Poly[[{μ(3)-tris-[2-(4-phenyl-1,2,3-triazol-1-yl)eth-yl]amine}silver(I)] hexa-fluorido-phosphate].

The title compound, {[Ag(L)]PF(6))(n) {L is tris-[2-(4-phenyl-1,2,3-triazol-1-yl)eth-yl]amine, C(30)H(30)N(10)}, consists of alternating two-dimensional cationic layers of [Ag(L)](+) and anionic PF(6) (-) layers. Each Ag(I) atom is three coordinated in a T-shaped geometry by three N atoms from three ligands. Each ligand links three Ag(I) atoms, generating a two-dimensional network structure with two different metallacycles, A and B. In A, eight coordination units from four ligands connect four Ag(I) atoms, forming a 48-membered ring. In B, four coordination units from two ligands link two Ag(I) atoms, forming a 24-membered ring. Each B ring is surrounded by four A rings, and each A ring has four A and four B rings as neighbours. This cationic layer thus generates a 4.8(2) topology network, with each Ag(I) centre and ligand acting as a three-connected topological node.

Related literature

For related literature, see: Newkome et al. (1999 ▶); n class="Species">Robin & Fromm (2006 ▶); Ohi et al. (2004 ▶, 2005 ▶); Obata et al. (2008 ▶).

Experimental

Crystal data

[Ag(C30H30N10)]PF6

M = 783.47

Monoclinic,

a = 14.893 (3) Å

b = 14.935 (3) Å

c = 15.735 (3) Å

β = 112.646 (5)°

V = 3230.2 (12) Å3

Z = 4

Mo Kα radiation

μ = 0.75 mm−1

T = 193.1 K

0.30 × 0.15 × 0.05 mm

Data collection

Rigaku Mercury diffractometer

Absorption correction: multi-scan (Jacobson, 1998 ▶) T min = 0.776, T max = 0.963

31971 measured reflections

7326 independent reflections

4647 reflections with F 2 > 2σ(F 2)

R int = 0.075

Refinement

R[F 2 > 2σ(F 2)] = 0.054

wR(F 2) = 0.055

S = 1.03

7326 reflections

463 parameters

All H-atom parameters refined

Δρmax = 3.48 e Å−3

Δρmin = −2.33 e Å−3

Data collection: CrystalClear (Rigaku/MSC & Rigaku, 2006 ▶); cell refinement: CrystalClear; data reduction: CrystalStructure; program(s) used to solve structure: SIR97 (Altomare et al., 1999 ▶); program(s) used to refine structure: CRYSTALS (Betteridge et al., 2003 ▶); molecular graphics: ORTEPIII (Burnett & Johnson, 1996 ▶); software used to prepare material for publication: CrystalStructure (Rigaku/MSC & Rigaku, 2006 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808028298/bt2780sup1.cif

Structure factors: contains datablocks I, I. DOI: 10.1107/S1600536808028298/bt2780Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ag(C30H30N10)]PF6	F(000) = 1584.00
Mr = 783.47	Dx = 1.611 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71070 Å
Hall symbol: -P 2yn	Cell parameters from 9566 reflections
a = 14.893 (3) Å	θ = 4.0–27.5°
b = 14.935 (3) Å	µ = 0.75 mm−1
c = 15.735 (3) Å	T = 193 K
β = 112.646 (5)°	Platelet, colourless
V = 3230.2 (12) Å3	0.30 × 0.15 × 0.05 mm
Z = 4

Rigaku Mercury diffractometer	4647 reflections with F2 > 2σ(F2)
Detector resolution: 7.31 pixels mm-1	Rint = 0.075
ω scans	θmax = 27.5°
Absorption correction: multi-scan (Jacobson, 1998)	h = −19→16
Tmin = 0.776, Tmax = 0.963	k = −19→19
31971 measured reflections	l = −20→20
7326 independent reflections

Refinement on F2	0 restraints
R[F2 > 2σ(F2)] = 0.054	All H-atom parameters refined
wR(F2) = 0.055	w = 1/[1.0000σ(Fo2)]/(4Fo2)
S = 1.03	(Δ/σ)max < 0.001
7326 reflections	Δρmax = 3.48 e Å−3
463 parameters	Δρmin = −2.33 e Å−3

