Literature DB >> 21201615

(4-Oxido-2-oxo-1,2-dihydro-pyrimidine-5-carboxyl-ato-κO,O)(4-oxido-2-oxo-1,2-dihydro-pyrimidin-3-ium-5-carboxyl-ato-κO,O)bis-(1,10-phenanthroline-κN,N')gadolinium(III) dihydrate.

Wei Xiong1, Huihui Xing, Yan Su, Zilu Chen.   

Abstract

The title compound, [Gd(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(C(12)H(8)N(2))(2)]·2H(2)O, was obtained from a solvothermal reaction of 2,4-dihydroxy-pyrimidine-5-carboxylic acid (H(3)iso), GdCl(3)·6H(2)O and 1,10-phenanthroline (phen). The Gd(III) ion is located on a twofold rotation axis and is coordinated by four N atoms from two chelating phen ligands and four O atoms (5-carboxyl-ate and 4-oxido O atoms) from H(2)iso(-) and Hiso(2-) ligands. The mol-ecules are linked into a three-dimensional network by N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds. The H atom involved in an N-H⋯N hydrogen bond is disordered around a twofold rotation axis with half occupancy.

Entities:  

Year:  2008        PMID： 21201615      PMCID： PMC2960513          DOI： 10.1107/S1600536808025713

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For isostructural lanthanide complexes with 2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidine-5-carboxylic acid, see: Sun & Jin (2004a ▶,b ▶); Xing et al. (2008a ▶). For related literature, see: Hueso-Ureña et al. (1993 ▶, 1996 ▶); Baran et al. (1996 ▶); Luo et al. (2002 ▶); Maistralis et al. (1991 ▶, 1992 ▶); Xing et al. (2008b ▶).

Experimental

Crystal data

[Gd(C5H2N2O4)(C5H3N2O4)(C12H8N2)2]·2H2O M = 862.87 Monoclinic, a = 17.158 (8) Å b = 14.504 (7) Å c = 13.197 (7) Å β = 99.955 (5)° V = 3235 (3) Å3 Z = 4 Mo Kα radiation μ = 2.13 mm−1 T = 273 (2) K 0.20 × 0.10 × 0.10 mm

Data collection

Bruker APEXII CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Bruker, 1998 ▶) T min = 0.676, T max = 0.816 9884 measured reflections 3686 independent reflections 3212 reflections with I > 2σ(I) R int = 0.039

