4,5,6,7-Tetra-bromo-1,1,3-trimethyl-3-(2,3,4,5-tetra-bromo-phen-yl)indane.

The title compound (OctaInd), C(18)H(12)Br(8), is a commercial brominated flame retardant (BFR). In the mol-ecule, the five-membered ring has a slight envelope conformation, with a deviation of 0.317 (9) Å for the flap C atom from four essentially planar C atoms. The dihedral angle between the two benzene rings is 74.00 (16) Å.

Related literature

For related literature, see: Andersson et al. (2006 ▶); Muir et al. (2007 ▶); Richardson (2007 ▶). See also Appendix 3 in a Danish EPA report published in 1999 on ‘Physical-chemical Properties of Brominated Flame Retardants’; http://www2.mst.dk/udgiv/Publications/1999/87-7909-416-3/html/bil03_eng.htm.

Experimental

Crystal data

C18H12Br8

M = 867.56

Monoclinic,

a = 20.2603 (6) Å

b = 7.3862 (2) Å

c = 15.2233 (8) Å

β = 110.4070 (15)°

V = 2135.14 (14) Å3

Z = 4

Mo Kα radiation

μ = 15.03 mm−1

T = 150 (1) K

0.16 × 0.14 × 0.14 mm

Data collection

Nonius KappaCCD diffractometer

Absorption correction: multi-scan (SORTAV; Blessing, 1995 ▶) T min = 0.057, T max = 0.122

13121 measured reflections

4862 independent reflections

3509 reflections with I > 2σ(I)

R int = 0.059

Refinement

R[F 2 > 2σ(F 2)] = 0.045

wR(F 2) = 0.111

S = 0.99

4862 reflections

238 parameters

H-atom parameters constrained

Δρmax = 1.33 e Å−3

Δρmin = −1.34 e Å−3

Data collection: COLLECT (Nonius, 2002 ▶); cell refinement: DENZO–SMN (Otwinowski & Minor, 1997 ▶); data reduction: DENZO–SMN; program(s) used to solve structure: SIR92 (Altomare et al., 1994 ▶); program(s) used to refine structure: SHELXTL (Sheldrick, 2001 ▶); molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808000494/bv2087sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808000494/bv2087Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C18H12Br8	F000 = 1600
Mr = 867.56	Dx = 2.699 Mg m−3
Monoclinic, P21/c	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 13121 reflections
a = 20.2603 (6) Å	θ = 2.7–27.5º
b = 7.3862 (2) Å	µ = 15.03 mm−1
c = 15.2233 (8) Å	T = 150 (1) K
β = 110.4070 (15)º	Block, colourless
V = 2135.14 (14) Å3	0.16 × 0.14 × 0.14 mm
Z = 4

Nonius KappaCCD diffractometer	4862 independent reflections
Radiation source: fine-focus sealed tube	3509 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.059
Detector resolution: 9 pixels mm-1	θmax = 27.5º
T = 150(1) K	θmin = 2.7º
φ scans and ω scans with κ offsets	h = −25→26
Absorption correction: multi-scan(SORTAV; Blessing, 1995)	k = −9→8
Tmin = 0.057, Tmax = 0.122	l = −19→19
13121 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.045	H-atom parameters constrained
wR(F2) = 0.111	w = 1/[σ2(Fo2) + (0.0587P)2] where P = (Fo2 + 2Fc2)/3
S = 0.99	(Δ/σ)max = 0.001
4862 reflections	Δρmax = 1.33 e Å−3
238 parameters	Δρmin = −1.34 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Br1	0.27614 (3)	0.65858 (8)	0.41094 (4)	0.02811 (17)
Br2	0.42084 (3)	0.88707 (8)	0.48485 (5)	0.03059 (17)
Br3	0.56522 (3)	0.70567 (8)	0.63052 (4)	0.02834 (17)
Br4	0.55454 (3)	0.31103 (9)	0.72840 (4)	0.03124 (17)
Br5	0.28644 (3)	0.57820 (9)	0.70187 (4)	0.03205 (17)
Br6	0.14076 (4)	0.81344 (9)	0.65538 (5)	0.03543 (19)
Br7	0.01011 (3)	0.75190 (9)	0.45738 (5)	0.03139 (17)
Br8	0.01921 (3)	0.43423 (9)	0.31278 (4)	0.03253 (18)
C1	0.1758 (3)	0.2215 (7)	0.3861 (4)	0.0219 (13)
C1A	0.1588 (4)	0.2594 (8)	0.2807 (4)	0.0288 (15)
H1AA	0.1810	0.3735	0.2731	0.043*
H1AB	0.1077	0.2685	0.2493	0.043*
H1AC	0.1770	0.1604	0.2529	0.043*
C1'	0.3483 (3)	0.3945 (7)	0.5524 (4)	0.0206 (13)
C2	0.2562 (3)	0.2027 (8)	0.4324 (4)	0.0226 (13)
H2A	0.2800	0.2652	0.3940	0.027*
H2B	0.2698	0.0733	0.4372	0.027*
C2A	0.1361 (3)	0.0495 (7)	0.3963 (5)	0.0294 (15)
H2AA	0.0853	0.0730	0.3723	0.044*
H2AB	0.1508	0.0155	0.4626	0.044*
H2AC	0.1469	−0.0495	0.3606	0.044*
C2'	0.3537 (3)	0.5593 (7)	0.5085 (4)	0.0205 (12)
C3	0.2792 (3)	0.2890 (7)	0.5320 (4)	0.0212 (13)
C3A	0.2846 (3)	0.1397 (8)	0.6056 (4)	0.0294 (15)
H3AA	0.3016	0.1929	0.6685	0.044*
H3AB	0.3175	0.0459	0.6012	0.044*
H3AC	0.2381	0.0858	0.5935	0.044*
C3'	0.4168 (3)	0.6534 (8)	0.5333 (4)	0.0240 (13)
C4	0.2098 (3)	0.5358 (8)	0.5891 (4)	0.0249 (14)
C4'	0.4786 (3)	0.5817 (7)	0.5981 (4)	0.0201 (13)
C5	0.1486 (3)	0.6364 (8)	0.5695 (4)	0.0253 (14)
C5'	0.4740 (3)	0.4165 (8)	0.6388 (4)	0.0232 (13)
C6	0.0929 (3)	0.6090 (8)	0.4852 (4)	0.0229 (13)
C6'	0.4110 (3)	0.3272 (7)	0.6172 (4)	0.0208 (13)
H6'A	0.4099	0.2153	0.6474	0.025*
C7	0.0975 (3)	0.4758 (8)	0.4235 (4)	0.0232 (13)
C8	0.1586 (3)	0.3757 (8)	0.4420 (4)	0.0244 (13)
C9	0.2156 (3)	0.4084 (7)	0.5251 (4)	0.0222 (13)

