μ-1,2-Bis(diethyl-phosphino)ethane-κP:P'-bis-{[1,2-bis-(diethyl-phosphino)ethane-κP,P']trichloridonitrosyl-tungsten(II)}.

The title binuclear compound, [W(2)Cl(6)(NO)(2)(C(10)H(22)P(2))(3)], contains two W atoms which are bridged by a bis-(diethyl-phosphino)-ethane (depe) ligand. The seven-coord-inated tungsten(II) centres display distorted penta-gonal-bipyramidal geometries with trans nitrosyl and chloride ligands. The title mol-ecule lies on a crystallographic inversion centre. The ethane group of the non-bridging depe ligand is positionally disordered, with site-occupancy factors of 0.63 and 0.37. In the crystal structure, the binuclear mol-ecules are linked by weak inter-molecular C-H⋯O and C-H⋯Cl inter-actions. In addition, weak intra-molecular C-H⋯Cl inter-actions are also present.

Related literature

For related literature, see: Avramović et al. (2008 ▶); Bencze & Kohàn (1982 ▶); Campbell et al. (1985 ▶); Carmona et al. (1989 ▶); Desiraju & Steiner (1999 ▶); Han & Coucouvanis (2002 ▶); Hunter & Legzdins (1984 ▶); Landau et al. (1999 ▶); Zeng et al. (1994 ▶).

Experimental

Crystal data

[W2Cl6(NO)2(C10H22P2)3]

M = 1259.10

Orthorhombic,

a = 12.6406 (14) Å

b = 17.6485 (14) Å

c = 20.5243 (17) Å

V = 4578.7 (7) Å3

Z = 4

Mo Kα radiation

μ = 5.61 mm−1

T = 183 (2) K

0.26 × 0.20 × 0.15 mm

Data collection

Stoe IPDS diffractometer

Absorption correction: numerical (Coppens et al., 1965 ▶) T min = 0.329, T max = 0.499

52250 measured reflections

3982 independent reflections

3026 reflections with I > 2σ(I)

R int = 0.079

Refinement

R[F 2 > 2σ(F 2)] = 0.024

wR(F 2) = 0.056

S = 0.84

3982 reflections

224 parameters

1 restraint

H-atom parameters constrained

Δρmax = 1.04 e Å−3

Δρmin = −1.27 e Å−3

Data collection: IPDS Software (Stoe & Cie, 1999 ▶); cell refinement: IPDS Software; data reduction: X-RED (Stoe & Cie, 1999 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶), SHELXL97 and PLATON (Spek, 2003 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808001141/su2041sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808001141/su2041Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[W2Cl6(NO)2(C10H22P2)3]	F000 = 2488
Mr = 1259.10	Dx = 1.827 Mg m−3
Orthorhombic, Pbca	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 7997 reflections
a = 12.6406 (14) Å	θ = 2.8–30.4º
b = 17.6485 (14) Å	µ = 5.61 mm−1
c = 20.5243 (17) Å	T = 183 (2) K
V = 4578.7 (7) Å3	Block, yellow
Z = 4	0.26 × 0.20 × 0.15 mm

Stoe IPDS diffractometer	3982 independent reflections
Radiation source: fine-focus sealed tube	3026 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.079
T = 183(2) K	θmax = 25.0º
φ oscillation scan	θmin = 2.8º
Absorption correction: numerical(Coppens et al., 1965)	h = −15→15
Tmin = 0.329, Tmax = 0.499	k = −20→20
52250 measured reflections	l = −24→24

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.024	H-atom parameters constrained
wR(F2) = 0.056	w = 1/[σ^2^(Fo^2^) + (0.0357P)^2^] where P = (Fo^2^ + 2Fc^2^)/3
S = 0.85	(Δ/σ)max = 0.001
3982 reflections	Δρmax = 1.04 e Å−3
224 parameters	Δρmin = −1.27 e Å−3
1 restraint	Extinction correction: none
Primary atom site location: structure-invariant direct methods

