Tetra-kis(μ-2,4-difluoro-benzoato)bis-[(2,4-difluoro-benzoato)(1,10-phenanthroline)gadolinium(III)].

In the title compound, [Gd(2)(C(7)H(3)F(2)O(2))(6)(C(12)H(8)N(2))(2)], the asymmetric unit comprises one Gd(3+) cation chelated by two 2,4-difluoro-benzoate and one 1,10-phenanthroline ligands. Two cations are linked into a centrosymmetric dimer via three bridging carboxyl-ate groups of 2,4-difluoro-benzoate ligands. Each Gd(3+) ion is nine-coordinated by seven O atoms and two N atoms.

Related literature

For related literature, see: Church & Halvorson (1959 ▶); Chung et al. (1971 ▶); Okabe & Oya (2000 ▶); Serre et al. (2005 ▶); Pocker & Fong (1980 ▶); Scapin et al. (1997 ▶).

Experimental

Crystal data

[Gd2(C7H3F2O2)6(C12H8N2)2]

M = 1617.47

Monoclinic,

a = 15.132 (3) Å

b = 13.663 (3) Å

c = 15.286 (3) Å

β = 109.364 (2)°

V = 2981.6 (9) Å3

Z = 2

Mo Kα radiation

μ = 2.31 mm−1

T = 295 (2) K

0.33 × 0.14 × 0.08 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T min = 0.516, T max = 0.837

15634 measured reflections

5535 independent reflections

4598 reflections with I > 2σ(I)

R int = 0.037

Refinement

R[F 2 > 2σ(F 2)] = 0.032

wR(F 2) = 0.095

S = 1.00

5535 reflections

433 parameters

H-atom parameters constrained

Δρmax = 1.69 e Å−3

Δρmin = −0.64 e Å−3

Data collection: APEX2 (Bruker, 2004 ▶); cell refinement: SAINT-Plus (Bruker, 2001 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808004431/cf2184sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808004431/cf2184Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Gd2(C7H3F2O2)6(C12H8N2)2]	F000 = 1580
Mr = 1617.47	Dx = 1.802 Mg m−3
Monoclinic, P21/n	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 5535 reflections
a = 15.132 (3) Å	θ = 2.1–25.5º
b = 13.663 (3) Å	µ = 2.31 mm−1
c = 15.286 (3) Å	T = 295 (2) K
β = 109.364 (2)º	Block, colourless
V = 2981.6 (9) Å3	0.33 × 0.14 × 0.08 mm
Z = 2

Bruker APEXII CCD area-detector diffractometer	5535 independent reflections
Radiation source: fine-focus sealed tube	4598 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.037
T = 295(2) K	θmax = 25.5º
φ and ω scans	θmin = 2.1º
Absorption correction: multi-scan(SADABS; Bruker, 2001)	h = −14→18
Tmin = 0.516, Tmax = 0.837	k = −16→16
15634 measured reflections	l = −17→18

