Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(4-toluene-sulfonato-κO)silver(I)] monohydrate.

The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluene-sulfonate with diphenyl-phosphinomethane (dppm) in acetonitrile. There are two unique half-mol-ecules of the complex in the asymmetric unit, together with one water mol-ecule, which is disordered over two positions with site occupancy factors of 0.6 and 0.4. In each centrosymmetric neutral dimeric mol-ecule, two Ag atoms are bridged by a pair of dppm ligands to give an eight-membered Ag(2)P(4)C(2) ring with a distorted AgOP(2) trigonal-planar environment. The Ag-Ag distances of 2.9215 (9) and 3.027 (1) Å indicate a direct bonding inter-action.

Related literature

For similar structures, see: Chen et al. (2004 ▶); Effendy et al. (2005 ▶); Fournier, Decken & Harvey (2004 ▶); Fournier, Lebrun et al. (2004 ▶); Hong et al. (1997 ▶); Youm et al. (2000 ▶).

Experimental

Crystal data

[Ag2(C7H7O3S)2(C25H22P2)2]·H2O

M = 1344.86

Triclinic,

a = 11.239 (2) Å

b = 11.802 (2) Å

c = 23.363 (5) Å

α = 103.86 (3)°

β = 93.79 (3)°

γ = 91.95 (3)°

V = 2998.1 (10) Å3

Z = 2

Mo Kα radiation

μ = 0.88 mm−1

T = 293 (2) K

0.36 × 0.31 × 0.28 mm

Data collection

Rigaku Weissenberg IP diffractometer

Absorption correction: none

27870 measured reflections

13424 independent reflections

11383 reflections with I > 2σ(I)

R int = 0.029

Refinement

R[F 2 > 2σ(F 2)] = 0.042

wR(F 2) = 0.131

S = 1.05

13424 reflections

721 parameters

H-atom parameters constrained

Δρmax = 0.71 e Å−3

Δρmin = −1.86 e Å−3

Data collection: CrystalClear (Rigaku, 2000 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997 ▶); molecular graphics: SHELXTL/PC (Sheldrick, 1993 ▶); software used to prepare material for publication: SHELXL97.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807067311/cf2162sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807067311/cf2162Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag2(C7H7O3S)2(C25H22P2)2]·H2O	Z = 2
Mr = 1344.86	F000 = 1372
Triclinic, P1	Dx = 1.490 Mg m−3
a = 11.239 (2) Å	Mo Kα radiation λ = 0.71073 Å
b = 11.802 (2) Å	Cell parameters from 27870 reflections
c = 23.363 (5) Å	θ = 0.9–27.5º
α = 103.86 (3)º	µ = 0.88 mm−1
β = 93.79 (3)º	T = 293 (2) K
γ = 91.95 (3)º	Prism, colorless
V = 2998.1 (10) Å3	0.36 × 0.31 × 0.28 mm