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > σ(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
W1	0.826046 (13)	0.388044 (11)	0.379416 (7)	0.01301 (6)
Cl1	0.77419 (9)	0.50925 (7)	0.43099 (5)	0.0229 (3)
Cl2	0.95733 (9)	0.33344 (8)	0.30362 (5)	0.0232 (3)
Cl3	0.76818 (10)	0.45607 (8)	0.27925 (5)	0.0261 (3)
P1	0.75410 (11)	0.26356 (8)	0.33323 (6)	0.0221 (3)
P2	0.62919 (11)	0.38137 (9)	0.40971 (8)	0.0319 (3)
P3	0.99811 (9)	0.46776 (7)	0.39288 (5)	0.0141 (3)
N1	0.8622 (3)	0.3381 (2)	0.45154 (17)	0.0180 (9)
O1	0.8860 (3)	0.3047 (2)	0.50083 (16)	0.0282 (9)
C1	0.6454 (7)	0.2268 (5)	0.3833 (5)	0.0341 (16)	0.631 (8)
H1A	0.6141	0.1827	0.3627	0.041*	0.631 (8)
H1B	0.6716	0.2120	0.4259	0.041*	0.631 (8)
C2	0.5642 (6)	0.2887 (5)	0.3901 (5)	0.0341 (16)	0.631 (8)
H2A	0.5147	0.2756	0.4244	0.041*	0.631 (8)
H2B	0.5248	0.2934	0.3497	0.041*	0.631 (8)
C3	0.6069 (13)	0.2531 (10)	0.3577 (7)	0.0341 (16)	0.369 (8)
H3A	0.5619	0.2840	0.3301	0.041*	0.369 (8)
H3B	0.5842	0.2007	0.3547	0.041*	0.369 (8)
C4	0.6042 (13)	0.2805 (9)	0.4274 (7)	0.0341 (16)	0.369 (8)
H4A	0.6597	0.2580	0.4538	0.041*	0.369 (8)
H4B	0.5360	0.2723	0.4478	0.041*	0.369 (8)
C5	0.8399 (6)	0.1786 (4)	0.3396 (3)	0.0505 (18)
H5A	0.7963	0.1345	0.3313	0.061*
H5B	0.8917	0.1813	0.3048	0.061*
C6	0.8966 (6)	0.1655 (4)	0.4000 (4)	0.072 (3)
H6A	0.9530	0.2016	0.4040	0.107*
H6B	0.9255	0.1152	0.3999	0.107*
H6C	0.8489	0.1709	0.4361	0.107*
C7	0.7194 (6)	0.2647 (3)	0.2484 (3)	0.0408 (15)
H7A	0.6749	0.3085	0.2405	0.049*
H7B	0.7837	0.2714	0.2232	0.049*
C8	0.6617 (5)	0.1942 (4)	0.2226 (3)	0.0484 (18)
H8A	0.7019	0.1497	0.2332	0.073*
H8B	0.6542	0.1980	0.1762	0.073*
H8C	0.5930	0.1909	0.2423	0.073*
C9	0.5410 (4)	0.4353 (5)	0.3574 (3)	0.051 (2)
H9A	0.5584	0.4886	0.3613	0.062*
H9B	0.5535	0.4205	0.3126	0.062*
C10	0.4233 (5)	0.4248 (7)	0.3728 (3)	0.099 (4)
H10A	0.3817	0.4455	0.3380	0.148*
H10B	0.4065	0.4504	0.4127	0.148*
H10C	0.4080	0.3718	0.3773	0.148*
C11	0.5917 (5)	0.4121 (4)	0.4913 (3)	0.0462 (19)
H11A	0.5940	0.4670	0.4927	0.055*
H11B	0.5192	0.3968	0.4992	0.055*
C12	0.6603 (6)	0.3814 (6)	0.5455 (3)	0.082 (3)
H12A	0.6658	0.3273	0.5415	0.123*
H12B	0.6291	0.3938	0.5868	0.123*
H12C	0.7295	0.4035	0.5428	0.123*
C13	1.0135 (4)	0.5223 (3)	0.46896 (19)	0.0157 (10)
H13A	1.0860	0.5398	0.4720	0.019*
H13B	0.9682	0.5666	0.4668	0.019*
C14	1.1275 (4)	0.4204 (3)	0.3871 (2)	0.0207 (10)
H14A	1.1397	0.4068	0.3419	0.025*
H14B	1.1818	0.4565	0.3994	0.025*
C15	1.1407 (4)	0.3499 (3)	0.4285 (3)	0.0306 (13)
H15A	1.1336	0.3630	0.4737	0.046*
H15B	1.2094	0.3285	0.4211	0.046*
H15C	1.0874	0.3135	0.4170	0.046*
C16	1.0053 (4)	0.5396 (3)	0.3298 (2)	0.0239 (12)
H16A	1.0112	0.5143	0.2880	0.029*
H16B	0.9390	0.5674	0.3297	0.029*
C17	1.0947 (4)	0.5963 (3)	0.3352 (3)	0.0340 (14)
H17A	1.0875	0.6246	0.3749	0.051*
H17B	1.0923	0.6305	0.2988	0.051*
H17C	1.1612	0.5700	0.3352	0.051*