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.032	H-atom parameters constrained
wR(F2) = 0.095	w = 1/[σ2(Fo2) + (0.0528P)2 + 4.39P] where P = (Fo2 + 2Fc2)/3
S = 1.00	(Δ/σ)max = 0.008
5535 reflections	Δρmax = 1.69 e Å−3
433 parameters	Δρmin = −0.64 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Gd1	0.997885 (14)	0.144628 (14)	0.957975 (13)	0.02862 (9)
C1	1.1346 (3)	0.2166 (3)	0.8849 (3)	0.0373 (10)
C2	1.2110 (3)	0.2446 (3)	0.8476 (3)	0.0428 (11)
C3	1.1982 (4)	0.2280 (4)	0.7539 (4)	0.0530 (13)
H3	1.1411	0.2041	0.7152	0.064*
C4	1.2694 (5)	0.2467 (5)	0.7181 (4)	0.0725 (19)
H4	1.2606	0.2353	0.6558	0.087*
C5	1.3513 (5)	0.2816 (5)	0.7747 (5)	0.076 (2)
C6	1.3667 (5)	0.2995 (6)	0.8637 (6)	0.095 (3)
H6	1.4243	0.3240	0.9009	0.113*
C7	1.2965 (4)	0.2815 (5)	0.9009 (4)	0.0667 (17)
C8	0.9247 (3)	−0.0549 (3)	0.8221 (3)	0.0316 (9)
C9	0.9086 (3)	−0.0732 (3)	0.7207 (3)	0.0328 (9)
C10	0.9380 (3)	−0.0029 (3)	0.6705 (3)	0.0413 (11)
H10	0.9713	0.0512	0.7013	0.050*
C11	0.9189 (4)	−0.0117 (4)	0.5764 (3)	0.0573 (14)
H11	0.9399	0.0351	0.5437	0.069*
C12	0.8686 (5)	−0.0904 (5)	0.5324 (3)	0.0656 (17)
C13	0.8377 (4)	−0.1626 (4)	0.5768 (3)	0.0541 (14)
H13	0.8030	−0.2153	0.5446	0.065*
C14	0.8605 (3)	−0.1536 (3)	0.6721 (3)	0.0407 (11)
C15	0.8390 (3)	0.0592 (3)	1.0120 (3)	0.0344 (9)
C16	0.7585 (3)	0.0448 (3)	1.0482 (3)	0.0422 (11)
C17	0.7753 (5)	0.0095 (4)	1.1374 (4)	0.0631 (16)
H17	0.8347	−0.0130	1.1717	0.076*
C18	0.7040 (6)	0.0075 (5)	1.1760 (5)	0.085 (2)
H18	0.7150	−0.0182	1.2350	0.102*
C19	0.6197 (6)	0.0427 (6)	1.1277 (6)	0.092 (3)
C20	0.5978 (4)	0.0755 (5)	1.0382 (5)	0.0761 (19)
H20	0.5378	0.0968	1.0048	0.091*
C21	0.6685 (4)	0.0755 (4)	0.9998 (4)	0.0532 (13)
C22	0.9877 (4)	0.3346 (4)	1.1111 (3)	0.0454 (12)
H22	1.0244	0.2895	1.1532	0.054*
C23	0.9628 (4)	0.4212 (4)	1.1453 (4)	0.0553 (14)
H23	0.9809	0.4318	1.2089	0.066*
C24	0.9121 (4)	0.4896 (4)	1.0857 (4)	0.0548 (14)
H24	0.8961	0.5479	1.1082	0.066*
C25	0.8838 (3)	0.4726 (3)	0.9899 (4)	0.0440 (11)
C26	0.9099 (3)	0.3819 (3)	0.9608 (3)	0.0371 (10)
C27	0.8324 (4)	0.5425 (4)	0.9223 (4)	0.0569 (15)
H27	0.8156	0.6020	0.9418	0.068*
C28	0.8081 (4)	0.5232 (4)	0.8309 (4)	0.0547 (14)
H28	0.7764	0.5704	0.7882	0.066*
C29	0.8303 (3)	0.4316 (3)	0.7986 (4)	0.0452 (11)
C30	0.8798 (3)	0.3602 (3)	0.8629 (3)	0.0361 (10)
C31	0.8017 (4)	0.4072 (4)	0.7045 (4)	0.0551 (14)
H31	0.7696	0.4526	0.6600	0.066*
C32	0.8213 (4)	0.3157 (5)	0.6782 (4)	0.0598 (15)
H32	0.8018	0.2980	0.6160	0.072*
C33	0.8708 (4)	0.2504 (4)	0.7466 (3)	0.0480 (12)
H33	0.8836	0.1887	0.7281	0.058*
F1	1.3151 (4)	0.3046 (6)	0.9873 (4)	0.153 (3)
F2	1.4208 (3)	0.3002 (4)	0.7394 (4)	0.133 (2)
F3	0.8319 (2)	−0.2247 (2)	0.71639 (19)	0.0520 (7)
F4	0.8467 (4)	−0.0971 (4)	0.4386 (2)	0.1107 (16)
F5	0.6472 (2)	0.1067 (3)	0.9116 (2)	0.0688 (9)
F6	0.5496 (4)	0.0443 (4)	1.1648 (4)	0.141 (2)
N1	0.9615 (2)	0.3134 (3)	1.0209 (2)	0.0331 (8)
N2	0.9010 (3)	0.2706 (3)	0.8367 (2)	0.0355 (8)
O1	1.1385 (2)	0.2404 (3)	0.9662 (2)	0.0486 (8)
O2	1.0671 (2)	0.1674 (2)	0.8334 (2)	0.0418 (7)
O3	0.9197 (2)	0.0335 (2)	0.84238 (19)	0.0360 (7)
O4	0.9422 (2)	−0.1250 (2)	0.8774 (2)	0.0398 (7)
O5	0.8436 (2)	0.1391 (2)	0.9743 (2)	0.0440 (8)
O6	0.8994 (2)	−0.0069 (2)	1.0241 (2)	0.0449 (8)

