| Literature DB >> 21201607 |
Roya Ahmadi, Vahid Amani, Hamid Reza Khavasi.
Abstract
In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordination. In the crystal structure, intra- and inter-molecular C-H⋯Cl hydrogen bonds are found.Entities:
Year: 2008 PMID: 21201607 PMCID: PMC2960497 DOI: 10.1107/S1600536808025476
Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN: 1600-5368
| [AuCl2(C24H16N2)][AuCl4] | |
| Monoclinic, | Mo |
| Hall symbol: -C 2yc | Cell parameters from 2231 reflections |
| θ = 1.7–29.2º | |
| µ = 12.10 mm−1 | |
| β = 101.207 (5)º | Prism, yellow |
| 0.43 × 0.35 × 0.30 mm | |
| Bruker SMART CCD area-detector diffractometer | 6864 independent reflections |
| Radiation source: fine-focus sealed tube | 6404 reflections with |
| Monochromator: graphite | |
| θmax = 29.2º | |
| φ and ω scans | θmin = 1.7º |
| Absorption correction: numericalshape of crystal determined optically (PROGRAM? Reference?) | |
| 18667 measured reflections |
| Refinement on | Hydrogen site location: inferred from neighbouring sites |
| Least-squares matrix: full | H-atom parameters constrained |
| | |
| (Δ/σ)max = 0.048 | |
| Δρmax = 1.07 e Å−3 | |
| 6864 reflections | Δρmin = −1.02 e Å−3 |
| 308 parameters | Extinction correction: SHELXTL (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4 |
| Primary atom site location: structure-invariant direct methods | Extinction coefficient: 0.00055 (6) |
| Secondary atom site location: difference Fourier map |
| Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
| Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
| Au1 | 0.097267 (11) | −0.152249 (19) | 0.112685 (18) | 0.01435 (13) | |
| Au2 | 0.165438 (12) | 0.96986 (2) | 0.854512 (18) | 0.01739 (13) | |
| Cl1 | 0.12293 (8) | −0.30783 (14) | 0.10295 (15) | 0.0240 (4) | |
| Cl2 | 0.01813 (8) | −0.20496 (16) | 0.12856 (16) | 0.0259 (4) | |
| Cl3 | 0.21356 (9) | 1.10394 (18) | 0.83479 (15) | 0.0280 (4) | |
| Cl4 | 0.23388 (10) | 0.87252 (19) | 0.84084 (16) | 0.0320 (5) | |
| Cl5 | 0.11779 (10) | 0.83657 (16) | 0.87768 (15) | 0.0284 (5) | |
| Cl6 | 0.09622 (8) | 1.06689 (16) | 0.86481 (15) | 0.0257 (4) | |
| N1 | 0.0787 (3) | −0.0088 (5) | 0.1182 (5) | 0.0160 (12) | |
| N2 | 0.1667 (2) | −0.0939 (5) | 0.1005 (4) | 0.0138 (11) | |
| C1 | 0.0334 (3) | 0.0290 (6) | 0.1291 (6) | 0.0203 (15) | |
