6)°

γ = 84.189 (6)°

V = 915.3 (7) Å3

Z = 2

Mo Kα radiation

μ = 0.56 mm−1

T = 273 (2) K

0.35 × 0.26 × 0.15 mm

Data collection

Bruker SMART CCD area-detector diffractometer

Absorption correction: none

4535 measured reflections

3166 independent reflections

2189 reflections with I > 2σ(I)

R int = 0.028

Refinement

R[F 2 > 2σ(F 2)] = 0.053

wR(F 2) = 0.159

S = 0.99

3166 reflections

196 parameters

H-atom parameters constrained

Δρmax = 0.44 e Å−3

Δρmin = −0.43 e Å−3

Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT-Plus (Bruker, 1998 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: PLATON (Spek, 2003 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808010398/cv2396sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808010398/cv2396Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C15H23Cl3N2Si	Z = 2
Mr = 365.80	F(000) = 384
Triclinic, P1	Dx = 1.327 Mg m−3
a = 6.372 (3) Å	Mo Kα radiation, λ = 0.71073 Å
b = 10.278 (4) Å	Cell parameters from 1365 reflections
c = 14.229 (6) Å	θ = 2.0–25.0°
α = 83.222 (6)°	µ = 0.56 mm−1
β = 83.227 (6)°	T = 273 K
γ = 84.189 (6)°	Block, colourless
V = 915.3 (7) Å3	0.35 × 0.26 × 0.15 mm

Bruker SMART CCD area-detector diffractometer	2189 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.028
graphite	θmax = 25.0°, θmin = 2.0°
φ and ω scans	h = −7→7
4535 measured reflections	k = −7→12
3166 independent reflections	l = −16→16

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.053	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.159	H-atom parameters constrained
S = 0.99	w = 1/[σ2(Fo2) + (0.102P)2] where P = (Fo2 + 2Fc2)/3
3166 reflections	(Δ/σ)max < 0.001
196 parameters	Δρmax = 0.44 e Å−3
0 restraints	Δρmin = −0.43 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Si1	0.38635 (14)	0.09933 (9)	0.76514 (7)	0.0428 (3)
Cl1	0.54115 (17)	−0.02445 (10)	0.66177 (8)	0.0732 (4)
Cl2	0.22531 (16)	−0.05055 (9)	0.84243 (7)	0.0598 (3)
Cl3	0.67974 (13)	0.13745 (9)	0.80465 (7)	0.0564 (3)
N1	0.2423 (4)	0.2341 (2)	0.83913 (18)	0.0396 (6)
N2	0.2521 (4)	0.2228 (3)	0.68974 (18)	0.0443 (7)
C1	0.1884 (5)	0.3019 (3)	0.7605 (2)	0.0390 (7)
C2	0.1051 (5)	0.4426 (3)	0.7473 (2)	0.0406 (8)
C3	0.2489 (6)	0.5342 (3)	0.7133 (3)	0.0536 (9)
H3	0.3908	0.5063	0.6976	0.064*
C4	0.1823 (7)	0.6665 (4)	0.7027 (3)	0.0649 (11)
H4	0.2794	0.7278	0.6807	0.078*
C5	−0.0281 (8)	0.7075 (4)	0.7249 (3)	0.0675 (12)
H5	−0.0728	0.7967	0.7177	0.081*
C6	−0.1716 (6)	0.6183 (4)	0.7572 (3)	0.0596 (10)
H6	−0.3137	0.6470	0.7716	0.072*
C7	−0.1065 (5)	0.4847 (3)	0.7686 (2)	0.0499 (9)
H7	−0.2046	0.4240	0.7906	0.060*
C8	0.1975 (6)	0.2399 (4)	0.5881 (2)	0.0564 (10)
C9	0.3937 (9)	0.2735 (6)	0.5218 (3)	0.0974 (18)
H9A	0.4331	0.3576	0.5330	0.146*
H9B	0.3638	0.2767	0.4570	0.146*
H9C	0.5081	0.2074	0.5335	0.146*
C10	0.0117 (9)	0.3443 (4)	0.5736 (3)	0.0904 (16)
H10A	−0.1015	0.3288	0.6233	0.136*
H10B	−0.0376	0.3396	0.5130	0.136*
H10C	0.0577	0.4300	0.5755	0.136*
C11	0.1190 (7)	0.1105 (4)	0.5664 (3)	0.0682 (12)
H11A	0.2315	0.0412	0.5708	0.102*
H11B	0.0761	0.1215	0.5032	0.102*
H11C	0.0005	0.0882	0.6115	0.102*
C12	0.2239 (5)	0.2735 (3)	0.9381 (2)	0.0452 (8)
C13	0.3108 (7)	0.1583 (4)	1.0033 (3)	0.0732 (12)
H13A	0.2254	0.0860	1.0053	0.110*
H13B	0.3077	0.1839	1.0662	0.110*
H13C	0.4543	0.1319	0.9796	0.110*
C14	0.3482 (7)	0.3920 (4)	0.9418 (3)	0.0686 (12)
H14A	0.4918	0.3739	0.9145	0.103*
H14B	0.3474	0.4087	1.0068	0.103*
H14C	0.2833	0.4677	0.9064	0.103*
C15	−0.0083 (6)	0.3052 (4)	0.9733 (3)	0.0659 (11)
H15A	−0.0616	0.3854	0.9388	0.099*
H15B	−0.0213	0.3155	1.0400	0.099*
H15C	−0.0884	0.2348	0.9633	0.099*