	U11	U22	U33	U12	U13	U23
Br1	0.0233 (3)	0.0283 (3)	0.0269 (3)	−0.0021 (3)	0.0014 (3)	0.0100 (2)
Br2	0.0284 (4)	0.0269 (3)	0.0339 (4)	−0.0043 (3)	0.0076 (3)	0.0071 (3)
Br3	0.0214 (3)	0.0361 (4)	0.0255 (4)	−0.0062 (3)	0.0058 (3)	0.0005 (3)
Br4	0.0226 (3)	0.0402 (4)	0.0257 (4)	0.0027 (3)	0.0019 (3)	0.0090 (3)
Br5	0.0270 (4)	0.0470 (4)	0.0193 (3)	−0.0080 (3)	0.0046 (3)	−0.0090 (3)
Br6	0.0361 (4)	0.0397 (4)	0.0333 (4)	−0.0052 (3)	0.0155 (3)	−0.0145 (3)
Br7	0.0281 (4)	0.0332 (4)	0.0333 (4)	0.0045 (3)	0.0112 (3)	0.0007 (3)
Br8	0.0250 (4)	0.0405 (4)	0.0239 (4)	0.0027 (3)	−0.0018 (3)	−0.0040 (3)
C1	0.021 (3)	0.026 (3)	0.018 (3)	0.000 (2)	0.005 (3)	0.000 (2)
C1A	0.035 (4)	0.033 (3)	0.016 (3)	−0.003 (3)	0.005 (3)	0.000 (2)
C1'	0.019 (3)	0.022 (3)	0.020 (3)	−0.003 (2)	0.006 (3)	−0.001 (2)
C2	0.022 (3)	0.023 (3)	0.020 (3)	0.001 (2)	0.003 (3)	−0.002 (2)
C2A	0.029 (4)	0.027 (3)	0.029 (4)	−0.005 (3)	0.005 (3)	−0.005 (3)
C2'	0.022 (3)	0.024 (3)	0.015 (3)	−0.002 (2)	0.007 (2)	−0.001 (2)
C3	0.019 (3)	0.024 (3)	0.017 (3)	−0.008 (2)	0.002 (2)	0.002 (2)
C3A	0.025 (3)	0.031 (3)	0.026 (4)	−0.004 (3)	0.002 (3)	0.007 (3)
C3'	0.026 (3)	0.029 (3)	0.017 (3)	−0.002 (3)	0.007 (3)	0.002 (2)
C4	0.023 (3)	0.033 (3)	0.016 (3)	−0.015 (3)	0.004 (3)	−0.005 (2)
C4'	0.019 (3)	0.024 (3)	0.018 (3)	−0.003 (2)	0.007 (2)	−0.006 (2)
C5	0.031 (4)	0.027 (3)	0.023 (3)	−0.003 (3)	0.016 (3)	−0.005 (3)
C5'	0.018 (3)	0.030 (3)	0.020 (3)	0.006 (2)	0.005 (3)	0.001 (2)
C6	0.017 (3)	0.026 (3)	0.026 (3)	−0.002 (2)	0.008 (3)	−0.001 (2)
C6'	0.023 (3)	0.020 (3)	0.018 (3)	−0.001 (2)	0.004 (2)	0.004 (2)
C7	0.023 (3)	0.025 (3)	0.020 (3)	−0.008 (3)	0.005 (3)	0.003 (2)
C8	0.027 (3)	0.026 (3)	0.019 (3)	−0.004 (3)	0.005 (3)	0.003 (2)
C9	0.023 (3)	0.024 (3)	0.021 (3)	−0.008 (3)	0.009 (3)	0.002 (2)