| H1 | 0.0055 | −0.0117 | 0.1321 | 0.024* | |
| C2 | 0.0279 (3) | 0.1283 (7) | 0.1359 (6) | 0.0193 (14) | |
| H2 | −0.0041 | 0.1535 | 0.1422 | 0.023* | |
| C3 | 0.0691 (3) | 0.1922 (6) | 0.1336 (5) | 0.0159 (13) | |
| C4 | 0.0612 (3) | 0.2989 (6) | 0.1480 (5) | 0.0161 (13) | |
| C5 | 0.0146 (4) | 0.3441 (6) | 0.1051 (6) | 0.0211 (16) | |
| H5 | −0.0114 | 0.3090 | 0.0661 | 0.025* | |
| C6 | 0.0082 (3) | 0.4422 (7) | 0.1221 (6) | 0.0239 (16) | |
| H6 | −0.0222 | 0.4734 | 0.0937 | 0.029* | |
| C7 | 0.0463 (4) | 0.4939 (6) | 0.1804 (6) | 0.0229 (16) | |
| H7 | 0.0418 | 0.5599 | 0.1898 | 0.027* | |
| C8 | 0.0914 (4) | 0.4485 (6) | 0.2254 (6) | 0.0243 (16) | |
| H8 | 0.1167 | 0.4834 | 0.2660 | 0.029* | |
| C9 | 0.0985 (4) | 0.3503 (5) | 0.2094 (6) | 0.0194 (15) | |
| H9 | 0.1285 | 0.3191 | 0.2400 | 0.023* | |
| C10 | 0.1156 (3) | 0.1527 (5) | 0.1165 (5) | 0.0127 (13) | |
| C11 | 0.1599 (3) | 0.2079 (5) | 0.1012 (5) | 0.0146 (13) | |
| H11 | 0.1577 | 0.2754 | 0.0998 | 0.018* | |
| C12 | 0.2050 (3) | 0.1647 (5) | 0.0888 (6) | 0.0161 (13) | |
| H12 | 0.2322 | 0.2029 | 0.0769 | 0.019* | |
| C13 | 0.2106 (3) | 0.0604 (5) | 0.0940 (5) | 0.0125 (12) | |
| C14 | 0.2567 (3) | 0.0094 (5) | 0.0877 (5) | 0.0139 (12) | |
| C15 | 0.3067 (3) | 0.0582 (5) | 0.0815 (5) | 0.0133 (12) | |
| C16 | 0.3258 (3) | 0.1344 (6) | 0.1443 (5) | 0.0178 (14) | |
| H16 | 0.3066 | 0.1577 | 0.1874 | 0.021* | |
| C17 | 0.3743 (3) | 0.1738 (6) | 0.1401 (6) | 0.0194 (14) | |
| H17 | 0.3868 | 0.2254 | 0.1796 | 0.023* | |
| C18 | 0.4039 (3) | 0.1381 (6) | 0.0787 (6) | 0.0202 (15) | |
| H18 | 0.4366 | 0.1637 | 0.0782 | 0.024* | |
| C19 | 0.3838 (3) | 0.0621 (6) | 0.0167 (5) | 0.0195 (14) | |
| H19 | 0.4032 | 0.0384 | −0.0258 | 0.023* | |
| C20 | 0.3364 (3) | 0.0230 (5) | 0.0182 (5) | 0.0146 (13) | |
| H20 | 0.3236 | −0.0272 | −0.0230 | 0.018* | |
| C21 | 0.2552 (3) | −0.0924 (6) | 0.0870 (5) | 0.0160 (13) | |
| H21 | 0.2849 | −0.1274 | 0.0823 | 0.019* | |
| C22 | 0.2093 (3) | −0.1420 (6) | 0.0935 (5) | 0.0170 (14) | |
| H22 | 0.2089 | −0.2096 | 0.0929 | 0.020* | |
| C23 | 0.1672 (3) | 0.0044 (5) | 0.1023 (4) | 0.0129 (13) | |
| C24 | 0.1190 (3) | 0.0514 (5) | 0.1122 (5) | 0.0113 (12) |
| Au1 | 0.01838 (19) | 0.01279 (17) | 0.01316 (17) | −0.00363 (8) | 0.00622 (12) | −0.00142 (9) |
| Au2 | 0.0225 (2) | 0.01961 (19) | 0.00978 (17) | 0.00323 (9) | 0.00248 (12) | −0.00040 (9) |