	U11	U22	U33	U12	U13	U23
Gd1	0.03159 (14)	0.02662 (13)	0.02902 (13)	−0.00158 (8)	0.01190 (9)	−0.00349 (8)
C1	0.043 (3)	0.030 (2)	0.045 (3)	−0.0028 (19)	0.022 (2)	−0.0029 (19)
C2	0.046 (3)	0.036 (3)	0.055 (3)	−0.009 (2)	0.029 (2)	−0.006 (2)
C3	0.060 (3)	0.056 (3)	0.054 (3)	−0.016 (3)	0.034 (3)	−0.004 (2)
C4	0.087 (5)	0.082 (5)	0.071 (4)	−0.032 (4)	0.056 (4)	−0.020 (3)
C5	0.075 (4)	0.088 (5)	0.094 (5)	−0.041 (4)	0.065 (4)	−0.042 (4)
C6	0.060 (4)	0.118 (7)	0.118 (6)	−0.048 (4)	0.047 (4)	−0.043 (5)
C7	0.062 (4)	0.089 (5)	0.058 (3)	−0.031 (3)	0.031 (3)	−0.033 (3)
C8	0.028 (2)	0.033 (2)	0.034 (2)	−0.0040 (17)	0.0107 (17)	−0.0075 (18)
C9	0.034 (2)	0.034 (2)	0.028 (2)	0.0058 (18)	0.0075 (17)	−0.0058 (17)
C10	0.049 (3)	0.039 (3)	0.039 (2)	0.005 (2)	0.020 (2)	−0.002 (2)
C11	0.081 (4)	0.058 (3)	0.042 (3)	0.010 (3)	0.032 (3)	0.006 (3)
C12	0.095 (5)	0.072 (4)	0.031 (3)	0.014 (3)	0.021 (3)	−0.009 (3)
C13	0.067 (4)	0.054 (3)	0.034 (3)	0.004 (3)	0.006 (2)	−0.019 (2)
C14	0.046 (3)	0.035 (3)	0.038 (2)	0.008 (2)	0.011 (2)	−0.0043 (19)
C15	0.031 (2)	0.040 (2)	0.033 (2)	0.0016 (19)	0.0113 (18)	−0.0068 (19)
C16	0.047 (3)	0.031 (2)	0.057 (3)	−0.001 (2)	0.029 (2)	−0.001 (2)
C17	0.089 (5)	0.047 (3)	0.071 (4)	0.018 (3)	0.051 (3)	0.011 (3)
C18	0.117 (6)	0.069 (4)	0.103 (5)	0.022 (4)	0.081 (5)	0.028 (4)
C19	0.104 (6)	0.080 (5)	0.134 (7)	0.002 (4)	0.095 (6)	0.020 (5)
C20	0.049 (3)	0.073 (4)	0.120 (6)	−0.006 (3)	0.047 (4)	0.006 (4)
C21	0.044 (3)	0.044 (3)	0.079 (4)	−0.006 (2)	0.030 (3)	0.005 (3)
C22	0.053 (3)	0.041 (3)	0.045 (3)	−0.003 (2)	0.020 (2)	−0.010 (2)
C23	0.065 (3)	0.055 (3)	0.056 (3)	−0.012 (3)	0.033 (3)	−0.024 (3)