Rigaku Weissenberg IP diffractometer	11383 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.029
Monochromator: graphite	θmax = 27.5º
T = 293(2) K	θmin = 0.9º
ω scans	h = −14→14
Absorption correction: none	k = 0→15
27870 measured reflections	l = −30→29
13424 independent reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.042	H-atom parameters constrained
wR(F2) = 0.131	w = 1/[σ2(Fo2) + (0.0589P)2 + 6.0201P] where P = (Fo2 + 2Fc2)/3
S = 1.05	(Δ/σ)max = 0.001
13424 reflections	Δρmax = 0.71 e Å−3
721 parameters	Δρmin = −1.86 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ag1	0.11622 (2)	0.48402 (2)	0.475474 (11)	0.03703 (8)
Ag2	0.52075 (3)	−0.12811 (4)	−0.005498 (15)	0.05974 (11)
S1	0.17891 (10)	0.82300 (8)	0.53039 (5)	0.0482 (2)
S2	0.32006 (9)	−0.14579 (10)	0.12284 (4)	0.0468 (2)
P1	0.20944 (7)	0.48870 (7)	0.57271 (4)	0.02923 (16)
P2	0.02266 (7)	0.42514 (8)	0.37653 (4)	0.03273 (18)
P3	0.33812 (8)	−0.17322 (7)	−0.06908 (4)	0.03266 (17)
P4	0.72861 (7)	−0.07571 (7)	0.02262 (4)	0.03080 (17)
O1	0.2033 (3)	−0.1768 (3)	0.09323 (16)	0.0647 (9)
O2	0.3227 (4)	−0.0401 (3)	0.16896 (17)	0.0817 (11)
O3	0.4092 (3)	−0.1455 (4)	0.08136 (16)	0.0742 (11)
O4	0.2356 (3)	0.8514 (3)	0.58977 (13)	0.0560 (7)
O5	0.0663 (3)	0.8772 (3)	0.52626 (17)	0.0671 (9)
O6	0.1714 (4)	0.6974 (3)	0.50571 (16)	0.0792 (12)
O7	0.5206 (6)	−0.4429 (5)	−0.0011 (4)	0.088 (2)	0.60
O7'	0.5506 (10)	−0.3613 (10)	−0.0078 (6)	0.089 (3)	0.40
C2	0.3684 (3)	0.5306 (3)	0.58370 (14)	0.0331 (7)
C6	0.7859 (3)	−0.1123 (3)	0.08989 (15)	0.0333 (7)
C7	0.0743 (3)	0.2859 (3)	0.33560 (15)	0.0378 (7)
C8	0.3349 (3)	−0.1564 (3)	−0.14428 (15)	0.0376 (7)
C9	0.2753 (3)	−0.3222 (3)	−0.07880 (17)	0.0393 (7)
C12	0.0512 (3)	0.5273 (3)	0.33133 (16)	0.0383 (7)
C13	0.8185 (3)	−0.1551 (3)	−0.03427 (15)	0.0357 (7)
C14	0.1999 (3)	0.3577 (3)	0.60008 (16)	0.0367 (7)
C15	0.2273 (4)	−0.1704 (4)	−0.17894 (17)	0.0478 (9)
H15A	0.1569	−0.1888	−0.1636	0.057*
C17	0.8550 (4)	−0.1080 (4)	−0.07943 (17)	0.0467 (9)
H17A	0.8406	−0.0307	−0.0791	0.056*
C19	0.7052 (3)	−0.1347 (3)	0.12909 (16)	0.0400 (8)
H19A	0.6235	−0.1371	0.1193	0.048*
C20	0.7485 (4)	−0.1536 (4)	0.18303 (18)	0.0496 (9)
H20A	0.6952	−0.1674	0.2097	0.060*
C21	0.3563 (4)	−0.2598 (4)	0.15795 (17)	0.0463 (9)
C22	0.2751 (4)	0.8784 (3)	0.48523 (18)	0.0473 (9)
C23	0.4493 (3)	0.4454 (4)	0.5664 (2)	0.0512 (10)
H23A	0.4219	0.3681	0.5512	0.061*
C24	0.1552 (4)	0.2805 (4)	0.29251 (19)	0.0538 (10)
H24A	0.1796	0.3479	0.2816	0.065*
C26	0.9490 (4)	−0.1326 (4)	0.15803 (19)	0.0517 (10)
H26A	1.0306	−0.1331	0.1676	0.062*
C27	0.9081 (3)	−0.1125 (3)	0.10436 (17)	0.0417 (8)
H27A	0.9622	−0.0992	0.0779	0.050*
C29	0.8692 (4)	−0.1519 (4)	0.19723 (18)	0.0534 (10)
H29A	0.8971	−0.1639	0.2336	0.064*
C30	0.4389 (4)	−0.1289 (4)	−0.16758 (18)	0.0478 (9)
H30A	0.5112	−0.1184	−0.1447	0.057*
C31	0.2081 (4)	−0.3538 (4)	−0.0374 (2)	0.0537 (10)
H31A	0.1895	−0.2975	−0.0044	0.064*
C32	0.0403 (4)	0.1840 (4)	0.3511 (2)	0.0542 (10)
H32A	−0.0120	0.1870	0.3806	0.065*
C33	0.0006 (4)	0.5106 (4)	0.27401 (18)	0.0517 (10)
H33A	−0.0534	0.4476	0.2583	0.062*
C38	0.4246 (4)	0.9528 (4)	0.4089 (2)	0.0553 (10)
C39	0.1301 (4)	0.6226 (4)	0.3540 (2)	0.0530 (10)
H39A	0.1643	0.6357	0.3925	0.064*
C40	0.8402 (4)	−0.2709 (4)	−0.0359 (2)	0.0565 (11)
H40A	0.8163	−0.3039	−0.0059	0.068*
C41	0.1347 (4)	0.2598 (3)	0.5671 (2)	0.0506 (9)