| Cl1 | 0.0312 (9) | 0.0133 (8) | 0.0308 (9) | −0.0030 (7) | 0.0144 (8) | 0.0002 (7) |
| Cl2 | 0.0258 (9) | 0.0216 (9) | 0.0340 (10) | −0.0098 (7) | 0.0152 (8) | −0.0046 (8) |
| Cl3 | 0.0315 (10) | 0.0319 (11) | 0.0216 (8) | −0.0063 (8) | 0.0079 (8) | 0.0042 (8) |
| Cl4 | 0.0382 (12) | 0.0347 (11) | 0.0229 (9) | 0.0178 (10) | 0.0057 (9) | −0.0016 (9) |
| Cl5 | 0.0424 (12) | 0.0248 (10) | 0.0176 (8) | −0.0076 (8) | 0.0050 (8) | −0.0014 (7) |
| Cl6 | 0.0248 (9) | 0.0259 (10) | 0.0272 (9) | 0.0051 (7) | 0.0066 (8) | −0.0032 (8) |
| N1 | 0.023 (3) | 0.012 (3) | 0.016 (3) | −0.002 (2) | 0.010 (2) | 0.002 (2) |
| N2 | 0.015 (3) | 0.016 (3) | 0.013 (2) | −0.003 (2) | 0.007 (2) | 0.001 (2) |
| C1 | 0.022 (4) | 0.017 (4) | 0.024 (4) | −0.005 (3) | 0.009 (3) | −0.003 (3) |
| C2 | 0.012 (3) | 0.026 (4) | 0.022 (3) | 0.000 (3) | 0.008 (3) | −0.003 (3) |
| C3 | 0.015 (3) | 0.016 (3) | 0.016 (3) | 0.003 (3) | 0.001 (3) | 0.004 (3) |
| C4 | 0.024 (3) | 0.014 (3) | 0.014 (3) | 0.004 (3) | 0.011 (3) | −0.002 (3) |
| C5 | 0.027 (4) | 0.018 (4) | 0.018 (3) | 0.005 (3) | 0.007 (3) | −0.003 (3) |
| C6 | 0.025 (4) | 0.027 (4) | 0.023 (4) | 0.014 (3) | 0.015 (3) | 0.004 (3) |
| C7 | 0.038 (5) | 0.016 (3) | 0.021 (3) | 0.001 (3) | 0.022 (3) | −0.002 (3) |
| C8 | 0.031 (4) | 0.016 (3) | 0.025 (4) | −0.003 (3) | 0.003 (3) | −0.004 (3) |
| C9 | 0.030 (4) | 0.012 (3) | 0.016 (3) | 0.002 (3) | 0.002 (3) | −0.001 (3) |
| C10 | 0.014 (3) | 0.014 (3) | 0.012 (3) | −0.002 (2) | 0.007 (2) | 0.000 (2) |
| C11 | 0.016 (3) | 0.015 (3) | 0.015 (3) | 0.002 (2) | 0.006 (3) | 0.002 (3) |
| C12 | 0.015 (3) | 0.012 (3) | 0.022 (3) | −0.006 (2) | 0.006 (3) | 0.002 (3) |
| C13 | 0.009 (3) | 0.015 (3) | 0.015 (3) | −0.001 (2) | 0.006 (2) | 0.000 (3) |
| C14 | 0.018 (3) | 0.012 (3) | 0.012 (3) | −0.002 (2) | 0.003 (3) | −0.001 (2) |
| C15 | 0.007 (3) | 0.017 (3) | 0.015 (3) | 0.003 (2) | 0.001 (2) | 0.003 (3) |
| C16 | 0.016 (3) | 0.018 (3) | 0.017 (3) | 0.002 (3) | −0.001 (3) | 0.002 (3) |
| C17 | 0.021 (4) | 0.015 (3) | 0.022 (3) | −0.001 (3) | 0.006 (3) | 0.000 (3) |
| C18 | 0.019 (4) | 0.016 (3) | 0.026 (4) | −0.001 (3) | 0.005 (3) | −0.001 (3) |
| C19 | 0.019 (3) | 0.024 (4) | 0.016 (3) | −0.001 (3) | 0.005 (3) | −0.001 (3) |
| C20 | 0.018 (3) | 0.018 (3) | 0.010 (3) | −0.001 (2) | 0.008 (3) | −0.001 (2) |