Experimental. The ligand tris((4-phenyl-1,2,3-triazole-1-yl)ethyl)amine) (L) was synthesized by using Huisgen reaction, which is known as cycloaddition of azide and acetylene derivatives to give 1,2,3-triazole unit. The conversion of tris(2-chloroethyl)amine (2.21 g, 10.9 mmol) into tris(2-azidoethyl)amine was achieved by addition of 3 mole equivalents of sodium azide to tris(2-chloroethyl)amine in dimethylformamide under stirring at 80 °C. To the THF (100 ml) and water (100 ml) solution of crude tris(2-azidoethyl)amine obtained and phenylacethylene (2.57 g, 25.2 mmol) was added 1 M sodium ascorbate (aq) (0.9 ml) and 7.5 wt% CuSO4 (aq) (2.5 ml) and the mixture was stirred at 50 °C for 1 day. After concentration under reduced pressure, the resulting residue was then suspended in CHCl3, to which an aqueous solution of NH3 was successively added. After washing the organic layer with the NH3 aqueous solution, the organic layer was dried over anhydrous Na2SO4 and concentrated by evaporation. The resulting residue was purified by silica gel column chromatography (eluent; from CHCl3 to ethyl acetate). The organic materials having Rf = 0.21 (eluent; ethyl acetate) were collected (1.73 g, yield 37%). 1H NMR (CDCl3, 400 MHz): δ 3.33 (dt, 6H, J = 4.8, 2.4 Hz, N—CH2CH2–), 4.10 (dt, 6H, J = 4.8, 2.4 Hz, N—CH2CH2–), 6.80 (s, 3H, triazole-H), 7.00 (t, 6H, J = 7.6 Hz Ar-3H, 5H), 7.18 (tt, 3H, J = 7.6, 1.2 Hz, Ar-4H), 7.27 (d, 3H, J = 7.6 Hz, Ar-2H or 6H), 7.28 (d, 3H, J = 7.6 Hz, Ar-2H or 6H). HRMS (FAB, pos): m/z = 531.2729 calcd for [L + H]+, C30H31N10, 531.2733.

Geometry. ENTER SPECIAL DETAILS OF THE MOLECULAR GEOMETRY

Refinement. Refinement was performed using all reflections. The weighted R-factor (wR) and goodness of fit (S) are based on F2. R-factor (gt) are based on F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt).