Refinement

R[F 2 > 2σ(F 2)] = 0.031 wR(F 2) = 0.064 S = 1.05 3686 reflections 240 parameters H-atom parameters constrained Δρmax = 0.74 e Å−3 Δρmin = −0.65 e Å−3 Data collection: APEX2 (Bruker, 2004 ▶); cell refinement: APEX2; data reduction: SAINT (Bruker, 2004 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL. Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808025713/ci2644sup1.cif Structure factors: contains datablocks I. DOI: 10.1107/S1600536808025713/ci2644Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report
[Gd(C5H2N2O4)(C5H3N2O4)(C12H8N2)2]·2H2OF000 = 1716
Mr = 862.87Dx = 1.772 Mg m−3
Monoclinic, C2/cMo Kα radiation λ = 0.71073 Å
Hall symbol: -C 2ycCell parameters from 3284 reflections
a = 17.158 (8) Åθ = 2.3–25.5º
b = 14.504 (7) ŵ = 2.13 mm−1
c = 13.197 (7) ÅT = 273 (2) K
β = 99.955 (5)ºBlock, colourless
V = 3235 (3) Å30.20 × 0.10 × 0.10 mm
Z = 4
Bruker APEXII CCD area-detector diffractometer3686 independent reflections
Radiation source: fine-focus sealed tube3212 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.039
T = 273(2) Kθmax = 27.5º
φ and ω scansθmin = 2.3º
Absorption correction: multi-scan(SADABS; Bruker, 1998)h = −21→22
Tmin = 0.676, Tmax = 0.816k = −18→13
9884 measured reflectionsl = −17→16
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.031H-atom parameters constrained
wR(F2) = 0.064  w = 1/[σ2(Fo2) + (0.0258P)2] where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max = 0.001
3686 reflectionsΔρmax = 0.74 e Å−3
240 parametersΔρmin = −0.65 e Å−3
Primary atom site location: structure-invariant direct methodsExtinction correction: none
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/UeqOcc. (<1)
Gd10.50000.111515 (14)0.25000.02254 (7)
O10.42801 (12)−0.00176 (14)0.31169 (16)0.0329 (5)
O20.34603 (14)−0.11272 (15)0.33997 (16)0.0352 (5)
O30.40327 (12)0.06523 (14)0.11160 (16)0.0320 (5)
O40.26936 (15)−0.11830 (15)−0.13464 (17)0.0424 (6)
N10.33231 (15)−0.02639 (17)−0.00642 (19)0.0296 (6)
H10.33710.0157−0.05080.035*
N20.28238 (16)−0.16877 (18)0.0304 (2)0.0361 (7)
H20.2589−0.22010.01250.043*0.50
N30.40482 (14)0.25042 (17)0.2136 (2)0.0300 (6)
N40.46494 (14)0.19709 (17)0.40957 (19)0.0282 (6)
C10.34878 (17)−0.0740 (2)0.1674 (2)0.0248 (7)
C20.36429 (17)−0.0080 (2)0.0939 (2)0.0251 (7)
C30.29303 (19)−0.1061 (2)−0.0434 (2)0.0304 (7)
C40.3080 (2)−0.1512 (2)0.1292 (2)0.0348 (8)
H40.2973−0.19490.17650.042*
C50.37526 (17)−0.0627 (2)0.2800 (2)0.0248 (6)
C60.37014 (18)0.2746 (2)0.1201 (3)0.0372 (8)
H60.36890.23190.06720.045*
C70.3352 (2)0.3608 (3)0.0960 (3)0.0475 (10)
H70.31130.37470.02900.057*
C80.3372 (2)0.4239 (3)0.1725 (3)0.0499 (10)