C24	0.057 (3)	0.038 (3)	0.078 (4)	−0.004 (2)	0.034 (3)	−0.023 (3)
C25	0.035 (2)	0.031 (2)	0.070 (3)	−0.0048 (19)	0.023 (2)	−0.010 (2)
C26	0.030 (2)	0.032 (2)	0.053 (3)	−0.0045 (18)	0.018 (2)	−0.006 (2)
C27	0.044 (3)	0.029 (3)	0.095 (5)	0.004 (2)	0.019 (3)	−0.006 (3)
C28	0.040 (3)	0.036 (3)	0.082 (4)	0.003 (2)	0.012 (3)	0.011 (3)
C29	0.035 (2)	0.037 (3)	0.062 (3)	0.001 (2)	0.014 (2)	0.010 (2)
C30	0.030 (2)	0.031 (2)	0.049 (3)	−0.0040 (17)	0.015 (2)	−0.0011 (19)
C31	0.049 (3)	0.054 (3)	0.059 (3)	0.007 (3)	0.015 (3)	0.023 (3)
C32	0.062 (4)	0.073 (4)	0.039 (3)	0.008 (3)	0.010 (3)	0.009 (3)
C33	0.055 (3)	0.051 (3)	0.037 (3)	0.010 (2)	0.013 (2)	0.000 (2)
F1	0.123 (4)	0.247 (7)	0.102 (4)	−0.105 (5)	0.056 (3)	−0.058 (4)
F2	0.114 (4)	0.163 (5)	0.174 (5)	−0.081 (4)	0.116 (4)	−0.077 (4)
F3	0.0626 (18)	0.0388 (15)	0.0505 (16)	−0.0103 (13)	0.0131 (14)	−0.0080 (13)
F4	0.176 (5)	0.118 (4)	0.0343 (18)	−0.005 (3)	0.030 (2)	−0.014 (2)
F5	0.0458 (18)	0.080 (2)	0.076 (2)	0.0011 (17)	0.0149 (17)	0.0107 (19)
F6	0.130 (4)	0.150 (5)	0.206 (6)	0.017 (3)	0.141 (4)	0.043 (4)
N1	0.0321 (19)	0.0286 (18)	0.042 (2)	0.0002 (15)	0.0168 (16)	−0.0034 (16)
N2	0.038 (2)	0.033 (2)	0.0369 (19)	0.0011 (16)	0.0140 (16)	−0.0016 (16)
O1	0.053 (2)	0.054 (2)	0.0486 (19)	−0.0209 (17)	0.0298 (17)	−0.0205 (16)
O2	0.0395 (18)	0.0489 (19)	0.0399 (17)	−0.0076 (15)	0.0170 (15)	−0.0039 (15)
O3	0.0447 (18)	0.0327 (16)	0.0306 (15)	−0.0033 (13)	0.0124 (13)	−0.0070 (12)
O4	0.057 (2)	0.0307 (16)	0.0282 (15)	−0.0037 (14)	0.0100 (14)	−0.0012 (13)
O5	0.0467 (19)	0.0359 (18)	0.057 (2)	−0.0036 (14)	0.0269 (17)	0.0006 (15)
O6	0.0462 (19)	0.049 (2)	0.0405 (18)	0.0153 (16)	0.0155 (15)	0.0000 (15)