	x	y	z	Uiso*/Ueq
Ag(1)	0.45614 (2)	0.23636 (2)	0.47433 (2)	0.02556 (7)
P(1)	0.72081 (8)	0.21389 (8)	0.19893 (9)	0.0300 (3)
F(1)	0.78327 (16)	0.23364 (19)	0.13875 (17)	0.0552 (8)
F(2)	0.65821 (18)	0.19439 (16)	0.25993 (18)	0.0492 (9)
F(3)	0.7415 (2)	0.31311 (17)	0.2382 (2)	0.0583 (10)
F(4)	0.81644 (17)	0.17994 (18)	0.28073 (17)	0.0477 (8)
F(5)	0.70048 (18)	0.11394 (16)	0.15986 (17)	0.0475 (8)
F(6)	0.62526 (17)	0.2473 (2)	0.11681 (17)	0.0628 (9)
N(1)	0.0406 (2)	0.4073 (2)	0.3528 (2)	0.0209 (9)
N(2)	0.2601 (2)	0.4507 (2)	0.4393 (2)	0.0264 (10)
N(3)	0.2869 (2)	0.3656 (2)	0.4548 (2)	0.0249 (10)
N(4)	0.3631 (2)	0.3565 (2)	0.4315 (2)	0.0223 (9)
N(5)	−0.0085 (2)	0.5197 (2)	0.1746 (2)	0.0258 (10)
N(6)	−0.0277 (2)	0.5971 (2)	0.1282 (2)	0.0303 (10)
N(7)	0.0412 (2)	0.6093 (2)	0.0966 (2)	0.0242 (9)
N(8)	0.0859 (2)	0.2467 (2)	0.26377 (19)	0.0231 (9)
N(9)	0.0191 (2)	0.2593 (2)	0.1787 (2)	0.0265 (9)
N(10)	0.06704 (19)	0.2581 (2)	0.1214 (2)	0.0214 (8)
C(1)	0.1011 (2)	0.4214 (2)	0.4501 (2)	0.0245 (11)
C(2)	0.1823 (3)	0.4872 (2)	0.4670 (3)	0.0290 (13)
C(3)	0.3162 (3)	0.4970 (2)	0.4061 (2)	0.0258 (12)
C(4)	0.3837 (2)	0.4368 (2)	0.4008 (2)	0.0196 (10)
C(5)	0.4644 (2)	0.4490 (2)	0.3710 (2)	0.0216 (11)
C(6)	0.5077 (3)	0.3770 (2)	0.3441 (3)	0.0320 (13)
C(7)	0.5821 (3)	0.3898 (2)	0.3148 (3)	0.0355 (13)
C(8)	0.6151 (3)	0.4762 (2)	0.3095 (3)	0.0339 (13)
C(9)	0.5733 (3)	0.5481 (2)	0.3355 (3)	0.0334 (13)
C(10)	0.4994 (2)	0.5343 (2)	0.3659 (2)	0.0262 (12)
C(11)	−0.0307 (2)	0.4794 (2)	0.3191 (2)	0.0275 (12)
C(12)	−0.0760 (3)	0.4862 (2)	0.2144 (2)	0.0292 (12)
C(13)	0.0726 (3)	0.4829 (2)	0.1727 (2)	0.0289 (12)
C(14)	0.1058 (2)	0.5395 (2)	0.1229 (2)	0.0213 (11)
C(15)	0.1908 (3)	0.5339 (2)	0.0964 (3)	0.0260 (12)
C(16)	0.2701 (3)	0.4828 (2)	0.1481 (3)	0.0338 (13)