| C21 | 0.017 (3) | 0.016 (3) | 0.018 (3) | 0.002 (2) | 0.009 (3) | −0.001 (3) |
| C22 | 0.024 (4) | 0.016 (3) | 0.013 (3) | 0.004 (3) | 0.008 (3) | 0.002 (3) |
| C23 | 0.018 (3) | 0.017 (3) | 0.005 (3) | 0.003 (3) | 0.004 (2) | −0.004 (3) |
| C24 | 0.015 (3) | 0.009 (3) | 0.011 (3) | −0.006 (2) | 0.007 (2) | 0.001 (2) |
| Au1—N2 | 2.032 (6) | C10—C11 | 1.442 (10) |
| Au1—N1 | 2.039 (7) | C11—C12 | 1.367 (10) |
| Au1—Cl2 | 2.2546 (19) | C11—H11 | 0.9300 |
| Au1—Cl1 | 2.257 (2) | C12—C13 | 1.444 (10) |
| Au2—Cl4 | 2.281 (2) | C12—H12 | 0.9300 |
| Au2—Cl5 | 2.281 (2) | C13—C23 | 1.401 (9) |
| Au2—Cl6 | 2.284 (2) | C13—C14 | 1.417 (10) |
| Au2—Cl3 | 2.285 (2) | C14—C21 | 1.400 (10) |
| C1—N1 | 1.335 (10) | C14—C15 | 1.494 (10) |
| C1—C2 | 1.379 (11) | C15—C20 | 1.398 (9) |
| C1—H1 | 0.9300 | C15—C16 | 1.412 (11) |
| C2—C3 | 1.399 (10) | C16—C17 | 1.395 (11) |
| C2—H2 | 0.9300 | C16—H16 | 0.9300 |
| C3—C10 | 1.403 (10) | C17—C18 | 1.378 (12) |
| C3—C4 | 1.502 (10) | C17—H17 | 0.9300 |
| C4—C9 | 1.381 (11) | C18—C19 | 1.411 (11) |
| C4—C5 | 1.404 (11) | C18—H18 | 0.9300 |
| C5—C6 | 1.389 (11) | C19—C20 | 1.361 (10) |
| C5—H5 | 0.9300 | C19—H19 | 0.9300 |
| C6—C7 | 1.373 (14) | C20—H20 | 0.9300 |
| C6—H6 | 0.9300 | C21—C22 | 1.405 (11) |
| C7—C8 | 1.383 (13) | C21—H21 | 0.9300 |
| C7—H7 | 0.9300 | C22—N2 | 1.320 (10) |
| C8—C9 | 1.390 (11) | C22—H22 | 0.9300 |
| C8—H8 | 0.9300 | C23—N2 | 1.352 (9) |
| C9—H9 | 0.9300 | C23—C24 | 1.454 (9) |
| C10—C24 | 1.399 (9) | C24—N1 | 1.359 (9) |
| N2—Au1—N1 | 81.1 (3) | C11—C12—C13 | 120.6 (7) |
| N2—Au1—Cl2 | 175.42 (19) | C11—C12—H12 | 119.7 |
| N1—Au1—Cl2 | 94.3 (2) | C13—C12—H12 | 119.7 |
| N2—Au1—Cl1 | 94.92 (19) | C23—C13—C14 | 116.9 (7) |
| N1—Au1—Cl1 | 175.95 (19) | C23—C13—C12 | 118.3 (6) |
| Cl2—Au1—Cl1 | 89.62 (8) | C14—C13—C12 | 124.8 (6) |
| Cl4—Au2—Cl5 | 90.26 (10) | C21—C14—C13 | 118.2 (7) |
| Cl4—Au2—Cl6 | 178.77 (8) | C21—C14—C15 | 118.3 (7) |
| Cl5—Au2—Cl6 | 89.67 (9) | C13—C14—C15 | 123.5 (7) |
| Cl4—Au2—Cl3 | 89.96 (10) | C20—C15—C16 | 120.2 (7) |
| Cl5—Au2—Cl3 | 178.75 (7) | C20—C15—C14 | 119.4 (7) |
| Cl6—Au2—Cl3 | 90.14 (9) | C16—C15—C14 | 120.2 (6) |
| N1—C1—C2 | 120.1 (7) | C17—C16—C15 | 118.3 (7) |
| N1—C1—H1 | 119.9 | C17—C16—H16 | 120.8 |
| C2—C1—H1 | 119.9 | C15—C16—H16 | 120.9 |
| C1—C2—C3 | 121.9 (7) | C18—C17—C16 | 121.5 (8) |