H41A	0.0956	0.2610	0.5309	0.061*
C42	0.9330 (5)	−0.2888 (4)	−0.1265 (2)	0.0646 (13)
H42A	0.9712	−0.3339	−0.1576	0.078*
C43	0.3292 (6)	−0.3750 (5)	0.1302 (2)	0.0782 (16)
H43A	0.2921	−0.3946	0.0921	0.094*
C45	0.4113 (3)	0.6444 (4)	0.6055 (2)	0.0571 (12)
H45A	0.3586	0.7035	0.6163	0.069*
C46	0.2370 (4)	0.9589 (5)	0.4548 (2)	0.0614 (12)
H46A	0.1614	0.9881	0.4592	0.074*
C48	0.0302 (5)	0.5871 (5)	0.2401 (2)	0.0638 (12)
H48A	−0.0040	0.5750	0.2016	0.077*
C49	0.3296 (5)	−0.1306 (4)	−0.25938 (19)	0.0649 (13)
H49A	0.3280	−0.1222	−0.2980	0.078*
C50	0.9128 (4)	−0.1759 (4)	−0.12514 (19)	0.0577 (11)
H50A	0.9380	−0.1435	−0.1551	0.069*
C51	0.2566 (4)	0.3543 (4)	0.6541 (2)	0.0566 (11)
H51A	0.2993	0.4203	0.6772	0.068*
C53	0.4351 (5)	−0.1169 (5)	−0.2258 (2)	0.0630 (12)
H53A	0.5052	−0.0994	−0.2416	0.076*
C54	0.8970 (5)	−0.3371 (4)	−0.0820 (3)	0.0697 (14)
H54A	0.9111	−0.4147	−0.0830	0.084*
C55	0.2253 (5)	−0.1568 (4)	−0.23639 (19)	0.0595 (11)
H55A	0.1533	−0.1655	−0.2594	0.071*
C56	0.1858 (5)	0.1565 (4)	0.6406 (3)	0.0690 (14)
H56A	0.1819	0.0885	0.6539	0.083*
C57	0.1992 (5)	0.1740 (5)	0.2660 (2)	0.0671 (14)
H57A	0.2545	0.1707	0.2379	0.081*
C58	0.6119 (4)	0.5862 (5)	0.5946 (2)	0.0620 (12)
H58A	0.6935	0.6051	0.5992	0.074*
C59	0.5332 (4)	0.6708 (4)	0.6112 (3)	0.0713 (15)
H59A	0.5618	0.7477	0.6266	0.086*
C60	0.1949 (6)	−0.5531 (4)	−0.0928 (3)	0.0740 (15)
H60A	0.1672	−0.6303	−0.0979	0.089*
C61	0.2631 (7)	−0.5224 (4)	−0.1333 (3)	0.092 (2)
H61A	0.2832	−0.5794	−0.1657	0.110*
C62	0.1624 (5)	0.0729 (5)	0.2808 (2)	0.0672 (14)
H62A	0.1913	0.0016	0.2621	0.081*
C64	0.3126 (5)	0.9959 (5)	0.4174 (2)	0.0660 (13)
H64A	0.2872	1.0514	0.3975	0.079*
C66	0.3889 (5)	0.8387 (4)	0.4794 (2)	0.0590 (11)
H66A	0.4163	0.7873	0.5014	0.071*
C67	0.5707 (4)	0.4744 (5)	0.5714 (2)	0.0624 (12)
H67A	0.6242	0.4168	0.5589	0.075*
C68	0.1278 (5)	0.1597 (4)	0.5881 (3)	0.0678 (13)
H68A	0.0830	0.0941	0.5661	0.081*
C70	0.1094 (5)	0.6806 (5)	0.2626 (3)	0.0705 (14)
H70A	0.1296	0.7313	0.2394	0.085*
C73	0.1676 (5)	−0.4697 (4)	−0.0447 (3)	0.0663 (13)
H73A	0.1219	−0.4903	−0.0167	0.080*
C78	0.4108 (5)	−0.2348 (5)	0.2141 (2)	0.0680 (13)
H78A	0.4303	−0.1574	0.2337	0.082*
C81	0.4107 (5)	−0.4374 (5)	0.2148 (3)	0.0704 (14)
C83	0.0827 (5)	0.0782 (4)	0.3233 (3)	0.0674 (13)
H83A	0.0573	0.0102	0.3335	0.081*
C84	0.1582 (5)	0.6988 (5)	0.3191 (3)	0.0723 (14)
H84A	0.2110	0.7628	0.3346	0.087*
C85	0.4626 (5)	0.8747 (4)	0.4412 (2)	0.0632 (12)
H85A	0.5385	0.8461	0.4372	0.076*
C87	0.3025 (6)	−0.4082 (4)	−0.1268 (2)	0.0752 (16)
H87A	0.3481	−0.3887	−0.1551	0.090*
C88	0.2498 (5)	0.2531 (5)	0.6737 (3)	0.0716 (14)
H88A	0.2891	0.2506	0.7096	0.086*
C90	0.4370 (6)	−0.3222 (6)	0.2419 (3)	0.0800 (17)
H90A	0.4736	−0.3025	0.2801	0.096*
C96	0.1402 (3)	0.5998 (3)	0.62743 (14)	0.0318 (6)
H96A	0.1589	0.6763	0.6209	0.038*
H96B	0.1735	0.5990	0.6667	0.038*
C97	0.7757 (3)	0.0787 (3)	0.03314 (15)	0.0337 (7)
H97A	0.7883	0.0948	−0.0049	0.040*
H97B	0.8507	0.0954	0.0573	0.040*
C98	0.5038 (5)	0.9900 (5)	0.3662 (2)	0.0739 (15)
H98A	0.5768	0.9500	0.3656	0.111*
H98B	0.5214	1.0728	0.3786	0.111*
H98C	0.4636	0.9709	0.3273	0.111*
C99	0.4362 (7)	−0.5352 (7)	0.2452 (4)	0.107 (2)
H99A	0.4112	−0.6090	0.2187	0.161*
H99B	0.3933	−0.5244	0.2801	0.161*
H99C	0.5203	−0.5340	0.2559	0.161*
C101	0.3570 (7)	−0.4622 (5)	0.1587 (3)	0.0879 (19)
H10A	0.3385	−0.5398	0.1391	0.105*