C(17)	0.3512 (3)	0.4771 (3)	0.1237 (3)	0.0435 (15)
C(18)	0.3528 (3)	0.5245 (3)	0.0501 (3)	0.0378 (14)
C(19)	0.2756 (3)	0.5757 (2)	−0.0014 (3)	0.0373 (14)
C(20)	0.1933 (3)	0.5808 (2)	0.0213 (3)	0.0330 (13)
C(21)	−0.0095 (2)	0.3209 (2)	0.3415 (2)	0.0264 (12)
C(22)	0.0557 (2)	0.2428 (2)	0.3421 (2)	0.0305 (11)
C(23)	0.1756 (2)	0.2375 (2)	0.2625 (2)	0.0246 (10)
C(24)	0.1642 (2)	0.2460 (2)	0.1730 (2)	0.0186 (9)
C(25)	0.2370 (2)	0.2422 (2)	0.1313 (2)	0.0229 (10)
C(26)	0.3333 (2)	0.2192 (2)	0.1856 (2)	0.0300 (12)
C(27)	0.4044 (2)	0.2207 (2)	0.1484 (2)	0.0348 (13)
C(28)	0.3802 (2)	0.2411 (3)	0.0577 (3)	0.0398 (13)
C(29)	0.2856 (3)	0.2615 (3)	0.0021 (2)	0.0463 (14)
C(30)	0.2140 (2)	0.2632 (3)	0.0378 (2)	0.0371 (12)
H(1)	0.0609	0.4411	0.4809	0.031*
H(2)	0.1300	0.3657	0.4752	0.031*
H(3)	0.2097	0.5019	0.5306	0.035*
H(4)	0.1560	0.5396	0.4320	0.035*
H(5)	0.3109	0.5585	0.3894	0.030*
H(6)	0.4843	0.3180	0.3456	0.038*
H(7)	0.6119	0.3401	0.2984	0.043*
H(8)	0.6660	0.4853	0.2882	0.042*
H(9)	0.5956	0.6070	0.3318	0.039*
H(10)	0.4713	0.5841	0.3842	0.032*
H(11)	−0.0812	0.4703	0.3410	0.033*
H(12)	0.0015	0.5343	0.3426	0.033*
H(13)	−0.1302	0.5256	0.1973	0.034*
H(14)	−0.0975	0.4283	0.1902	0.035*
H(15)	0.1018	0.4283	0.2008	0.034*
H(16)	0.2699	0.4520	0.2009	0.042*
H(17)	0.4051	0.4408	0.1587	0.051*
H(18)	0.4077	0.5204	0.0335	0.046*
H(19)	0.2777	0.6090	−0.0521	0.046*
H(20)	0.1390	0.6162	−0.0148	0.038*
H(21)	−0.0344	0.3136	0.3883	0.033*
H(22)	−0.0618	0.3215	0.2829	0.033*
H(23)	0.0215	0.1885	0.3391	0.038*
H(24)	0.1117	0.2447	0.3979	0.038*
H(25)	0.2345	0.2270	0.3140	0.029*
H(26)	0.3498	0.2023	0.2480	0.033*
H(27)	0.4700	0.2075	0.1866	0.041*
H(28)	0.4292	0.2411	0.0330	0.049*
H(29)	0.2695	0.2747	−0.0612	0.056*
H(30)	0.1488	0.2782	−0.0003	0.043*