Gd1—O3	2.332 (3)	C15—C16	1.509 (6)
Gd1—O4i	2.391 (3)	C16—C21	1.382 (7)
Gd1—O6i	2.397 (3)	C16—C17	1.388 (7)
Gd1—O5	2.429 (3)	C17—C18	1.391 (9)
Gd1—O1	2.465 (3)	C17—H17	0.930
Gd1—O2	2.479 (3)	C18—C19	1.334 (11)
Gd1—N2	2.597 (4)	C18—H18	0.930
Gd1—N1	2.627 (3)	C19—F6	1.359 (7)
Gd1—O6	2.921 (4)	C19—C20	1.372 (10)
C1—O2	1.257 (5)	C20—C21	1.381 (8)
C1—O1	1.267 (5)	C20—H20	0.930
C1—C2	1.499 (6)	C21—F5	1.346 (6)
C2—C7	1.376 (7)	C22—N1	1.334 (6)
C2—C3	1.398 (7)	C22—C23	1.395 (7)
C3—C4	1.385 (7)	C22—H22	0.930
C3—H3	0.930	C23—C24	1.353 (8)
C4—C5	1.342 (9)	C23—H23	0.930
C4—H4	0.930	C24—C25	1.402 (7)
C5—C6	1.325 (10)	C24—H24	0.930
C5—F2	1.355 (6)	C25—C26	1.416 (6)
C6—C7	1.383 (9)	C25—C27	1.431 (7)
C6—H6	0.930	C26—N1	1.362 (6)
C7—F1	1.295 (7)	C26—C30	1.444 (7)
C8—O4	1.246 (5)	C27—C28	1.348 (8)
C8—O3	1.256 (5)	C27—H27	0.930
C8—C9	1.507 (5)	C28—C29	1.426 (7)
C9—C14	1.390 (6)	C28—H28	0.930
C9—C10	1.391 (6)	C29—C31	1.398 (8)
C10—C11	1.376 (6)	C29—C30	1.411 (6)
C10—H10	0.930	C30—N2	1.358 (5)
C11—C12	1.360 (8)	C31—C32	1.375 (8)
C11—H11	0.930	C31—H31	0.930
C12—C13	1.364 (9)	C32—C33	1.390 (7)
C12—F4	1.364 (6)	C32—H32	0.930
C13—C14	1.387 (7)	C33—N2	1.329 (6)
C13—H13	0.930	C33—H33	0.930
C14—F3	1.335 (6)	O4—Gd1i	2.391 (3)
C15—O5	1.247 (5)	O6—Gd1i	2.397 (3)
C15—O6	1.255 (5)
O3—Gd1—O4i	130.13 (10)	F3—C14—C13	117.3 (4)
O3—Gd1—O6i	73.87 (11)	F3—C14—C9	120.3 (4)
O4i—Gd1—O6i	77.68 (10)	C13—C14—C9	122.4 (5)
O3—Gd1—O5	78.14 (11)	O5—C15—O6	123.2 (4)
O4i—Gd1—O5	85.99 (12)	O5—C15—C16	117.4 (4)
O6i—Gd1—O5	124.91 (11)	O6—C15—C16	119.3 (4)
O3—Gd1—O1	126.62 (10)	C21—C16—C17	117.4 (5)
O4i—Gd1—O1	89.20 (11)	C21—C16—C15	122.3 (4)
O6i—Gd1—O1	83.97 (12)	C17—C16—C15	119.9 (5)
O5—Gd1—O1	148.60 (11)	C16—C17—C18	120.6 (6)
O3—Gd1—O2	74.75 (10)	C16—C17—H17	119.7
O4i—Gd1—O2	135.54 (11)	C18—C17—H17	119.7
O6i—Gd1—O2	76.31 (11)	C19—C18—C17	119.5 (6)
O5—Gd1—O2	138.42 (11)	C19—C18—H18	120.3
O1—Gd1—O2	52.79 (10)	C17—C18—H18	120.3
O3—Gd1—N2	82.32 (11)	C18—C19—F6	120.7 (7)
O4i—Gd1—N2	138.85 (11)	C18—C19—C20	122.7 (6)
O6i—Gd1—N2	142.42 (11)	F6—C19—C20	116.5 (8)
O5—Gd1—N2	76.13 (11)	C19—C20—C21	117.4 (6)
O1—Gd1—N2	87.58 (12)	C19—C20—H20	121.3
O2—Gd1—N2	69.53 (11)	C21—C20—H20	121.3