	U11	U22	U33	U12	U13	U23
Ag1	0.02949 (13)	0.05165 (17)	0.02728 (12)	0.00223 (10)	−0.00020 (9)	0.00493 (10)
Ag2	0.03214 (16)	0.1020 (3)	0.04636 (18)	−0.00563 (16)	−0.00490 (12)	0.02374 (18)
S1	0.0611 (6)	0.0363 (5)	0.0468 (5)	−0.0101 (4)	−0.0032 (4)	0.0132 (4)
S2	0.0446 (5)	0.0581 (6)	0.0402 (5)	0.0047 (4)	0.0103 (4)	0.0144 (4)
P1	0.0275 (4)	0.0300 (4)	0.0289 (4)	0.0025 (3)	−0.0004 (3)	0.0051 (3)
P2	0.0282 (4)	0.0415 (5)	0.0263 (4)	0.0019 (3)	0.0013 (3)	0.0040 (3)
P3	0.0328 (4)	0.0324 (4)	0.0320 (4)	0.0027 (3)	0.0011 (3)	0.0065 (3)
P4	0.0304 (4)	0.0321 (4)	0.0316 (4)	0.0038 (3)	0.0027 (3)	0.0107 (3)
O1	0.0455 (17)	0.080 (2)	0.073 (2)	0.0070 (15)	0.0001 (15)	0.0274 (18)
O2	0.116 (3)	0.062 (2)	0.061 (2)	0.013 (2)	0.005 (2)	0.0021 (17)
O3	0.0556 (19)	0.117 (3)	0.068 (2)	0.0161 (19)	0.0280 (17)	0.050 (2)
O4	0.0642 (19)	0.0592 (18)	0.0449 (15)	−0.0055 (14)	−0.0003 (14)	0.0153 (13)
O5	0.0529 (18)	0.073 (2)	0.084 (2)	−0.0070 (16)	−0.0007 (17)	0.0381 (19)
O6	0.130 (3)	0.0410 (17)	0.064 (2)	−0.0213 (19)	0.004 (2)	0.0114 (15)
O7	0.067 (4)	0.050 (3)	0.160 (7)	0.009 (3)	−0.008 (4)	0.053 (4)
O7'	0.082 (7)	0.069 (7)	0.118 (9)	0.015 (5)	−0.014 (6)	0.030 (6)
C2	0.0264 (15)	0.0412 (18)	0.0313 (15)	0.0033 (12)	0.0000 (12)	0.0085 (13)
C6	0.0345 (16)	0.0326 (16)	0.0344 (16)	0.0028 (12)	0.0027 (13)	0.0113 (13)
C7	0.0299 (16)	0.048 (2)	0.0319 (16)	0.0082 (14)	−0.0004 (13)	0.0017 (14)
C8	0.0439 (19)	0.0366 (18)	0.0310 (16)	0.0032 (14)	0.0050 (14)	0.0050 (13)
C9	0.0424 (19)	0.0316 (17)	0.0433 (19)	0.0044 (14)	−0.0026 (15)	0.0089 (14)
C12	0.0389 (18)	0.0421 (19)	0.0348 (17)	0.0054 (14)	0.0071 (14)	0.0094 (14)
C13	0.0320 (16)	0.0399 (18)	0.0337 (16)	0.0027 (13)	0.0000 (13)	0.0066 (14)
C14	0.0344 (17)	0.0363 (17)	0.0409 (18)	0.0047 (13)	0.0044 (14)	0.0112 (14)
C15	0.048 (2)	0.054 (2)	0.0384 (19)	−0.0008 (17)	−0.0033 (16)	0.0061 (17)
C17	0.054 (2)	0.046 (2)	0.042 (2)	0.0077 (17)	0.0102 (17)	0.0110 (16)
C19	0.0395 (18)	0.0420 (19)	0.0430 (19)	0.0068 (14)	0.0072 (15)	0.0174 (15)
C20	0.058 (2)	0.057 (2)	0.041 (2)	0.0102 (19)	0.0128 (18)	0.0231 (18)
C21	0.045 (2)	0.058 (2)	0.0385 (19)	0.0019 (17)	0.0085 (15)	0.0154 (17)
C22	0.062 (2)	0.0354 (19)	0.045 (2)	−0.0049 (17)	−0.0005 (18)	0.0123 (16)
C23	0.0357 (19)	0.043 (2)	0.069 (3)	0.0072 (15)	0.0046 (18)	0.0010 (19)
C24	0.048 (2)	0.065 (3)	0.047 (2)	0.0126 (19)	0.0138 (18)	0.0066 (19)
C26	0.041 (2)	0.062 (3)	0.052 (2)	0.0079 (18)	−0.0085 (17)	0.018 (2)
C27	0.0354 (18)	0.049 (2)	0.0443 (19)	0.0025 (15)	0.0019 (15)	0.0177 (16)
C29	0.066 (3)	0.059 (3)	0.038 (2)	0.013 (2)	−0.0041 (18)	0.0182 (18)
C30	0.048 (2)	0.052 (2)	0.044 (2)	0.0070 (17)	0.0105 (17)	0.0117 (17)
C31	0.065 (3)	0.039 (2)	0.058 (2)	0.0033 (18)	0.011 (2)	0.0123 (18)
C32	0.046 (2)	0.057 (3)	0.061 (3)	0.0145 (18)	0.0103 (19)	0.015 (2)
C33	0.054 (2)	0.061 (3)	0.039 (2)	0.0014 (19)	0.0009 (17)	0.0129 (18)
C38	0.066 (3)	0.048 (2)	0.050 (2)	−0.011 (2)	0.002 (2)	0.0095 (18)
C39	0.054 (2)	0.055 (2)	0.049 (2)	−0.0085 (19)	0.0034 (18)	0.0128 (19)
C40	0.075 (3)	0.039 (2)	0.059 (3)	0.0149 (19)	0.021 (2)	0.0144 (18)
C41	0.054 (2)	0.037 (2)	0.057 (2)	−0.0024 (17)	−0.0037 (19)	0.0087 (17)
C42	0.067 (3)	0.061 (3)	0.055 (3)	0.003 (2)	0.020 (2)	−0.011 (2)
C43	0.111 (5)	0.067 (3)	0.053 (3)	−0.006 (3)	−0.012 (3)	0.015 (2)
C45	0.0327 (19)	0.040 (2)	0.088 (3)	0.0046 (15)	0.0014 (19)	−0.006 (2)
C46	0.053 (3)	0.071 (3)	0.069 (3)	−0.001 (2)	0.001 (2)	0.037 (2)
C48	0.073 (3)	0.081 (3)	0.044 (2)	0.015 (3)	0.008 (2)	0.027 (2)
C49	0.101 (4)	0.060 (3)	0.033 (2)	0.009 (3)	0.008 (2)	0.0095 (19)
C50	0.064 (3)	0.069 (3)	0.040 (2)	0.005 (2)	0.0167 (19)	0.008 (2)
C51	0.068 (3)	0.056 (3)	0.049 (2)	−0.005 (2)	−0.008 (2)	0.024 (2)
C53	0.075 (3)	0.070 (3)	0.047 (2)	0.009 (2)	0.022 (2)	0.016 (2)
C54	0.087 (4)	0.041 (2)	0.079 (3)	0.014 (2)	0.022 (3)	0.006 (2)
C55	0.074 (3)	0.061 (3)	0.038 (2)	0.003 (2)	−0.012 (2)	0.0054 (19)
C56	0.075 (3)	0.055 (3)	0.092 (4)	0.012 (2)	0.024 (3)	0.042 (3)
C57	0.065 (3)	0.086 (4)	0.048 (2)	0.030 (3)	0.017 (2)	0.002 (2)
C58	0.0260 (18)	0.084 (3)	0.069 (3)	0.0000 (19)	0.0031 (18)	0.005 (2)
C59	0.040 (2)	0.053 (3)	0.106 (4)	−0.0103 (19)	0.001 (2)	−0.007 (3)
C60	0.104 (4)	0.032 (2)	0.084 (4)	−0.005 (2)	−0.009 (3)	0.015 (2)
C61	0.161 (7)	0.030 (2)	0.078 (4)	0.000 (3)	0.026 (4)	0.000 (2)
C62	0.065 (3)	0.067 (3)	0.059 (3)	0.029 (2)	−0.005 (2)	−0.006 (2)
C64	0.069 (3)	0.070 (3)	0.070 (3)	−0.010 (2)	−0.007 (2)	0.041 (3)
C66	0.075 (3)	0.046 (2)	0.060 (3)	0.009 (2)	0.009 (2)	0.019 (2)
C67	0.034 (2)	0.070 (3)	0.077 (3)	0.0134 (19)	0.008 (2)	0.003 (2)
C68	0.075 (3)	0.036 (2)	0.092 (4)	−0.004 (2)	0.010 (3)	0.014 (2)
C70	0.077 (3)	0.071 (3)	0.076 (3)	0.011 (3)	0.022 (3)	0.038 (3)
C73	0.077 (3)	0.047 (3)	0.082 (3)	−0.003 (2)	0.012 (3)	0.028 (2)
C78	0.072 (3)	0.074 (3)	0.055 (3)	−0.008 (3)	−0.014 (2)	0.017 (2)
C81	0.068 (3)	0.078 (4)	0.077 (3)	0.006 (3)	0.008 (3)	0.041 (3)
C83	0.061 (3)	0.054 (3)	0.086 (4)	0.017 (2)	0.004 (3)	0.014 (2)
C84	0.077 (3)	0.066 (3)	0.078 (4)	−0.014 (3)	0.013 (3)	0.026 (3)
C85	0.074 (3)	0.048 (2)	0.070 (3)	0.010 (2)	0.016 (2)	0.015 (2)
C87	0.115 (5)	0.044 (2)	0.066 (3)	0.005 (3)	0.035 (3)	0.005 (2)
C88	0.083 (4)	0.075 (3)	0.070 (3)	0.001 (3)	−0.001 (3)	0.046 (3)
C90	0.083 (4)	0.105 (5)	0.058 (3)	−0.005 (3)	−0.012 (3)	0.038 (3)
C96	0.0271 (15)	0.0364 (17)	0.0297 (15)	0.0019 (12)	0.0007 (12)	0.0042 (12)
C97	0.0359 (17)	0.0314 (16)	0.0344 (16)	0.0023 (12)	0.0045 (13)	0.0088 (13)
C98	0.085 (4)	0.072 (3)	0.064 (3)	−0.018 (3)	0.011 (3)	0.016 (3)
C99	0.115 (6)	0.107 (5)	0.122 (6)	0.010 (4)	0.008 (5)	0.073 (5)
C101	0.122 (5)	0.060 (3)	0.083 (4)	−0.006 (3)	−0.004 (4)	0.024 (3)