| C1—C2—H2 | 119.0 | C18—C17—H17 | 119.2 |
| C3—C2—H2 | 119.0 | C16—C17—H17 | 119.2 |
| C2—C3—C10 | 117.7 (7) | C17—C18—C19 | 118.9 (8) |
| C2—C3—C4 | 118.9 (7) | C17—C18—H18 | 120.6 |
| C10—C3—C4 | 123.5 (7) | C19—C18—H18 | 120.5 |
| C9—C4—C5 | 120.3 (7) | C20—C19—C18 | 120.9 (7) |
| C9—C4—C3 | 119.3 (7) | C20—C19—H19 | 119.5 |
| C5—C4—C3 | 120.2 (7) | C18—C19—H19 | 119.6 |
| C6—C5—C4 | 118.5 (8) | C19—C20—C15 | 120.1 (7) |
| C6—C5—H5 | 120.7 | C19—C20—H20 | 119.9 |
| C4—C5—H5 | 120.8 | C15—C20—H20 | 120.0 |
| C7—C6—C5 | 120.9 (8) | C14—C21—C22 | 120.7 (7) |
| C7—C6—H6 | 119.6 | C14—C21—H21 | 119.6 |
| C5—C6—H6 | 119.5 | C22—C21—H21 | 119.7 |
| C6—C7—C8 | 120.6 (8) | N2—C22—C21 | 120.7 (7) |
| C6—C7—H7 | 119.7 | N2—C22—H22 | 119.7 |
| C8—C7—H7 | 119.7 | C21—C22—H22 | 119.6 |
| C7—C8—C9 | 119.4 (8) | N2—C23—C13 | 123.6 (6) |
| C7—C8—H8 | 120.3 | N2—C23—C24 | 116.2 (6) |
| C9—C8—H8 | 120.3 | C13—C23—C24 | 120.2 (6) |
| C4—C9—C8 | 120.2 (8) | N1—C24—C10 | 123.2 (7) |
| C4—C9—H9 | 119.9 | N1—C24—C23 | 116.0 (6) |
| C8—C9—H9 | 119.9 | C10—C24—C23 | 120.8 (6) |
| C24—C10—C3 | 117.3 (7) | C1—N1—C24 | 119.5 (7) |
| C24—C10—C11 | 117.3 (6) | C1—N1—Au1 | 127.4 (5) |
| C3—C10—C11 | 125.4 (7) | C24—N1—Au1 | 113.1 (5) |
| C12—C11—C10 | 122.4 (7) | C22—N2—C23 | 119.9 (6) |
| C12—C11—H11 | 118.8 | C22—N2—Au1 | 126.6 (5) |
| C10—C11—H11 | 118.8 | C23—N2—Au1 | 113.5 (5) |
| N1—C1—C2—C3 | −1.3 (13) | C18—C19—C20—C15 | 0.2 (12) |
| C1—C2—C3—C10 | 5.0 (12) | C16—C15—C20—C19 | 0.0 (11) |
| C1—C2—C3—C4 | −175.9 (8) | C14—C15—C20—C19 | −175.1 (7) |
| C2—C3—C4—C9 | 133.5 (8) | C13—C14—C21—C22 | −0.7 (10) |
| C10—C3—C4—C9 | −47.4 (10) | C15—C14—C21—C22 | 179.4 (7) |
| C2—C3—C4—C5 | −41.7 (10) | C14—C21—C22—N2 | −0.1 (11) |
| C10—C3—C4—C5 | 137.4 (8) | C14—C13—C23—N2 | −2.9 (10) |
| C9—C4—C5—C6 | 3.2 (12) | C12—C13—C23—N2 | 174.8 (7) |
| C3—C4—C5—C6 | 178.3 (7) | C14—C13—C23—C24 | 178.0 (6) |
| C4—C5—C6—C7 | −0.7 (12) | C12—C13—C23—C24 | −4.3 (10) |
| C5—C6—C7—C8 | −1.6 (13) | C3—C10—C24—N1 | 3.9 (10) |
| C6—C7—C8—C9 | 1.5 (13) | C11—C10—C24—N1 | −175.0 (6) |
| C5—C4—C9—C8 | −3.3 (12) | C3—C10—C24—C23 | −175.0 (6) |
| C3—C4—C9—C8 | −178.5 (8) | C11—C10—C24—C23 | 6.1 (10) |
| C7—C8—C9—C4 | 0.9 (13) | N2—C23—C24—N1 | −0.2 (9) |
| C2—C3—C10—C24 | −6.1 (10) | C13—C23—C24—N1 | 179.0 (6) |
| C4—C3—C10—C24 | 174.8 (7) | N2—C23—C24—C10 | 178.9 (6) |