O3—Gd1—N1	137.20 (11)	F5—C21—C20	117.7 (5)
O4i—Gd1—N1	76.43 (11)	F5—C21—C16	119.9 (5)
O6i—Gd1—N1	148.65 (11)	C20—C21—C16	122.4 (6)
O5—Gd1—N1	70.40 (11)	N1—C22—C23	123.1 (5)
O1—Gd1—N1	78.31 (11)	N1—C22—H22	118.4
O2—Gd1—N1	111.36 (11)	C23—C22—H22	118.4
N2—Gd1—N1	62.75 (11)	C24—C23—C22	119.8 (5)
O3—Gd1—O6	67.18 (9)	C24—C23—H23	120.1
O4i—Gd1—O6	67.33 (10)	C22—C23—H23	120.1
O6i—Gd1—O6	77.87 (11)	C23—C24—C25	119.9 (5)
O5—Gd1—O6	47.51 (10)	C23—C24—H24	120.1
O1—Gd1—O6	152.79 (11)	C25—C24—H24	120.1
O2—Gd1—O6	138.53 (10)	C24—C25—C26	116.9 (5)
N2—Gd1—O6	119.04 (10)	C24—C25—C27	123.2 (5)
N1—Gd1—O6	107.62 (10)	C26—C25—C27	119.8 (5)
O2—C1—O1	121.1 (4)	N1—C26—C25	123.1 (4)
O2—C1—C2	117.8 (4)	N1—C26—C30	118.1 (4)
O1—C1—C2	121.1 (4)	C25—C26—C30	118.8 (4)
C7—C2—C3	116.7 (5)	C28—C27—C25	121.0 (5)
C7—C2—C1	124.1 (4)	C28—C27—H27	119.5
C3—C2—C1	119.1 (4)	C25—C27—H27	119.5
C4—C3—C2	120.9 (5)	C27—C28—C29	121.0 (5)
C4—C3—H3	119.6	C27—C28—H28	119.5
C2—C3—H3	119.6	C29—C28—H28	119.5
C5—C4—C3	119.0 (5)	C31—C29—C30	117.6 (5)
C5—C4—H4	120.5	C31—C29—C28	122.5 (5)
C3—C4—H4	120.5	C30—C29—C28	119.9 (5)
C6—C5—C4	122.6 (6)	N2—C30—C29	122.7 (4)
C6—C5—F2	118.5 (6)	N2—C30—C26	117.8 (4)
C4—C5—F2	118.9 (6)	C29—C30—C26	119.4 (4)
C5—C6—C7	119.4 (6)	C32—C31—C29	119.7 (5)
C5—C6—H6	120.3	C32—C31—H31	120.2
C7—C6—H6	120.3	C29—C31—H31	120.2
F1—C7—C2	122.5 (5)	C31—C32—C33	118.6 (5)
F1—C7—C6	116.0 (6)	C31—C32—H32	120.7
C2—C7—C6	121.4 (5)	C33—C32—H32	120.7
O4—C8—O3	126.0 (4)	N2—C33—C32	124.1 (5)
O4—C8—C9	119.7 (4)	N2—C33—H33	117.9
O3—C8—C9	114.2 (4)	C32—C33—H33	117.9
C14—C9—C10	117.2 (4)	C22—N1—C26	117.1 (4)
C14—C9—C8	123.9 (4)	C22—N1—Gd1	122.8 (3)
C10—C9—C8	118.7 (4)	C26—N1—Gd1	119.9 (3)
C11—C10—C9	121.5 (5)	C33—N2—C30	117.3 (4)
C11—C10—H10	119.3	C33—N2—Gd1	121.4 (3)
C9—C10—H10	119.3	C30—N2—Gd1	121.3 (3)
C12—C11—C10	118.3 (5)	C1—O1—Gd1	93.1 (3)
C12—C11—H11	120.8	C1—O2—Gd1	92.7 (3)
C10—C11—H11	120.8	C8—O3—Gd1	139.2 (3)
C11—C12—C13	123.7 (5)	C8—O4—Gd1i	136.2 (3)
C11—C12—F4	118.3 (6)	C15—O5—Gd1	106.2 (3)
C13—C12—F4	118.1 (6)	C15—O6—Gd1i	174.2 (3)
C12—C13—C14	116.8 (5)	C15—O6—Gd1	82.5 (3)
C12—C13—H13	121.6	Gd1i—O6—Gd1	102.13 (11)
C14—C13—H13	121.6