	U11	U22	U33	U12	U13	U23
Si1	0.0501 (6)	0.0290 (5)	0.0498 (6)	−0.0020 (4)	−0.0022 (4)	−0.0107 (4)
Cl1	0.0790 (7)	0.0593 (7)	0.0827 (8)	0.0118 (5)	0.0007 (6)	−0.0375 (6)
Cl2	0.0756 (7)	0.0345 (5)	0.0695 (6)	−0.0162 (4)	−0.0042 (5)	−0.0006 (4)
Cl3	0.0471 (5)	0.0533 (6)	0.0713 (6)	−0.0056 (4)	−0.0073 (4)	−0.0152 (5)
N1	0.0508 (15)	0.0308 (15)	0.0374 (15)	0.0031 (12)	−0.0052 (12)	−0.0105 (12)
N2	0.0605 (17)	0.0336 (15)	0.0396 (15)	−0.0012 (13)	−0.0024 (13)	−0.0129 (13)
C1	0.0439 (17)	0.0298 (17)	0.0451 (19)	−0.0076 (14)	−0.0032 (14)	−0.0094 (15)
C2	0.053 (2)	0.0281 (17)	0.0425 (18)	−0.0024 (15)	−0.0092 (15)	−0.0083 (14)
C3	0.064 (2)	0.035 (2)	0.063 (2)	−0.0093 (17)	−0.0059 (18)	−0.0084 (17)
C4	0.087 (3)	0.035 (2)	0.075 (3)	−0.017 (2)	−0.016 (2)	−0.002 (2)
C5	0.101 (3)	0.031 (2)	0.073 (3)	0.005 (2)	−0.029 (2)	−0.0103 (19)
C6	0.065 (2)	0.046 (2)	0.068 (3)	0.0146 (19)	−0.015 (2)	−0.0132 (19)
C7	0.056 (2)	0.0355 (19)	0.060 (2)	−0.0060 (16)	−0.0092 (17)	−0.0067 (17)
C8	0.088 (3)	0.045 (2)	0.040 (2)	−0.015 (2)	−0.0090 (18)	−0.0070 (17)
C9	0.136 (5)	0.114 (4)	0.049 (3)	−0.065 (4)	0.010 (3)	−0.008 (3)
C10	0.151 (5)	0.064 (3)	0.063 (3)	0.016 (3)	−0.053 (3)	−0.014 (2)
C11	0.087 (3)	0.061 (3)	0.064 (3)	−0.017 (2)	−0.013 (2)	−0.023 (2)
C12	0.055 (2)	0.042 (2)	0.0395 (18)	0.0009 (16)	−0.0067 (15)	−0.0108 (16)
C13	0.105 (3)	0.066 (3)	0.046 (2)	0.022 (2)	−0.020 (2)	−0.009 (2)
C14	0.091 (3)	0.068 (3)	0.055 (2)	−0.029 (2)	−0.004 (2)	−0.025 (2)
C15	0.068 (3)	0.078 (3)	0.049 (2)	−0.001 (2)	0.0006 (19)	−0.009 (2)