	U11	U22	U33	U12	U13	U23
W1	0.01297 (9)	0.01534 (10)	0.01072 (9)	0.00073 (8)	0.00014 (7)	0.00121 (8)
Cl1	0.0221 (6)	0.0214 (7)	0.0251 (6)	0.0079 (5)	−0.0026 (5)	−0.0062 (5)
Cl2	0.0198 (6)	0.0291 (7)	0.0206 (6)	0.0006 (5)	0.0059 (5)	−0.0074 (5)
Cl3	0.0311 (7)	0.0298 (8)	0.0174 (5)	0.0003 (6)	−0.0063 (5)	0.0073 (5)
P1	0.0230 (7)	0.0242 (8)	0.0190 (6)	−0.0073 (6)	0.0008 (5)	−0.0066 (5)
P2	0.0183 (6)	0.0265 (8)	0.0510 (9)	−0.0004 (7)	0.0133 (6)	−0.0013 (7)
P3	0.0145 (6)	0.0166 (6)	0.0113 (5)	−0.0011 (5)	0.0025 (4)	0.0009 (4)
N1	0.0156 (19)	0.025 (2)	0.0137 (18)	−0.0019 (18)	−0.0001 (15)	0.0010 (18)
O1	0.033 (2)	0.028 (2)	0.0232 (18)	0.0046 (17)	−0.0024 (16)	0.0112 (16)
C1	0.022 (4)	0.026 (4)	0.055 (5)	−0.006 (3)	0.011 (3)	0.000 (3)
C2	0.022 (4)	0.026 (4)	0.055 (5)	−0.006 (3)	0.011 (3)	0.000 (3)
C3	0.022 (4)	0.026 (4)	0.055 (5)	−0.006 (3)	0.011 (3)	0.000 (3)
C4	0.022 (4)	0.026 (4)	0.055 (5)	−0.006 (3)	0.011 (3)	0.000 (3)
C5	0.073 (5)	0.026 (4)	0.052 (4)	−0.012 (3)	−0.027 (4)	0.003 (3)
C6	0.068 (5)	0.020 (4)	0.127 (7)	0.004 (4)	−0.052 (5)	0.004 (4)
C7	0.065 (4)	0.026 (3)	0.032 (3)	−0.002 (3)	−0.029 (3)	−0.005 (3)
C8	0.063 (4)	0.035 (4)	0.047 (3)	0.010 (3)	−0.036 (3)	−0.019 (3)
C9	0.023 (3)	0.089 (6)	0.042 (3)	0.013 (3)	−0.013 (3)	−0.030 (4)
C10	0.015 (3)	0.233 (13)	0.049 (4)	0.007 (5)	−0.004 (3)	−0.047 (6)
C11	0.026 (3)	0.076 (6)	0.037 (3)	0.017 (3)	0.017 (3)	0.019 (3)
C12	0.045 (4)	0.143 (9)	0.058 (4)	0.040 (5)	0.025 (4)	0.062 (5)
C13	0.019 (2)	0.017 (3)	0.011 (2)	−0.006 (2)	0.0019 (18)	0.0006 (19)
C14	0.016 (2)	0.022 (3)	0.024 (2)	0.002 (2)	0.004 (2)	−0.002 (2)
C15	0.028 (3)	0.030 (3)	0.034 (3)	0.013 (2)	−0.001 (2)	0.000 (3)
C16	0.032 (3)	0.024 (3)	0.017 (2)	−0.004 (2)	0.004 (2)	0.006 (2)
C17	0.034 (3)	0.032 (4)	0.036 (3)	−0.008 (3)	0.003 (2)	0.017 (3)