Ag1—P2	2.4067 (11)	C38—C85	1.385 (7)
Ag1—P1	2.4255 (11)	C38—C98	1.510 (7)
Ag1—O6	2.491 (3)	C39—C84	1.392 (7)
Ag1—Ag1i	2.9215 (9)	C39—H39A	0.930
Ag2—P4	2.4033 (11)	C40—C54	1.378 (6)
Ag2—P3	2.4181 (12)	C40—H40A	0.930
Ag2—O3	2.500 (3)	C41—C68	1.384 (6)
Ag2—Ag2ii	3.0278 (11)	C41—H41A	0.930
S1—O5	1.445 (4)	C42—C50	1.353 (7)
S1—O4	1.446 (3)	C42—C54	1.376 (8)
S1—O6	1.454 (3)	C42—H42A	0.930
S1—C22	1.773 (4)	C43—C101	1.387 (8)
S2—O1	1.436 (3)	C43—H43A	0.930
S2—O2	1.438 (4)	C45—C59	1.386 (6)
S2—O3	1.439 (3)	C45—H45A	0.930
S2—C21	1.781 (4)	C46—C64	1.390 (7)
P1—C14	1.812 (4)	C46—H46A	0.930
P1—C2	1.823 (3)	C48—C70	1.371 (8)
P1—C96	1.832 (3)	C48—H48A	0.930
P2—C12	1.817 (4)	C49—C53	1.360 (7)
P2—C7	1.827 (4)	C49—C55	1.378 (8)
P2—C96i	1.837 (3)	C49—H49A	0.930
P3—C8	1.813 (4)	C50—H50A	0.930
P3—C9	1.828 (4)	C51—C88	1.379 (6)
P3—C97ii	1.837 (3)	C51—H51A	0.930
P4—C6	1.811 (3)	C53—H53A	0.930
P4—C13	1.820 (4)	C54—H54A	0.930
P4—C97	1.835 (3)	C55—H55A	0.930
O7—O7'	1.060 (12)	C56—C68	1.360 (8)
O7—O7iii	1.423 (12)	C56—C88	1.365 (8)
C2—C45	1.375 (5)	C56—H56A	0.930
C2—C23	1.384 (5)	C57—C62	1.376 (8)
C6—C19	1.393 (5)	C57—H57A	0.930
C6—C27	1.393 (5)	C58—C67	1.354 (7)
C7—C32	1.385 (6)	C58—C59	1.359 (7)
C7—C24	1.393 (5)	C58—H58A	0.930
C8—C30	1.383 (5)	C59—H59A	0.930
C8—C15	1.392 (5)	C60—C61	1.360 (9)
C9—C31	1.377 (6)	C60—C73	1.365 (8)
C9—C87	1.379 (6)	C60—H60A	0.930
C12—C39	1.385 (5)	C61—C87	1.374 (7)
C12—C33	1.386 (5)	C61—H61A	0.930
C13—C17	1.383 (5)	C62—C83	1.374 (8)
C13—C40	1.388 (5)	C62—H62A	0.930
C14—C41	1.381 (5)	C64—H64A	0.930
C14—C51	1.386 (5)	C66—C85	1.386 (7)
C15—C55	1.388 (6)	C66—H66A	0.930
C15—H15A	0.930	C67—H67A	0.930
C17—C50	1.387 (6)	C68—H68A	0.930
C17—H17A	0.930	C70—C84	1.361 (8)
C19—C20	1.391 (5)	C70—H70A	0.930
C19—H19A	0.930	C73—H73A	0.930
C20—C29	1.374 (6)	C78—C90	1.375 (8)
C20—H20A	0.930	C78—H78A	0.930
C21—C78	1.370 (6)	C81—C101	1.367 (8)
C21—C43	1.373 (7)	C81—C90	1.369 (8)
C22—C46	1.380 (6)	C81—C99	1.518 (8)
C22—C66	1.381 (7)	C83—H83A	0.930
C23—C67	1.386 (6)	C84—H84A	0.930
C23—H23A	0.930	C85—H85A	0.930
C24—C57	1.384 (6)	C87—H87A	0.930
C24—H24A	0.930	C88—H88A	0.930
C26—C29	1.374 (6)	C90—H90A	0.930
C26—C27	1.383 (5)	C96—P2i	1.837 (3)
C26—H26A	0.930	C96—H96A	0.970
C27—H27A	0.930	C96—H96B	0.970
C29—H29A	0.930	C97—P3ii	1.837 (3)
C30—C53	1.399 (6)	C97—H97A	0.970
C30—H30A	0.930	C97—H97B	0.970
C31—C73	1.394 (6)	C98—H98A	0.960
C31—H31A	0.930	C98—H98B	0.960
C32—C83	1.379 (6)	C98—H98C	0.960
C32—H32A	0.930	C99—H99A	0.960
C33—C48	1.382 (6)	C99—H99B	0.960
C33—H33A	0.930	C99—H99C	0.960
C38—C64	1.382 (7)	C101—H10A	0.930
P2—Ag1—P1	164.99 (3)	C13—C40—H40A	119.9
P2—Ag1—O6	112.29 (10)	C14—C41—C68	119.7 (4)
P1—Ag1—O6	82.57 (10)	C14—C41—H41A	120.1
P2—Ag1—Ag1i	91.08 (3)	C68—C41—H41A	120.1
P1—Ag1—Ag1i	90.23 (3)	C50—C42—C54	120.0 (4)
O6—Ag1—Ag1i	92.55 (11)	C50—C42—H42A	120.0
P4—Ag2—P3	158.11 (3)	C54—C42—H42A	120.0
P4—Ag2—O3	111.55 (9)	C21—C43—C101	120.3 (5)
P3—Ag2—O3	90.29 (9)	C21—C43—H43A	119.8
P4—Ag2—Ag2ii	88.54 (4)	C101—C43—H43A	119.8
P3—Ag2—Ag2ii	87.92 (4)	C2—C45—C59	119.8 (4)
O3—Ag2—Ag2ii	95.78 (10)	C2—C45—H45A	120.1
O5—S1—O4	112.8 (2)	C59—C45—H45A	120.1
O5—S1—O6	113.6 (2)	C22—C46—C64	119.3 (5)
O4—S1—O6	110.8 (2)	C22—C46—H46A	120.3
O5—S1—C22	107.0 (2)	C64—C46—H46A	120.3
O4—S1—C22	107.45 (19)	C70—C48—C33	120.7 (5)