| C2—C3—C10—C11 | 172.7 (7) | C13—C23—C24—C10 | −2.0 (10) |
| C4—C3—C10—C11 | −6.4 (11) | C2—C1—N1—C24 | −1.2 (12) |
| C24—C10—C11—C12 | −4.0 (11) | C2—C1—N1—Au1 | 176.9 (6) |
| C3—C10—C11—C12 | 177.2 (7) | C10—C24—N1—C1 | −0.2 (11) |
| C10—C11—C12—C13 | −2.3 (11) | C23—C24—N1—C1 | 178.8 (7) |
| C11—C12—C13—C23 | 6.5 (11) | C10—C24—N1—Au1 | −178.6 (5) |
| C11—C12—C13—C14 | −176.1 (7) | C23—C24—N1—Au1 | 0.4 (7) |
| C23—C13—C14—C21 | 2.1 (10) | N2—Au1—N1—C1 | −178.6 (7) |
| C12—C13—C14—C21 | −175.4 (7) | Cl2—Au1—N1—C1 | 0.7 (7) |
| C23—C13—C14—C15 | −178.1 (6) | N2—Au1—N1—C24 | −0.4 (5) |
| C12—C13—C14—C15 | 4.4 (11) | Cl2—Au1—N1—C24 | 179.0 (5) |
| C21—C14—C15—C20 | 42.6 (10) | C21—C22—N2—C23 | −0.6 (10) |
| C13—C14—C15—C20 | −137.3 (7) | C21—C22—N2—Au1 | −178.9 (5) |
| C21—C14—C15—C16 | −132.5 (7) | C13—C23—N2—C22 | 2.2 (10) |
| C13—C14—C15—C16 | 47.7 (10) | C24—C23—N2—C22 | −178.7 (6) |
| C20—C15—C16—C17 | 1.0 (11) | C13—C23—N2—Au1 | −179.3 (5) |
| C14—C15—C16—C17 | 176.0 (7) | C24—C23—N2—Au1 | −0.2 (7) |
| C15—C16—C17—C18 | −2.1 (12) | N1—Au1—N2—C22 | 178.7 (6) |
| C16—C17—C18—C19 | 2.2 (13) | N1—Au1—N2—C23 | 0.3 (5) |
| C17—C18—C19—C20 | −1.2 (12) | Cl1—Au1—N2—C23 | 179.4 (4) |
| H··· | ||||
| C1—H1···Cl2 | 0.93 | 2.68 | 3.244 (9) | 120 |
| C1—H1···Cl6i | 0.93 | 2.79 | 3.668 (8) | 159 |
| C18—H18···Cl2ii | 0.93 | 2.79 | 3.653 (8) | 155 |
| C22—H22···Cl1 | 0.93 | 2.66 | 3.239 (8) | 121 |
| C22—H22···Cl4iii | 0.93 | 2.76 | 3.555 (9) | 143 |
| Au1—N2 | 2.032 (6) |
| Au1—N1 | 2.039 (7) |
| Au1—Cl2 | 2.2546 (19) |
| Au1—Cl1 | 2.257 (2) |
| Au2—Cl4 | 2.281 (2) |
| Au2—Cl5 | 2.281 (2) |
| Au2—Cl6 | 2.284 (2) |
| Au2—Cl3 | 2.285 (2) |
| N2—Au1—N1 | 81.1 (3) |
| N2—Au1—Cl2 | 175.42 (19) |
| N1—Au1—Cl2 | 94.3 (2) |
| N2—Au1—Cl1 | 94.92 (19) |
| N1—Au1—Cl1 | 175.95 (19) |
| Cl2—Au1—Cl1 | 89.62 (8) |
| Cl4—Au2—Cl5 | 90.26 (10) |
| Cl4—Au2—Cl6 | 178.77 (8) |
| Cl5—Au2—Cl6 | 89.67 (9) |
| Cl4—Au2—Cl3 | 89.96 (10) |
| Cl5—Au2—Cl3 | 178.75 (7) |
| Cl6—Au2—Cl3 | 90.14 (9) |
Hydrogen-bond geometry (Å, °)
| H⋯ | ||||
|---|---|---|---|---|
| C1—H1⋯Cl2 | 0.93 | 2.68 | 3.244 (9) | 120 |
| C1—H1⋯Cl6i | 0.93 | 2.79 | 3.668 (8) | 159 |
| C18—H18⋯Cl2ii | 0.93 | 2.79 | 3.653 (8) | 155 |
| C22—H22⋯Cl1 | 0.93 | 2.66 | 3.239 (8) | 121 |
| C22—H22⋯Cl4iii | 0.93 | 2.76 | 3.555 (9) | 143 |
Symmetry codes: (i) ; (ii) ; (iii) .