W1—P1	2.5598 (13)	C6—H6C	0.9600
W1—P2	2.5675 (14)	C7—C8	1.536 (8)
W1—P3	2.6051 (12)	C7—H7A	0.9700
W1—Cl1	2.4750 (12)	C7—H7B	0.9700
W1—Cl2	2.4703 (11)	C8—H8A	0.9600
W1—Cl3	2.4905 (11)	C8—H8B	0.9600
W1—N1	1.783 (4)	C8—H8C	0.9600
P1—C7	1.796 (5)	C9—C10	1.531 (8)
P1—C1	1.834 (8)	C9—H9A	0.9700
P1—C5	1.855 (7)	C9—H9B	0.9700
P1—C3	1.936 (15)	C10—H10A	0.9600
P2—C9	1.817 (7)	C10—H10B	0.9600
P2—C11	1.822 (6)	C10—H10C	0.9600
P2—C4	1.844 (16)	C11—C12	1.512 (8)
P2—C2	1.874 (9)	C11—H11A	0.9700
P3—C16	1.815 (5)	C11—H11B	0.9700
P3—C14	1.840 (5)	C12—H12A	0.9600
P3—C13	1.844 (4)	C12—H12B	0.9600
N1—O1	1.208 (5)	C12—H12C	0.9600
C1—C2	1.506 (10)	C13—C13i	1.535 (8)
C1—H1A	0.9700	C13—H13A	0.9700
C1—H1B	0.9700	C13—H13B	0.9700
C2—H2A	0.9700	C14—C15	1.516 (7)
C2—H2B	0.9700	C14—H14A	0.9700
C3—C4	1.511 (10)	C14—H14B	0.9700
C3—H3A	0.9700	C15—H15A	0.9600
C3—H3B	0.9700	C15—H15B	0.9600
C4—H4A	0.9700	C15—H15C	0.9600
C4—H4B	0.9700	C16—C17	1.514 (7)
C5—C6	1.450 (9)	C16—H16A	0.9700
C5—H5A	0.9700	C16—H16B	0.9700
C5—H5B	0.9700	C17—H17A	0.9600
C6—H6A	0.9600	C17—H17B	0.9600
C6—H6B	0.9600	C17—H17C	0.9600
N1—W1—Cl1	98.06 (14)	P1—C5—H5B	107.7
N1—W1—Cl2	99.08 (13)	H5A—C5—H5B	107.1
N1—W1—Cl3	177.72 (13)	C5—C6—H6A	109.5
Cl1—W1—Cl2	141.66 (4)	C5—C6—H6B	109.5
Cl2—W1—Cl3	82.27 (4)	H6A—C6—H6B	109.5
Cl1—W1—Cl3	81.87 (4)	C5—C6—H6C	109.5
N1—W1—P1	88.51 (14)	H6A—C6—H6C	109.5
Cl1—W1—P1	143.71 (4)	H6B—C6—H6C	109.5
Cl1—W1—P2	71.30 (5)	C8—C7—P1	116.2 (4)
Cl1—W1—P3	73.09 (4)	C8—C7—H7A	108.2
Cl2—W1—P1	70.77 (4)	P1—C7—H7A	108.2
Cl2—W1—P3	73.54 (4)	C8—C7—H7B	108.2
Cl3—W1—P1	90.21 (4)	P1—C7—H7B	108.2
N1—W1—P2	91.41 (13)	H7A—C7—H7B	107.4
Cl2—W1—P2	141.78 (5)	C7—C8—H8A	109.5
Cl3—W1—P2	86.41 (5)	C7—C8—H8B	109.5
P1—W1—P2	72.90 (5)	H8A—C8—H8B	109.5
N1—W1—P3	88.00 (13)	C7—C8—H8C	109.5
Cl3—W1—P3	94.16 (4)	H8A—C8—H8C	109.5
P1—W1—P3	143.07 (4)	H8B—C8—H8C	109.5
P2—W1—P3	143.92 (4)	C10—C9—P2	114.3 (6)
C7—P1—C1	111.4 (4)	C10—C9—H9A	108.7
C7—P1—C5	102.7 (3)	P2—C9—H9A	108.7
C1—P1—C5	96.5 (4)	C10—C9—H9B	108.7
C7—P1—C3	91.0 (5)	P2—C9—H9B	108.7
C5—P1—C3	117.8 (6)	H9A—C9—H9B	107.6
C7—P1—W1	115.9 (2)	C9—C10—H10A	109.5
C1—P1—W1	111.2 (3)	C9—C10—H10B	109.5