O6—S1—C22	104.5 (2)	C70—C48—H48A	119.7
O1—S2—O2	112.5 (2)	C33—C48—H48A	119.7
O1—S2—O3	111.5 (2)	C53—C49—C55	120.2 (4)
O2—S2—O3	113.8 (3)	C53—C49—H49A	119.9
O1—S2—C21	106.5 (2)	C55—C49—H49A	119.9
O2—S2—C21	106.5 (2)	C42—C50—C17	120.7 (4)
O3—S2—C21	105.5 (2)	C42—C50—H50A	119.7
C14—P1—C2	103.14 (16)	C17—C50—H50A	119.7
C14—P1—C96	104.78 (16)	C88—C51—C14	119.9 (4)
C2—P1—C96	104.75 (15)	C88—C51—H51A	120.1
C14—P1—Ag1	118.76 (12)	C14—C51—H51A	120.1
C2—P1—Ag1	115.51 (11)	C49—C53—C30	120.6 (5)
C96—P1—Ag1	108.56 (11)	C49—C53—H53A	119.7
C12—P2—C7	105.20 (17)	C30—C53—H53A	119.7
C12—P2—C96i	106.36 (16)	C42—C54—C40	120.3 (5)
C7—P2—C96i	103.85 (16)	C42—C54—H54A	119.8
C12—P2—Ag1	114.08 (12)	C40—C54—H54A	119.8
C7—P2—Ag1	112.04 (12)	C49—C55—C15	120.2 (4)
C96i—P2—Ag1	114.38 (11)	C49—C55—H55A	119.9
C8—P3—C9	102.78 (17)	C15—C55—H55A	119.9
C8—P3—C97ii	105.92 (16)	C68—C56—C88	120.1 (4)
C9—P3—C97ii	104.90 (16)	C68—C56—H56A	119.9
C8—P3—Ag2	120.08 (13)	C88—C56—H56A	119.9
C9—P3—Ag2	114.48 (12)	C62—C57—C24	121.1 (5)
C97ii—P3—Ag2	107.44 (11)	C62—C57—H57A	119.5
C6—P4—C13	104.61 (16)	C24—C57—H57A	119.5
C6—P4—C97	104.25 (16)	C67—C58—C59	119.6 (4)
C13—P4—C97	105.29 (16)	C67—C58—H58A	120.2
C6—P4—Ag2	115.22 (11)	C59—C58—H58A	120.2
C13—P4—Ag2	109.60 (11)	C58—C59—C45	121.1 (4)
C97—P4—Ag2	116.76 (12)	C58—C59—H59A	119.4
S2—O3—Ag2	165.2 (2)	C45—C59—H59A	119.4
S1—O6—Ag1	167.0 (3)	C61—C60—C73	119.4 (4)
O7'—O7—O7iii	173.8 (14)	C61—C60—H60A	120.3
C45—C2—C23	118.5 (3)	C73—C60—H60A	120.3
C45—C2—P1	122.7 (3)	C60—C61—C87	120.7 (5)
C23—C2—P1	118.7 (3)	C60—C61—H61A	119.6
C19—C6—C27	119.8 (3)	C87—C61—H61A	119.6
C19—C6—P4	118.7 (3)	C83—C62—C57	119.4 (5)
C27—C6—P4	121.4 (3)	C83—C62—H62A	120.3
C32—C7—C24	118.8 (4)	C57—C62—H62A	120.3
C32—C7—P2	119.4 (3)	C38—C64—C46	121.9 (4)
C24—C7—P2	121.6 (3)	C38—C64—H64A	119.1
C30—C8—C15	119.4 (4)	C46—C64—H64A	119.1
C30—C8—P3	120.4 (3)	C22—C66—C85	120.5 (4)
C15—C8—P3	120.2 (3)	C22—C66—H66A	119.7
C31—C9—C87	118.2 (4)	C85—C66—H66A	119.7
C31—C9—P3	122.1 (3)	C58—C67—C23	120.3 (4)
C87—C9—P3	119.6 (3)	C58—C67—H67A	119.9
C39—C12—C33	118.8 (4)	C23—C67—H67A	119.9
C39—C12—P2	118.9 (3)	C56—C68—C41	120.6 (5)
C33—C12—P2	122.3 (3)	C56—C68—H68A	119.7
C17—C13—C40	118.9 (4)	C41—C68—H68A	119.7
C17—C13—P4	122.0 (3)	C84—C70—C48	119.5 (5)
C40—C13—P4	118.7 (3)	C84—C70—H70A	120.2
C41—C14—C51	119.3 (4)	C48—C70—H70A	120.2
C41—C14—P1	119.9 (3)	C60—C73—C31	120.3 (5)
C51—C14—P1	120.8 (3)	C60—C73—H73A	119.8
C55—C15—C8	119.9 (4)	C31—C73—H73A	119.8
C55—C15—H15A	120.0	C21—C78—C90	121.2 (5)
C8—C15—H15A	120.0	C21—C78—H78A	119.4
C13—C17—C50	120.0 (4)	C90—C78—H78A	119.4
C13—C17—H17A	120.0	C101—C81—C90	117.2 (5)
C50—C17—H17A	120.0	C101—C81—C99	120.2 (6)
C20—C19—C6	119.2 (4)	C90—C81—C99	122.6 (6)
C20—C19—H19A	120.4	C62—C83—C32	120.1 (5)
C6—C19—H19A	120.4	C62—C83—H83A	119.9
C29—C20—C19	120.6 (4)	C32—C83—H83A	119.9
C29—C20—H20A	119.7	C70—C84—C39	120.8 (5)
C19—C20—H20A	119.7	C70—C84—H84A	119.6
C78—C21—C43	117.9 (5)	C39—C84—H84A	119.6
C78—C21—S2	120.8 (4)	C38—C85—C66	120.8 (5)
C43—C21—S2	121.3 (4)	C38—C85—H85A	119.6
C46—C22—C66	119.5 (4)	C66—C85—H85A	119.6
C46—C22—S1	120.9 (4)	C61—C87—C9	120.9 (5)
C66—C22—S1	119.6 (3)	C61—C87—H87A	119.5
C2—C23—C67	120.6 (4)	C9—C87—H87A	119.5
C2—C23—H23A	119.7	C56—C88—C51	120.4 (5)