H80.31570.48220.15770.060*
C90.3710 (2)0.4014 (2)0.2728 (3)0.0428 (9)
C100.3742 (2)0.4633 (3)0.3580 (4)0.0592 (12)
H100.35470.52290.34610.071*
C110.4042 (3)0.4380 (3)0.4535 (4)0.0618 (12)
H110.40560.48030.50680.074*
C120.4346 (2)0.3467 (3)0.4763 (3)0.0442 (9)
C130.4638 (2)0.3150 (3)0.5755 (3)0.0577 (11)
H130.46480.35430.63140.069*
C140.4906 (2)0.2274 (3)0.5910 (3)0.0510 (10)
H140.50880.20560.65710.061*
C150.49028 (19)0.1703 (3)0.5054 (2)0.0359 (8)
H150.50890.11030.51660.043*
C160.43530 (18)0.2836 (2)0.3944 (2)0.0298 (7)
C170.40366 (18)0.3123 (2)0.2911 (3)0.0317 (7)
O50.3084 (2)0.6863 (2)0.3396 (2)0.0901 (11)
H5A0.27770.67080.28470.135*
H5B0.31660.74390.34410.135*
U11U22U33U12U13U23
Gd10.02861 (12)0.01718 (12)0.01966 (12)0.000−0.00192 (8)0.000
O10.0440 (13)0.0318 (13)0.0208 (11)−0.0131 (11)−0.0007 (10)0.0008 (9)
O20.0496 (14)0.0348 (13)0.0209 (11)−0.0118 (11)0.0055 (10)0.0019 (10)
O30.0427 (13)0.0250 (12)0.0243 (12)−0.0113 (10)−0.0055 (10)0.0032 (9)
O40.0627 (16)0.0363 (14)0.0217 (12)−0.0031 (12)−0.0108 (11)−0.0055 (10)
N10.0409 (15)0.0272 (15)0.0179 (13)−0.0076 (12)−0.0023 (11)0.0023 (11)
N20.0533 (18)0.0244 (15)0.0264 (15)−0.0114 (13)−0.0043 (13)−0.0024 (12)
N30.0299 (14)0.0263 (15)0.0319 (15)0.0024 (11)0.0000 (12)0.0012 (11)
N40.0324 (14)0.0271 (14)0.0244 (14)0.0016 (11)0.0028 (11)0.0010 (11)
C10.0306 (16)0.0229 (16)0.0197 (15)−0.0035 (13)0.0005 (13)0.0026 (12)
C20.0286 (16)0.0229 (16)0.0215 (16)0.0005 (13)−0.0022 (13)−0.0024 (12)
C30.0350 (17)0.0259 (17)0.0268 (17)0.0014 (14)−0.0045 (14)−0.0039 (14)
C40.049 (2)0.0291 (18)0.0247 (17)−0.0116 (16)0.0025 (15)0.0013 (14)
C50.0331 (17)0.0219 (16)0.0191 (15)−0.0014 (13)0.0031 (13)−0.0010 (12)
C60.0365 (18)0.039 (2)0.0339 (19)0.0071 (16)−0.0002 (15)0.0067 (15)
C70.043 (2)0.051 (2)0.047 (2)0.0128 (18)0.0026 (18)0.0207 (19)
C80.049 (2)0.033 (2)0.068 (3)0.0107 (18)0.010 (2)0.019 (2)
C90.040 (2)0.028 (2)0.062 (3)0.0083 (15)0.0133 (18)0.0040 (17)
C100.069 (3)0.030 (2)0.079 (3)0.016 (2)0.015 (2)−0.006 (2)
C110.077 (3)0.037 (2)0.071 (3)0.014 (2)0.013 (3)−0.025 (2)
C120.050 (2)0.039 (2)0.045 (2)0.0016 (18)0.0112 (18)−0.0138 (18)
C130.063 (3)0.068 (3)0.043 (2)0.007 (2)0.010 (2)−0.023 (2)
C140.054 (2)0.069 (3)0.029 (2)0.012 (2)0.0063 (18)−0.0081 (19)
C150.0372 (18)0.043 (2)0.0270 (18)0.0053 (16)0.0051 (15)0.0013 (15)
C160.0294 (17)0.0257 (17)0.0348 (19)0.0005 (13)0.0067 (14)−0.0027 (14)
C170.0271 (16)0.0278 (18)0.041 (2)0.0021 (13)0.0089 (15)0.0027 (15)
O50.133 (3)0.051 (2)0.070 (2)0.000 (2)−0.027 (2)0.0100 (16)
Gd1—O12.288 (2)C1—C51.485 (4)
Gd1—O1i2.288 (2)C4—H40.93
Gd1—O3i2.344 (2)C6—C71.399 (5)
Gd1—O32.344 (2)C6—H60.93
Gd1—N3i2.586 (3)C7—C81.358 (6)