Br1—C2'	1.894 (6)	C2—H2B	0.9900
Br2—C3'	1.890 (6)	C2A—H2AA	0.9800
Br3—C4'	1.886 (6)	C2A—H2AB	0.9800
Br4—C5'	1.892 (6)	C2A—H2AC	0.9800
Br5—C4	1.897 (6)	C2'—C3'	1.387 (8)
Br6—C5	1.895 (6)	C3—C9	1.533 (8)
Br7—C6	1.900 (6)	C3—C3A	1.548 (8)
Br8—C7	1.895 (6)	C3A—H3AA	0.9800
C1—C8	1.533 (8)	C3A—H3AB	0.9800
C1—C2	1.540 (8)	C3A—H3AC	0.9800
C1—C2A	1.541 (8)	C3'—C4'	1.401 (8)
C1—C1A	1.544 (8)	C4—C5	1.386 (9)
C1A—H1AA	0.9800	C4—C9	1.390 (8)
C1A—H1AB	0.9800	C4'—C5'	1.386 (8)
C1A—H1AC	0.9800	C5—C6	1.396 (8)
C1'—C6'	1.400 (8)	C5'—C6'	1.371 (8)
C1'—C2'	1.411 (8)	C6—C7	1.386 (8)
C1'—C3	1.537 (8)	C6'—H6'A	0.9500
C2—C3	1.560 (8)	C7—C8	1.384 (8)
C2—H2A	0.9900	C8—C9	1.405 (8)
C8—C1—C2	102.8 (5)	C3—C3A—H3AA	109.5
C8—C1—C2A	109.2 (5)	C3—C3A—H3AB	109.5
C2—C1—C2A	112.7 (5)	H3AA—C3A—H3AB	109.5
C8—C1—C1A	115.5 (5)	C3—C3A—H3AC	109.5
C2—C1—C1A	107.9 (5)	H3AA—C3A—H3AC	109.5
C2A—C1—C1A	108.7 (5)	H3AB—C3A—H3AC	109.5
C1—C1A—H1AA	109.5	C2'—C3'—C4'	121.0 (5)
C1—C1A—H1AB	109.5	C2'—C3'—Br2	120.8 (4)
H1AA—C1A—H1AB	109.5	C4'—C3'—Br2	118.1 (4)
C1—C1A—H1AC	109.5	C5—C4—C9	120.0 (5)
H1AA—C1A—H1AC	109.5	C5—C4—Br5	119.7 (4)
H1AB—C1A—H1AC	109.5	C9—C4—Br5	120.2 (5)
C6'—C1'—C2'	116.1 (5)	C5'—C4'—C3'	117.7 (5)
C6'—C1'—C3	120.1 (5)	C5'—C4'—Br3	120.8 (4)
C2'—C1'—C3	123.9 (5)	C3'—C4'—Br3	121.5 (4)
C1—C2—C3	108.5 (5)	C4—C5—C6	119.8 (5)
C1—C2—H2A	110.0	C4—C5—Br6	120.3 (5)
C3—C2—H2A	110.0	C6—C5—Br6	119.9 (5)
C1—C2—H2B	110.0	C6'—C5'—C4'	121.3 (5)
C3—C2—H2B	110.0	C6'—C5'—Br4	118.1 (4)
H2A—C2—H2B	108.4	C4'—C5'—Br4	120.6 (4)
C1—C2A—H2AA	109.5	C7—C6—C5	120.1 (5)
C1—C2A—H2AB	109.5	C7—C6—Br7	120.4 (4)
H2AA—C2A—H2AB	109.5	C5—C6—Br7	119.5 (4)
C1—C2A—H2AC	109.5	C5'—C6'—C1'	122.5 (5)
H2AA—C2A—H2AC	109.5	C5'—C6'—H6'A	118.7
H2AB—C2A—H2AC	109.5	C1'—C6'—H6'A	118.7
C3'—C2'—C1'	121.3 (5)	C8—C7—C6	120.6 (5)
C3'—C2'—Br1	117.0 (4)	C8—C7—Br8	120.4 (4)
C1'—C2'—Br1	121.7 (4)	C6—C7—Br8	119.0 (5)
C9—C3—C1'	114.0 (4)	C7—C8—C9	119.2 (6)
C9—C3—C3A	107.8 (5)	C7—C8—C1	130.1 (5)
C1'—C3—C3A	112.7 (5)	C9—C8—C1	110.7 (5)
C9—C3—C2	102.1 (4)	C4—C9—C8	120.2 (6)
C1'—C3—C2	110.2 (5)	C4—C9—C3	128.0 (5)
C3A—C3—C2	109.5 (5)	C8—C9—C3	111.8 (5)