C5—P1—W1	117.3 (2)	H10A—C10—H10B	109.5
C3—P1—W1	109.1 (5)	C9—C10—H10C	109.5
C9—P2—C11	103.1 (3)	H10A—C10—H10C	109.5
C9—P2—C4	121.1 (6)	H10B—C10—H10C	109.5
C11—P2—C4	93.5 (5)	C12—C11—P2	114.9 (5)
C9—P2—C2	93.5 (4)	C12—C11—H11A	108.5
C11—P2—C2	110.1 (4)	P2—C11—H11A	108.5
C9—P2—W1	115.3 (2)	C12—C11—H11B	108.5
C11—P2—W1	117.4 (2)	P2—C11—H11B	108.5
C4—P2—W1	104.9 (5)	H11A—C11—H11B	107.5
C2—P2—W1	114.4 (3)	C11—C12—H12A	109.5
C16—P3—C14	103.1 (2)	C11—C12—H12B	109.5
C16—P3—C13	103.6 (2)	H12A—C12—H12B	109.5
C14—P3—C13	101.4 (2)	C11—C12—H12C	109.5
C16—P3—W1	110.08 (17)	H12A—C12—H12C	109.5
C14—P3—W1	119.35 (17)	H12B—C12—H12C	109.5
C13—P3—W1	117.34 (15)	C13i—C13—P3	114.4 (4)
O1—N1—W1	179.3 (4)	C13i—C13—H13A	108.7
C2—C1—P1	107.8 (7)	P3—C13—H13A	108.7
C2—C1—H1A	110.1	C13i—C13—H13B	108.7
P1—C1—H1A	110.1	P3—C13—H13B	108.7
C2—C1—H1B	110.1	H13A—C13—H13B	107.6
P1—C1—H1B	110.1	C15—C14—P3	115.7 (3)
H1A—C1—H1B	108.5	C15—C14—H14A	108.3
C1—C2—P2	110.7 (6)	P3—C14—H14A	108.3
C1—C2—H2A	109.5	C15—C14—H14B	108.3
P2—C2—H2A	109.5	P3—C14—H14B	108.3
C1—C2—H2B	109.5	H14A—C14—H14B	107.4
P2—C2—H2B	109.5	C14—C15—H15A	109.5
H2A—C2—H2B	108.1	C14—C15—H15B	109.5
C4—C3—P1	103.7 (10)	H15A—C15—H15B	109.5
C4—C3—H3A	111.0	C14—C15—H15C	109.5
P1—C3—H3A	111.0	H15A—C15—H15C	109.5
C4—C3—H3B	111.0	H15B—C15—H15C	109.5
P1—C3—H3B	111.0	C17—C16—P3	116.6 (4)
H3A—C3—H3B	109.0	C17—C16—H16A	108.2
C3—C4—P2	96.8 (11)	P3—C16—H16A	108.2
C3—C4—H4A	112.4	C17—C16—H16B	108.2
P2—C4—H4A	112.4	P3—C16—H16B	108.2
C3—C4—H4B	112.4	H16A—C16—H16B	107.3
P2—C4—H4B	112.4	C16—C17—H17A	109.5
H4A—C4—H4B	110.0	C16—C17—H17B	109.5
C6—C5—P1	118.6 (5)	H17A—C17—H17B	109.5
C6—C5—H5A	107.7	C16—C17—H17C	109.5
P1—C5—H5A	107.7	H17A—C17—H17C	109.5
C6—C5—H5B	107.7	H17B—C17—H17C	109.5
N1—W1—P1—C7	−169.6 (3)	Cl2—W1—P3—C14	−36.06 (18)
Cl2—W1—P1—C7	−69.4 (3)	Cl1—W1—P3—C14	163.07 (18)
Cl1—W1—P1—C7	88.8 (3)	Cl3—W1—P3—C14	−116.74 (18)
Cl3—W1—P1—C7	12.3 (3)	P1—W1—P3—C14	−20.84 (19)
P2—W1—P1—C7	98.5 (3)	P2—W1—P3—C14	153.66 (18)
P3—W1—P1—C7	−84.9 (3)	N1—W1—P3—C13	−59.1 (2)
N1—W1—P1—C1	61.9 (4)	Cl2—W1—P3—C13	−159.16 (18)
Cl2—W1—P1—C1	162.1 (4)	Cl1—W1—P3—C13	39.97 (17)