Si1—N2	1.780 (3)	C8—C11	1.544 (5)
Si1—N1	1.931 (3)	C9—H9A	0.9600
Si1—Cl2	2.0711 (14)	C9—H9B	0.9600
Si1—Cl3	2.1005 (14)	C9—H9C	0.9600
Si1—Cl1	2.1449 (14)	C10—H10A	0.9600
N1—C1	1.308 (4)	C10—H10B	0.9600
N1—C12	1.499 (4)	C10—H10C	0.9600
N2—C1	1.368 (4)	C11—H11A	0.9600
N2—C8	1.513 (4)	C11—H11B	0.9600
C1—C2	1.488 (4)	C11—H11C	0.9600
C2—C7	1.383 (5)	C12—C13	1.516 (5)
C2—C3	1.386 (5)	C12—C15	1.520 (5)
C3—C4	1.379 (5)	C12—C14	1.527 (5)
C3—H3	0.9300	C13—H13A	0.9600
C4—C5	1.375 (6)	C13—H13B	0.9600
C4—H4	0.9300	C13—H13C	0.9600
C5—C6	1.363 (6)	C14—H14A	0.9600
C5—H5	0.9300	C14—H14B	0.9600
C6—C7	1.390 (5)	C14—H14C	0.9600
C6—H6	0.9300	C15—H15A	0.9600
C7—H7	0.9300	C15—H15B	0.9600
C8—C9	1.518 (6)	C15—H15C	0.9600
C8—C10	1.531 (6)
N2—Si1—N1	70.14 (12)	C9—C8—C11	110.8 (3)
N2—Si1—Cl2	120.61 (11)	C10—C8—C11	105.1 (3)
N1—Si1—Cl2	94.21 (10)	C8—C9—H9A	109.5
N2—Si1—Cl3	118.03 (10)	C8—C9—H9B	109.5
N1—Si1—Cl3	90.61 (9)	H9A—C9—H9B	109.5
Cl2—Si1—Cl3	119.05 (6)	C8—C9—H9C	109.5
N2—Si1—Cl1	100.24 (10)	H9A—C9—H9C	109.5
N1—Si1—Cl1	169.82 (10)	H9B—C9—H9C	109.5
Cl2—Si1—Cl1	93.66 (6)	C8—C10—H10A	109.5
Cl3—Si1—Cl1	91.20 (6)	C8—C10—H10B	109.5
C1—N1—C12	129.8 (3)	H10A—C10—H10B	109.5
C1—N1—Si1	89.35 (19)	C8—C10—H10C	109.5
C12—N1—Si1	139.8 (2)	H10A—C10—H10C	109.5
C1—N2—C8	128.9 (3)	H10B—C10—H10C	109.5
C1—N2—Si1	94.06 (19)	C8—C11—H11A	109.5
C8—N2—Si1	136.8 (2)	C8—C11—H11B	109.5
N1—C1—N2	105.9 (3)	H11A—C11—H11B	109.5
N1—C1—C2	127.5 (3)	C8—C11—H11C	109.5
N2—C1—C2	126.0 (3)	H11A—C11—H11C	109.5
N1—C1—Si1	56.34 (16)	H11B—C11—H11C	109.5
N2—C1—Si1	49.93 (16)	N1—C12—C13	108.6 (3)
C2—C1—Si1	167.6 (2)	N1—C12—C15	109.8 (3)
C7—C2—C3	119.5 (3)	C13—C12—C15	107.9 (3)
C7—C2—C1	122.9 (3)	N1—C12—C14	111.2 (3)
C3—C2—C1	117.6 (3)	C13—C12—C14	109.3 (3)
C4—C3—C2	120.2 (4)	C15—C12—C14	110.0 (3)
C4—C3—H3	119.9	C12—C13—H13A	109.5
C2—C3—H3	119.9	C12—C13—H13B	109.5
C5—C4—C3	119.8 (4)	H13A—C13—H13B	109.5
C5—C4—H4	120.1	C12—C13—H13C	109.5
C3—C4—H4	120.1	H13A—C13—H13C	109.5
C6—C5—C4	120.5 (4)	H13B—C13—H13C	109.5
C6—C5—H5	119.7	C12—C14—H14A	109.5
C4—C5—H5	119.7	C12—C14—H14B	109.5
C5—C6—C7	120.3 (4)	H14A—C14—H14B	109.5
C5—C6—H6	119.9	C12—C14—H14C	109.5
C7—C6—H6	119.9	H14A—C14—H14C	109.5
C2—C7—C6	119.6 (3)	H14B—C14—H14C	109.5
C2—C7—H7	120.2	C12—C15—H15A	109.5
C6—C7—H7	120.2	C12—C15—H15B	109.5
N2—C8—C9	109.0 (3)	H15A—C15—H15B	109.5
N2—C8—C10	111.9 (3)	C12—C15—H15C	109.5
C9—C8—C10	111.4 (4)	H15A—C15—H15C	109.5
N2—C8—C11	108.6 (3)	H15B—C15—H15C	109.5