Gd1—N32.586 (3)C7—H70.93
Gd1—N42.603 (3)C8—C91.389 (5)
Gd1—N4i2.603 (3)C8—H80.93
O1—C51.282 (3)C9—C171.414 (4)
O2—C51.242 (3)C9—C101.432 (6)
O3—C21.256 (3)C10—C111.329 (6)
O4—C31.216 (4)C10—H100.93
N1—C21.369 (4)C11—C121.435 (6)
N1—C31.383 (4)C11—H110.93
N1—H10.86C12—C131.396 (5)
N2—C41.327 (4)C12—C161.417 (5)
N2—C31.367 (4)C13—C141.355 (5)
N2—H20.86C13—H130.93
N3—C61.322 (4)C14—C151.399 (5)
N3—C171.364 (4)C14—H140.93
N4—C151.323 (4)C15—H150.93
N4—C161.356 (4)C16—C171.439 (4)
C1—C41.369 (4)O5—H5A0.85
C1—C21.421 (4)O5—H5B0.85
O1—Gd1—O1i88.22 (11)N1—C2—C1116.0 (3)
O1—Gd1—O3i82.54 (8)O4—C3—N2123.0 (3)
O1i—Gd1—O3i73.65 (8)O4—C3—N1122.0 (3)
O1—Gd1—O373.65 (8)N2—C3—N1114.9 (3)
O1i—Gd1—O382.54 (8)N2—C4—C1125.5 (3)
O3i—Gd1—O3146.71 (11)N2—C4—H4117.3
O1—Gd1—N3i148.84 (8)C1—C4—H4117.3
O1i—Gd1—N3i105.26 (9)O2—C5—O1122.3 (3)
O3i—Gd1—N3i74.86 (8)O2—C5—C1119.0 (3)
O3—Gd1—N3i135.03 (8)O1—C5—C1118.6 (3)
O1—Gd1—N3105.26 (9)N3—C6—C7123.7 (3)
O1i—Gd1—N3148.84 (8)N3—C6—H6118.1
O3i—Gd1—N3135.03 (8)C7—C6—H6118.1
O3—Gd1—N374.86 (8)C8—C7—C6118.6 (4)
N3i—Gd1—N377.63 (12)C8—C7—H7120.7
O1—Gd1—N480.80 (8)C6—C7—H7120.7
O1i—Gd1—N4147.64 (8)C7—C8—C9120.2 (4)
O3i—Gd1—N474.79 (8)C7—C8—H8119.9
O3—Gd1—N4122.38 (8)C9—C8—H8119.9
N3i—Gd1—N472.83 (8)C8—C9—C17117.7 (4)
N3—Gd1—N463.39 (8)C8—C9—C10123.7 (4)
O1—Gd1—N4i147.64 (8)C17—C9—C10118.6 (4)
O1i—Gd1—N4i80.80 (8)C11—C10—C9121.9 (4)
O3i—Gd1—N4i122.38 (8)C11—C10—H10119.1
O3—Gd1—N4i74.79 (8)C9—C10—H10119.1
N3i—Gd1—N4i63.39 (8)C10—C11—C12121.4 (4)
N3—Gd1—N4i72.83 (8)C10—C11—H11119.3
N4—Gd1—N4i123.04 (11)C12—C11—H11119.3
C5—O1—Gd1140.60 (19)C13—C12—C16116.9 (3)
C2—O3—Gd1132.05 (19)C13—C12—C11124.0 (4)
C2—N1—C3126.4 (3)C16—C12—C11119.1 (4)
C2—N1—H1116.8C14—C13—C12120.5 (4)
C3—N1—H1116.8C14—C13—H13119.7
C4—N2—C3120.6 (3)C12—C13—H13119.7
C4—N2—H2119.7C13—C14—C15118.7 (4)
C3—N2—H2119.7C13—C14—H14120.7
C6—N3—C17117.6 (3)C15—C14—H14120.7
C6—N3—Gd1123.3 (2)N4—C15—C14123.6 (3)
C17—N3—Gd1117.6 (2)N4—C15—H15118.2
C15—N4—C16117.7 (3)C14—C15—H15118.2
C15—N4—Gd1123.4 (2)N4—C16—C12122.5 (3)
C16—N4—Gd1117.1 (2)N4—C16—C17118.5 (3)
C4—C1—C2116.3 (3)C12—C16—C17119.0 (3)
C4—C1—C5120.5 (3)N3—C17—C9122.0 (3)
C2—C1—C5123.2 (3)N3—C17—C16118.0 (3)
O3—C2—N1117.1 (3)C9—C17—C16120.0 (3)
O3—C2—C1126.9 (3)H5A—O5—H5B113.1
O1i—Gd1—O1—C5−72.3 (3)C4—N2—C3—O4−178.6 (3)
O3i—Gd1—O1—C5−146.0 (3)C4—N2—C3—N10.8 (5)
O3—Gd1—O1—C510.5 (3)C2—N1—C3—O4−176.8 (3)
N3i—Gd1—O1—C5170.5 (3)C2—N1—C3—N23.9 (5)
N3—Gd1—O1—C579.2 (3)C3—N2—C4—C1−2.7 (5)
N4—Gd1—O1—C5138.3 (3)C2—C1—C4—N20.2 (5)
N4i—Gd1—O1—C5−2.7 (4)C5—C1—C4—N2−179.2 (3)
O1—Gd1—O3—C2−23.0 (3)Gd1—O1—C5—O2−176.9 (2)
O1i—Gd1—O3—C267.3 (3)Gd1—O1—C5—C13.6 (5)