Cl1—W1—P1—C1	−39.7 (4)	Cl3—W1—P3—C13	120.16 (18)
Cl3—W1—P1—C1	−116.2 (4)	P1—W1—P3—C13	−143.94 (18)
P2—W1—P1—C1	−30.0 (4)	P2—W1—P3—C13	30.6 (2)
P3—W1—P1—C1	146.6 (4)	C7—P1—C1—C2	−77.2 (8)
N1—W1—P1—C5	−47.8 (3)	C5—P1—C1—C2	176.4 (7)
Cl2—W1—P1—C5	52.4 (3)	C3—P1—C1—C2	−36.6 (10)
Cl1—W1—P1—C5	−149.4 (3)	W1—P1—C1—C2	53.7 (8)
Cl3—W1—P1—C5	134.1 (3)	P1—C1—C2—P2	−45.4 (9)
P2—W1—P1—C5	−139.7 (3)	C9—P2—C2—C1	140.7 (8)
P3—W1—P1—C5	36.9 (3)	C11—P2—C2—C1	−113.9 (7)
N1—W1—P1—C3	89.5 (5)	C4—P2—C2—C1	−55.6 (10)
Cl2—W1—P1—C3	−170.3 (5)	W1—P2—C2—C1	20.8 (9)
Cl1—W1—P1—C3	−12.1 (5)	C7—P1—C3—C4	−158.7 (11)
Cl3—W1—P1—C3	−88.6 (5)	C1—P1—C3—C4	58.6 (11)
P2—W1—P1—C3	−2.4 (5)	C5—P1—C3—C4	96.3 (12)
P3—W1—P1—C3	174.2 (5)	W1—P1—C3—C4	−40.8 (13)
N1—W1—P2—C9	172.8 (3)	P1—C3—C4—P2	69.6 (11)
Cl2—W1—P2—C9	−80.6 (3)	C9—P2—C4—C3	58.9 (12)
Cl1—W1—P2—C9	74.7 (3)	C11—P2—C4—C3	166.5 (10)
Cl3—W1—P2—C9	−7.9 (3)	C2—P2—C4—C3	39.8 (8)
P1—W1—P2—C9	−99.2 (3)	W1—P2—C4—C3	−73.8 (11)
P3—W1—P2—C9	84.2 (3)	C7—P1—C5—C6	170.9 (6)
N1—W1—P2—C11	50.8 (3)	C1—P1—C5—C6	−75.4 (7)
Cl2—W1—P2—C11	157.5 (3)	C3—P1—C5—C6	−91.1 (8)
Cl1—W1—P2—C11	−47.2 (3)	W1—P1—C5—C6	42.5 (7)
Cl3—W1—P2—C11	−129.8 (3)	C1—P1—C7—C8	−43.2 (6)
P1—W1—P2—C11	138.8 (3)	C5—P1—C7—C8	59.1 (6)
P3—W1—P2—C11	−37.7 (3)	C3—P1—C7—C8	−59.7 (7)
N1—W1—P2—C4	−51.3 (5)	W1—P1—C7—C8	−171.6 (4)
Cl2—W1—P2—C4	55.3 (5)	C11—P2—C9—C10	−55.8 (6)
Cl1—W1—P2—C4	−149.4 (5)	C4—P2—C9—C10	46.6 (8)
Cl3—W1—P2—C4	128.0 (5)	C2—P2—C9—C10	55.7 (6)
P1—W1—P2—C4	36.7 (5)	W1—P2—C9—C10	174.8 (5)
P3—W1—P2—C4	−139.9 (5)	C9—P2—C11—C12	−174.5 (6)
N1—W1—P2—C2	−80.5 (4)	C4—P2—C11—C12	62.4 (8)
Cl2—W1—P2—C2	26.2 (4)	C2—P2—C11—C12	86.8 (7)
Cl1—W1—P2—C2	−178.5 (4)	W1—P2—C11—C12	−46.4 (7)
Cl3—W1—P2—C2	98.9 (4)	C16—P3—C13—C13i	167.4 (5)
P1—W1—P2—C2	7.5 (4)	C14—P3—C13—C13i	−85.9 (5)
P3—W1—P2—C2	−169.0 (4)	W1—P3—C13—C13i	45.9 (5)
N1—W1—P3—C16	−177.1 (2)	C16—P3—C14—C15	−172.3 (4)
Cl2—W1—P3—C16	82.81 (18)	C13—P3—C14—C15	80.6 (4)
Cl1—W1—P3—C16	−78.06 (18)	W1—P3—C14—C15	−50.0 (4)
Cl3—W1—P3—C16	2.13 (18)	C14—P3—C16—C17	−58.1 (5)
P1—W1—P3—C16	98.03 (19)	C13—P3—C16—C17	47.3 (5)
P2—W1—P3—C16	−87.5 (2)	W1—P3—C16—C17	173.5 (4)
N1—W1—P3—C14	64.0 (2)