C67—C23—H23A	119.7	C56—C88—H88A	119.8
C57—C24—C7	119.5 (5)	C51—C88—H88A	119.8
C57—C24—H24A	120.2	C81—C90—C78	121.6 (5)
C7—C24—H24A	120.2	C81—C90—H90A	119.2
C29—C26—C27	120.1 (4)	C78—C90—H90A	119.2
C29—C26—H26A	119.9	P1—C96—P2i	112.06 (17)
C27—C26—H26A	119.9	P1—C96—H96A	109.2
C26—C27—C6	120.0 (4)	P2i—C96—H96A	109.2
C26—C27—H27A	120.0	P1—C96—H96B	109.2
C6—C27—H27A	120.0	P2i—C96—H96B	109.2
C20—C29—C26	120.4 (4)	H96A—C96—H96B	107.9
C20—C29—H29A	119.8	P4—C97—P3ii	110.50 (18)
C26—C29—H29A	119.8	P4—C97—H97A	109.6
C8—C30—C53	119.7 (4)	P3ii—C97—H97A	109.6
C8—C30—H30A	120.2	P4—C97—H97B	109.6
C53—C30—H30A	120.2	P3ii—C97—H97B	109.6
C9—C31—C73	120.4 (4)	H97A—C97—H97B	108.1
C9—C31—H31A	119.8	C38—C98—H98A	109.5
C73—C31—H31A	119.8	C38—C98—H98B	109.5
C83—C32—C7	121.0 (4)	H98A—C98—H98B	109.5
C83—C32—H32A	119.5	C38—C98—H98C	109.5
C7—C32—H32A	119.5	H98A—C98—H98C	109.5
C48—C33—C12	120.3 (4)	H98B—C98—H98C	109.5
C48—C33—H33A	119.9	C81—C99—H99A	109.5
C12—C33—H33A	119.9	C81—C99—H99B	109.5
C64—C38—C85	117.9 (4)	H99A—C99—H99B	109.5
C64—C38—C98	121.3 (5)	C81—C99—H99C	109.5
C85—C38—C98	120.8 (5)	H99A—C99—H99C	109.5
C12—C39—C84	119.9 (4)	H99B—C99—H99C	109.5
C12—C39—H39A	120.0	C81—C101—C43	121.9 (6)
C84—C39—H39A	120.0	C81—C101—H10A	119.1
C54—C40—C13	120.1 (4)	C43—C101—H10A	119.1
C54—C40—H40A	119.9
P2—Ag1—P1—C14	−14.84 (19)	P4—C13—C17—C50	−173.4 (3)
O6—Ag1—P1—C14	172.73 (17)	C27—C6—C19—C20	2.0 (6)
Ag1i—Ag1—P1—C14	80.19 (13)	P4—C6—C19—C20	−174.9 (3)
P2—Ag1—P1—C2	108.48 (17)	C6—C19—C20—C29	−1.0 (6)
O6—Ag1—P1—C2	−63.95 (17)	O1—S2—C21—C78	−138.1 (4)
Ag1i—Ag1—P1—C2	−156.49 (13)	O2—S2—C21—C78	−17.9 (5)
P2—Ag1—P1—C96	−134.27 (15)	O3—S2—C21—C78	103.3 (4)
O6—Ag1—P1—C96	53.30 (16)	O1—S2—C21—C43	40.9 (5)
Ag1i—Ag1—P1—C96	−39.24 (12)	O2—S2—C21—C43	161.1 (5)
P1—Ag1—P2—C12	−152.08 (15)	O3—S2—C21—C43	−77.6 (5)
O6—Ag1—P2—C12	19.80 (18)	O5—S1—C22—C46	0.5 (4)
Ag1i—Ag1—P2—C12	113.00 (13)	O4—S1—C22—C46	−120.9 (4)
P1—Ag1—P2—C7	−32.69 (19)	O6—S1—C22—C46	121.3 (4)
O6—Ag1—P2—C7	139.19 (18)	O5—S1—C22—C66	−178.1 (4)
Ag1i—Ag1—P2—C7	−127.61 (13)	O4—S1—C22—C66	60.5 (4)
P1—Ag1—P2—C96i	85.16 (17)	O6—S1—C22—C66	−57.3 (4)
O6—Ag1—P2—C96i	−102.97 (17)	C45—C2—C23—C67	0.6 (7)
Ag1i—Ag1—P2—C96i	−9.77 (12)	P1—C2—C23—C67	177.0 (4)
P4—Ag2—P3—C8	−6.50 (18)	C32—C7—C24—C57	0.3 (6)
O3—Ag2—P3—C8	170.12 (17)	P2—C7—C24—C57	174.8 (3)
Ag2ii—Ag2—P3—C8	74.34 (14)	C29—C26—C27—C6	−0.2 (6)
P4—Ag2—P3—C9	116.50 (16)	C19—C6—C27—C26	−1.4 (6)
O3—Ag2—P3—C9	−66.88 (17)	P4—C6—C27—C26	175.4 (3)
Ag2ii—Ag2—P3—C9	−162.66 (14)	C19—C20—C29—C26	−0.6 (7)
P4—Ag2—P3—C97ii	−127.45 (14)	C27—C26—C29—C20	1.2 (7)
O3—Ag2—P3—C97ii	49.17 (15)	C15—C8—C30—C53	−0.8 (6)
Ag2ii—Ag2—P3—C97ii	−46.60 (12)	P3—C8—C30—C53	179.6 (3)
P3—Ag2—P4—C6	−160.23 (14)	C87—C9—C31—C73	−0.8 (7)
O3—Ag2—P4—C6	23.41 (17)	P3—C9—C31—C73	−176.2 (4)
Ag2ii—Ag2—P4—C6	119.05 (13)	C24—C7—C32—C83	−1.8 (6)
P3—Ag2—P4—C13	−42.60 (16)	P2—C7—C32—C83	−176.4 (4)
O3—Ag2—P4—C13	141.04 (16)	C39—C12—C33—C48	0.9 (6)
Ag2ii—Ag2—P4—C13	−123.32 (13)	P2—C12—C33—C48	−176.3 (4)
P3—Ag2—P4—C97	76.94 (16)	C33—C12—C39—C84	−0.7 (7)
O3—Ag2—P4—C97	−99.42 (16)	P2—C12—C39—C84	176.7 (4)
Ag2ii—Ag2—P4—C97	−3.79 (12)	C17—C13—C40—C54	0.0 (7)
O1—S2—O3—Ag2	33.0 (12)	P4—C13—C40—C54	173.1 (4)
O2—S2—O3—Ag2	−95.4 (11)	C51—C14—C41—C68	−0.6 (7)