	U11	U22	U33	U12	U13	U23
Ag(1)	0.02591 (16)	0.01924 (15)	0.02906 (17)	0.00118 (17)	0.00786 (13)	−0.00264 (17)
P(1)	0.0251 (6)	0.0333 (7)	0.0370 (7)	0.0018 (5)	0.0179 (5)	−0.0044 (5)
F(1)	0.0571 (16)	0.0648 (18)	0.0679 (18)	0.0167 (16)	0.0508 (15)	0.0146 (17)
F(2)	0.0509 (16)	0.0533 (17)	0.066 (2)	−0.0082 (13)	0.0474 (15)	−0.0081 (14)
F(3)	0.059 (2)	0.0343 (16)	0.100 (2)	−0.0089 (14)	0.0517 (19)	−0.0210 (15)
F(4)	0.0291 (15)	0.0657 (19)	0.0396 (16)	−0.0025 (13)	0.0036 (13)	−0.0018 (13)
F(5)	0.0530 (17)	0.0392 (16)	0.0500 (17)	−0.0004 (13)	0.0195 (14)	−0.0172 (13)
F(6)	0.0385 (14)	0.073 (2)	0.0681 (18)	0.0214 (17)	0.0110 (13)	0.0161 (18)
N(1)	0.0190 (18)	0.0246 (19)	0.0191 (18)	0.0041 (14)	0.0073 (15)	0.0046 (14)
N(2)	0.0191 (19)	0.027 (2)	0.032 (2)	0.0078 (15)	0.0085 (17)	−0.0015 (16)
N(3)	0.025 (2)	0.0202 (19)	0.028 (2)	0.0007 (15)	0.0092 (17)	−0.0004 (15)
N(4)	0.0207 (18)	0.0194 (18)	0.027 (2)	−0.0013 (14)	0.0091 (16)	−0.0030 (15)
N(5)	0.027 (2)	0.024 (2)	0.024 (2)	−0.0012 (16)	0.0073 (17)	0.0025 (16)
N(6)	0.033 (2)	0.028 (2)	0.027 (2)	0.0027 (17)	0.0082 (18)	0.0069 (16)
N(7)	0.029 (2)	0.0230 (19)	0.0200 (19)	0.0010 (15)	0.0080 (16)	0.0034 (15)
N(8)	0.0319 (18)	0.0146 (19)	0.0206 (17)	0.0029 (15)	0.0076 (15)	0.0042 (15)
N(9)	0.0206 (16)	0.0262 (19)	0.0275 (18)	−0.0016 (16)	0.0035 (14)	0.0025 (17)
N(10)	0.0153 (15)	0.0141 (17)	0.0324 (18)	−0.0031 (14)	0.0065 (14)	−0.0005 (15)
C(1)	0.023 (2)	0.036 (2)	0.019 (2)	0.0077 (19)	0.0132 (19)	0.0000 (19)
C(2)	0.026 (2)	0.037 (2)	0.026 (2)	0.009 (2)	0.012 (2)	−0.002 (2)
C(3)	0.029 (2)	0.021 (2)	0.025 (2)	−0.0017 (18)	0.008 (2)	0.0042 (18)
C(4)	0.020 (2)	0.016 (2)	0.019 (2)	0.0022 (16)	0.0027 (18)	0.0006 (16)
C(5)	0.022 (2)	0.017 (2)	0.024 (2)	0.0005 (17)	0.0068 (19)	−0.0013 (17)
C(6)	0.033 (2)	0.023 (2)	0.039 (2)	−0.0044 (19)	0.012 (2)	−0.004 (2)
C(7)	0.028 (2)	0.034 (2)	0.045 (3)	0.003 (2)	0.015 (2)	−0.006 (2)
C(8)	0.024 (2)	0.041 (2)	0.040 (2)	−0.004 (2)	0.016 (2)	0.001 (2)
C(9)	0.028 (2)	0.026 (2)	0.044 (2)	−0.007 (2)	0.011 (2)	−0.002 (2)
C(10)	0.026 (2)	0.022 (2)	0.033 (2)	0.0018 (18)	0.013 (2)	0.0001 (19)
C(11)	0.023 (2)	0.030 (2)	0.029 (2)	0.0057 (19)	0.0093 (19)	0.0033 (19)
C(12)	0.026 (2)	0.034 (2)	0.026 (2)	0.0013 (19)	0.009 (2)	0.003 (2)
C(13)	0.034 (2)	0.020 (2)	0.031 (2)	0.0055 (19)	0.010 (2)	0.0060 (19)
C(14)	0.028 (2)	0.016 (2)	0.016 (2)	−0.0004 (18)	0.0034 (19)	−0.0009 (16)
C(15)	0.030 (2)	0.020 (2)	0.025 (2)	−0.0051 (19)	0.006 (2)	−0.0044 (18)
C(16)	0.037 (2)	0.032 (2)	0.035 (2)	−0.002 (2)	0.018 (2)	0.007 (2)
C(17)	0.037 (2)	0.048 (3)	0.042 (3)	0.010 (2)	0.012 (2)	0.009 (2)
C(18)	0.029 (2)	0.046 (3)	0.040 (2)	0.002 (2)	0.014 (2)	−0.000 (2)
C(19)	0.049 (3)	0.031 (2)	0.036 (2)	−0.006 (2)	0.020 (2)	0.003 (2)
C(20)	0.040 (2)	0.026 (2)	0.029 (2)	0.000 (2)	0.009 (2)	0.006 (2)
C(21)	0.025 (2)	0.031 (2)	0.026 (2)	0.0000 (19)	0.0136 (19)	0.0095 (19)
C(22)	0.041 (2)	0.027 (2)	0.028 (2)	−0.001 (2)	0.018 (2)	0.004 (2)
C(23)	0.020 (2)	0.029 (2)	0.024 (2)	0.004 (2)	0.0074 (17)	0.003 (2)
C(24)	0.0205 (19)	0.009 (2)	0.0212 (19)	−0.0041 (16)	0.0022 (16)	−0.0047 (16)
C(25)	0.0212 (19)	0.021 (2)	0.023 (2)	−0.0004 (18)	0.0052 (16)	−0.0066 (19)
C(26)	0.026 (2)	0.026 (2)	0.030 (2)	0.0029 (19)	0.003 (2)	0.0026 (19)
C(27)	0.020 (2)	0.041 (2)	0.040 (2)	0.005 (2)	0.008 (2)	−0.005 (2)
C(28)	0.030 (2)	0.051 (3)	0.042 (2)	−0.004 (2)	0.019 (2)	−0.011 (2)
C(29)	0.039 (2)	0.072 (3)	0.029 (2)	−0.006 (2)	0.014 (2)	0.002 (2)
C(30)	0.025 (2)	0.058 (2)	0.024 (2)	−0.005 (2)	0.0050 (18)	0.003 (2)