O3i—Gd1—O3—C223.1 (3)C4—C1—C5—O2−15.4 (5)
N3i—Gd1—O3—C2171.5 (2)C2—C1—C5—O2165.2 (3)
N3—Gd1—O3—C2−134.3 (3)C4—C1—C5—O1164.1 (3)
N4—Gd1—O3—C2−90.5 (3)C2—C1—C5—O1−15.2 (5)
N4i—Gd1—O3—C2149.8 (3)C17—N3—C6—C72.5 (5)
O1—Gd1—N3—C6−104.0 (2)Gd1—N3—C6—C7−163.2 (3)
O1i—Gd1—N3—C68.9 (3)N3—C6—C7—C80.3 (6)
O3i—Gd1—N3—C6161.3 (2)C6—C7—C8—C9−2.0 (6)
O3—Gd1—N3—C6−36.1 (2)C7—C8—C9—C170.9 (5)
N3i—Gd1—N3—C6108.0 (3)C7—C8—C9—C10−178.9 (4)
N4—Gd1—N3—C6−175.2 (3)C8—C9—C10—C11177.3 (4)
N4i—Gd1—N3—C642.3 (2)C17—C9—C10—C11−2.5 (6)
O1—Gd1—N3—C1790.3 (2)C9—C10—C11—C12−0.4 (7)
O1i—Gd1—N3—C17−156.8 (2)C10—C11—C12—C13−177.2 (4)
O3i—Gd1—N3—C17−4.4 (3)C10—C11—C12—C162.5 (6)
O3—Gd1—N3—C17158.2 (2)C16—C12—C13—C14−0.5 (6)
N3i—Gd1—N3—C17−57.7 (2)C11—C12—C13—C14179.1 (4)
N4—Gd1—N3—C1719.1 (2)C12—C13—C14—C151.6 (6)
N4i—Gd1—N3—C17−123.4 (2)C16—N4—C15—C14−2.3 (5)
O1—Gd1—N4—C1564.5 (2)Gd1—N4—C15—C14162.0 (3)
O1i—Gd1—N4—C15−7.1 (3)C13—C14—C15—N4−0.2 (6)
O3i—Gd1—N4—C15−20.2 (2)C15—N4—C16—C123.4 (5)
O3—Gd1—N4—C15128.4 (2)Gd1—N4—C16—C12−161.8 (3)
N3i—Gd1—N4—C15−98.7 (3)C15—N4—C16—C17−176.8 (3)
N3—Gd1—N4—C15176.8 (3)Gd1—N4—C16—C1718.0 (3)
N4i—Gd1—N4—C15−139.2 (3)C13—C12—C16—N4−2.1 (5)
O1—Gd1—N4—C16−131.1 (2)C11—C12—C16—N4178.2 (3)
O1i—Gd1—N4—C16157.20 (19)C13—C12—C16—C17178.2 (3)
O3i—Gd1—N4—C16144.2 (2)C11—C12—C16—C17−1.5 (5)
O3—Gd1—N4—C16−67.3 (2)C6—N3—C17—C9−3.7 (5)
N3i—Gd1—N4—C1665.6 (2)Gd1—N3—C17—C9162.9 (2)
N3—Gd1—N4—C16−18.8 (2)C6—N3—C17—C16174.8 (3)
N4i—Gd1—N4—C1625.13 (19)Gd1—N3—C17—C16−18.6 (4)
Gd1—O3—C2—N1−158.7 (2)C8—C9—C17—N32.0 (5)
Gd1—O3—C2—C122.2 (5)C10—C9—C17—N3−178.1 (3)
C3—N1—C2—O3174.5 (3)C8—C9—C17—C16−176.4 (3)
C3—N1—C2—C1−6.2 (5)C10—C9—C17—C163.4 (5)
C4—C1—C2—O3−176.9 (3)N4—C16—C17—N30.3 (4)
C5—C1—C2—O32.5 (5)C12—C16—C17—N3−179.9 (3)
C4—C1—C2—N13.9 (4)N4—C16—C17—C9178.8 (3)
C5—C1—C2—N1−176.7 (3)C12—C16—C17—C9−1.4 (5)
D—H···AD—HH···AD···AD—H···A
N1—H1···O2ii0.862.042.898 (3)178
N1—H1···O1ii0.862.603.160 (4)124
N2—H2···N2iii0.861.812.669 (5)174
O5—H5A···O4iv0.852.142.970 (4)164
O5—H5B···O2v0.852.142.985 (4)173
Gd1—O12.288 (2)
Gd1—O32.344 (2)
Gd1—N32.586 (3)
Gd1—N42.603 (3)
O1—Gd1—O1i88.22 (11)
O1—Gd1—O3i82.54 (8)
O1—Gd1—O373.65 (8)
O3i—Gd1—O3146.71 (11)
O1—Gd1—N3i148.84 (8)
O3—Gd1—N3i135.03 (8)
O1—Gd1—N3105.26 (9)
O3—Gd1—N374.86 (8)
O1—Gd1—N480.80 (8)
O3—Gd1—N4122.38 (8)
N3—Gd1—N463.39 (8)
O1—Gd1—N4i147.64 (8)
O3—Gd1—N4i74.79 (8)
N3—Gd1—N4i72.83 (8)
N4—Gd1—N4i123.04 (11)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯AD—HH⋯AD⋯AD—H⋯A
N1—H1⋯O2ii0.862.042.898 (3)178
N1—H1⋯O1ii0.862.603.160 (4)124
N2—H2⋯N2iii0.861.812.669 (5)174
O5—H5A⋯O4iv0.852.142.970 (4)164
O5—H5B⋯O2v0.852.142.985 (4)173