D—H···A	D—H	H···A	D···A	D—H···A
C5—H5B···Cl2	0.97	2.81	3.196 (7)	105
C11—H11A···Cl1	0.97	2.71	3.129 (7)	107
C13—H13B···Cl1	0.97	2.75	3.132 (5)	104
C14—H14A···Cl2	0.97	2.76	3.150 (5)	105
C13—H13A···Cl1i	0.97	2.80	3.425 (5)	123
C10—H10A···Cl3ii	0.96	2.81	3.726 (7)	161
C2—H2A···O1iii	0.97	2.65	3.579 (10)	161
C4—H4B···O1iii	0.97	2.56	3.470 (15)	156

W1—P1	2.5598 (13)
W1—P2	2.5675 (14)
W1—P3	2.6051 (12)
W1—Cl1	2.4750 (12)
W1—Cl2	2.4703 (11)
W1—Cl3	2.4905 (11)
W1—N1	1.783 (4)

N1—W1—Cl1	98.06 (14)
N1—W1—Cl2	99.08 (13)
N1—W1—Cl3	177.72 (13)
Cl1—W1—Cl2	141.66 (4)
Cl2—W1—Cl3	82.27 (4)
Cl1—W1—Cl3	81.87 (4)
Cl1—W1—P2	71.30 (5)
Cl1—W1—P3	73.09 (4)
Cl2—W1—P1	70.77 (4)
Cl2—W1—P3	73.54 (4)
Cl3—W1—P1	90.21 (4)
P1—W1—P2	72.90 (5)

Symmetry code: (i) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C5—H5B⋯Cl2	0.97	2.81	3.196 (7)	105
C11—H11A⋯Cl1	0.97	2.71	3.129 (7)	107
C13—H13B⋯Cl1	0.97	2.75	3.132 (5)	104
C14—H14A⋯Cl2	0.97	2.76	3.150 (5)	105
C13—H13A⋯Cl1i	0.97	2.80	3.425 (5)	123
C10—H10A⋯Cl3ii	0.96	2.81	3.726 (7)	161
C2—H2A⋯O1iii	0.97	2.65	3.579 (10)	161
C4—H4B⋯O1iii	0.97	2.56	3.470 (15)	156

Symmetry codes: (i) ; (ii) ; (iii) .