C21—S2—O3—Ag2	148.2 (11)	P1—C14—C41—C68	179.9 (4)
P4—Ag2—O3—S2	149.2 (11)	C78—C21—C43—C101	−0.1 (9)
P3—Ag2—O3—S2	−29.5 (11)	S2—C21—C43—C101	−179.2 (5)
Ag2ii—Ag2—O3—S2	58.5 (11)	C23—C2—C45—C59	−1.9 (7)
O5—S1—O6—Ag1	−43.5 (12)	P1—C2—C45—C59	−178.2 (4)
O4—S1—O6—Ag1	84.8 (12)	C66—C22—C46—C64	1.9 (7)
C22—S1—O6—Ag1	−159.8 (11)	S1—C22—C46—C64	−176.7 (4)
P2—Ag1—O6—S1	100.6 (11)	C12—C33—C48—C70	−0.2 (8)
P1—Ag1—O6—S1	−81.5 (11)	C54—C42—C50—C17	−0.6 (8)
Ag1i—Ag1—O6—S1	8.4 (12)	C13—C17—C50—C42	0.8 (7)
C14—P1—C2—C45	−137.3 (4)	C41—C14—C51—C88	1.5 (7)
C96—P1—C2—C45	−27.9 (4)	P1—C14—C51—C88	−178.9 (4)
Ag1—P1—C2—C45	91.4 (4)	C55—C49—C53—C30	−0.2 (8)
C14—P1—C2—C23	46.4 (3)	C8—C30—C53—C49	0.8 (7)
C96—P1—C2—C23	155.8 (3)	C50—C42—C54—C40	0.1 (9)
Ag1—P1—C2—C23	−84.9 (3)	C13—C40—C54—C42	0.2 (8)
C13—P4—C6—C19	−138.7 (3)	C53—C49—C55—C15	−0.5 (7)
C97—P4—C6—C19	111.0 (3)	C8—C15—C55—C49	0.6 (7)
Ag2—P4—C6—C19	−18.3 (3)	C7—C24—C57—C62	1.3 (7)
C13—P4—C6—C27	44.5 (3)	C67—C58—C59—C45	0.8 (9)
C97—P4—C6—C27	−65.8 (3)	C2—C45—C59—C58	1.2 (9)
Ag2—P4—C6—C27	164.9 (3)	C73—C60—C61—C87	−1.3 (11)
C12—P2—C7—C32	−165.1 (3)	C24—C57—C62—C83	−1.4 (8)
C96i—P2—C7—C32	−53.5 (3)	C85—C38—C64—C46	−3.1 (8)
Ag1—P2—C7—C32	70.5 (3)	C98—C38—C64—C46	177.4 (5)
C12—P2—C7—C24	20.4 (4)	C22—C46—C64—C38	1.3 (8)
C96i—P2—C7—C24	132.0 (3)	C46—C22—C66—C85	−3.1 (7)
Ag1—P2—C7—C24	−104.0 (3)	S1—C22—C66—C85	175.5 (4)
C9—P3—C8—C30	−122.1 (3)	C59—C58—C67—C23	−2.1 (9)
C97ii—P3—C8—C30	128.1 (3)	C2—C23—C67—C58	1.5 (8)
Ag2—P3—C8—C30	6.4 (4)	C88—C56—C68—C41	1.2 (8)
C9—P3—C8—C15	58.3 (3)	C14—C41—C68—C56	−0.8 (8)
C97ii—P3—C8—C15	−51.6 (3)	C33—C48—C70—C84	−0.7 (8)
Ag2—P3—C8—C15	−173.2 (3)	C61—C60—C73—C31	0.7 (9)
C8—P3—C9—C31	−147.3 (3)	C9—C31—C73—C60	0.4 (8)
C97ii—P3—C9—C31	−36.7 (4)	C43—C21—C78—C90	−0.3 (8)
Ag2—P3—C9—C31	80.8 (4)	S2—C21—C78—C90	178.8 (5)
C8—P3—C9—C87	37.4 (4)	C57—C62—C83—C32	−0.1 (8)
C97ii—P3—C9—C87	148.0 (4)	C7—C32—C83—C62	1.7 (7)
Ag2—P3—C9—C87	−94.5 (4)	C48—C70—C84—C39	1.0 (9)
C7—P2—C12—C39	−117.6 (3)	C12—C39—C84—C70	−0.3 (8)
C96i—P2—C12—C39	132.6 (3)	C64—C38—C85—C66	1.9 (7)
Ag1—P2—C12—C39	5.6 (4)	C98—C38—C85—C66	−178.7 (5)
C7—P2—C12—C33	59.6 (4)	C22—C66—C85—C38	1.2 (8)
C96i—P2—C12—C33	−50.1 (4)	C60—C61—C87—C9	0.8 (11)
Ag1—P2—C12—C33	−177.2 (3)	C31—C9—C87—C61	0.3 (9)
C6—P4—C13—C17	−142.1 (3)	P3—C9—C87—C61	175.7 (5)
C97—P4—C13—C17	−32.5 (4)	C68—C56—C88—C51	−0.3 (9)
Ag2—P4—C13—C17	93.8 (3)	C14—C51—C88—C56	−1.1 (8)
C6—P4—C13—C40	45.0 (4)	C101—C81—C90—C78	−0.1 (10)
C97—P4—C13—C40	154.5 (3)	C99—C81—C90—C78	−178.5 (6)
Ag2—P4—C13—C40	−79.1 (3)	C21—C78—C90—C81	0.4 (9)
C2—P1—C14—C41	−132.8 (3)	C14—P1—C96—P2i	−72.4 (2)
C96—P1—C14—C41	117.8 (3)	C2—P1—C96—P2i	179.37 (17)
Ag1—P1—C14—C41	−3.6 (4)	Ag1—P1—C96—P2i	55.44 (19)
C2—P1—C14—C51	47.6 (4)	C6—P4—C97—P3ii	−89.6 (2)
C96—P1—C14—C51	−61.8 (4)	C13—P4—C97—P3ii	160.60 (17)
Ag1—P1—C14—C51	176.8 (3)	Ag2—P4—C97—P3ii	38.8 (2)
C30—C8—C15—C55	0.1 (6)	C90—C81—C101—C43	−0.4 (10)
P3—C8—C15—C55	179.7 (3)	C99—C81—C101—C43	178.2 (7)
C40—C13—C17—C50	−0.5 (6)	C21—C43—C101—C81	0.5 (11)

Ag1—P2	2.4067 (11)
Ag1—P1	2.4255 (11)
Ag1—O6	2.491 (3)
Ag2—P4	2.4033 (11)
Ag2—P3	2.4181 (12)
Ag2—O3	2.500 (3)

P2—Ag1—P1	164.99 (3)
P2—Ag1—O6	112.29 (10)
P1—Ag1—O6	82.57 (10)
P4—Ag2—P3	158.11 (3)
P4—Ag2—O3	111.55 (9)
P3—Ag2—O3	90.29 (9)