Symmetry codes: (ii) ; (iii) ; (iv) ; (v) .

  3 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  (6-Oxido-2-oxo-1,2-dihydropyrimidine-5-carboxylato-κO,O)(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxyl-ato-κO,O)bis(1,10-phenanthroline-κN,N')erbium(III) dihydrate.

Authors:  Hui-Hui Xing; Zi-Lu Chen; Seik Weng Ng
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-01-25

3.  (μ-6-Oxido-4-oxo-1,2-dihydro-pyrimidine-5-carboxyl-ato-κO,O:O,N)bis-[aquabis-(4-oxido-2-oxo-1,2-dihydro-pyrimidin-3-ium-5-carboxyl-ato-κO,O)-(1,10-phenanthroline-κN,N')neodymium(III)] hexa-hydrate.

Authors:  Hui-Hui Xing; Zi-Lu Chen; Seik Weng Ng
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-01-25
  3 in total
  1 in total

1.  Bis[4-oxido-2-oxo-2,3-di-hydro-pyrimidin-1-ium-5-carboxyl-ato(1.5-)-κO,O]bis-(1,10-phenanthroline-κN,N')dysprosium(III) dihydrate.

Authors:  Xianlin Liu; Huihui Xing; Jing Miao; Maomao Jia; Zilu Chen
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-09-19
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.