Ag(1)—N(4)	2.208 (2)	C(17)—C(18)	1.365 (7)
Ag(1)—N(7)i	2.210 (3)	C(18)—C(19)	1.359 (5)
Ag(1)—N(10)ii	2.268 (2)	C(19)—C(20)	1.405 (8)
P(1)—F(1)	1.590 (3)	C(21)—C(22)	1.516 (5)
P(1)—F(2)	1.601 (3)	C(23)—C(24)	1.359 (5)
P(1)—F(3)	1.590 (2)	C(24)—C(25)	1.468 (6)
P(1)—F(4)	1.591 (2)	C(25)—C(26)	1.401 (4)
P(1)—F(5)	1.598 (2)	C(25)—C(30)	1.410 (5)
P(1)—F(6)	1.590 (2)	C(26)—C(27)	1.395 (7)
N(1)—C(1)	1.462 (4)	C(27)—C(28)	1.365 (6)
N(1)—C(11)	1.462 (4)	C(28)—C(29)	1.376 (5)
N(1)—C(21)	1.466 (4)	C(29)—C(30)	1.385 (7)
N(2)—N(3)	1.327 (4)	C(1)—H(1)	0.950
N(2)—C(2)	1.489 (6)	C(1)—H(2)	0.950
N(2)—C(3)	1.336 (6)	C(2)—H(3)	0.950
N(3)—N(4)	1.327 (5)	C(2)—H(4)	0.950
N(4)—C(4)	1.372 (5)	C(3)—H(5)	0.950
N(5)—N(6)	1.338 (4)	C(6)—H(6)	0.950
N(5)—C(12)	1.463 (6)	C(7)—H(7)	0.950
N(5)—C(13)	1.337 (6)	C(8)—H(8)	0.950
N(6)—N(7)	1.314 (6)	C(9)—H(9)	0.950
N(7)—C(14)	1.370 (4)	C(10)—H(10)	0.950
N(8)—N(9)	1.339 (3)	C(11)—H(11)	0.950
N(8)—C(22)	1.466 (5)	C(11)—H(12)	0.950
N(8)—C(23)	1.350 (5)	C(12)—H(13)	0.950
N(9)—N(10)	1.349 (5)	C(12)—H(14)	0.950
N(10)—C(24)	1.372 (3)	C(13)—H(15)	0.950
C(1)—C(2)	1.501 (5)	C(16)—H(16)	0.950
C(3)—C(4)	1.375 (6)	C(17)—H(17)	0.950
C(4)—C(5)	1.460 (6)	C(18)—H(18)	0.950
C(5)—C(6)	1.402 (6)	C(19)—H(19)	0.950
C(5)—C(10)	1.390 (5)	C(20)—H(20)	0.950
C(6)—C(7)	1.368 (7)	C(21)—H(21)	0.950
C(7)—C(8)	1.394 (6)	C(21)—H(22)	0.950
C(8)—C(9)	1.381 (6)	C(22)—H(23)	0.950
C(9)—C(10)	1.374 (7)	C(22)—H(24)	0.950
C(11)—C(12)	1.524 (5)	C(23)—H(25)	0.950
C(13)—C(14)	1.368 (6)	C(26)—H(26)	0.950
C(14)—C(15)	1.479 (7)	C(27)—H(27)	0.950
C(15)—C(16)	1.379 (5)	C(28)—H(28)	0.950
C(15)—C(20)	1.386 (6)	C(29)—H(29)	0.950
C(16)—C(17)	1.404 (8)	C(30)—H(30)	0.950
F(1)···N(3)iii	3.271 (4)	N(10)···H(20)ix	3.433
F(1)···N(9)iv	3.343 (3)	C(4)···H(10)vii	3.253
F(1)···C(9)v	3.427 (5)	C(7)···H(3)vii	3.513
F(1)···C(19)vi	3.477 (5)	C(8)···H(3)vii	2.863
F(2)···N(6)i	3.409 (5)	C(9)···H(3)vii	3.195
F(2)···C(7)	3.362 (5)	C(11)···H(1)xiii	3.550
F(2)···C(12)i	3.421 (5)	C(12)···H(19)ix	3.414
F(2)···C(27)	3.523 (4)	C(12)···H(20)ix	3.289
F(3)···C(7)	3.256 (6)	C(13)···H(20)ix	3.502
F(3)···C(8)	3.516 (5)	C(19)···H(13)ix	3.368
F(3)···C(21)iv	3.430 (4)	C(19)···H(14)ix	3.131
F(4)···C(9)v	3.498 (5)	C(20)···H(13)ix	3.572
F(4)···C(21)iv	3.188 (4)	C(20)···H(14)ix	3.079
F(4)···C(22)iv	3.445 (4)	C(21)···H(28)viii	3.591
F(5)···C(1)iii	3.099 (4)	C(28)···H(21)iii	3.465
F(5)···C(2)iii	3.307 (5)	H(1)···F(5)viii	2.901
F(5)···C(8)v	3.316 (5)	H(1)···F(6)viii	3.440
F(5)···C(9)v	3.484 (5)	H(1)···C(11)xiii	3.550
F(5)···C(11)i	3.345 (5)	H(1)···H(1)xiii	2.754
F(6)···C(1)iii	3.554 (4)	H(1)···H(11)xiii	3.006
F(6)···C(27)	3.533 (5)	H(1)···H(12)xiii	3.271
F(6)···C(28)	3.403 (4)	H(2)···P(1)viii	3.460
N(2)···C(9)vii	3.456 (4)	H(2)···F(1)viii	3.084
N(3)···F(1)viii	3.271 (4)	H(2)···F(5)viii	2.700
N(3)···C(9)vii	3.405 (4)	H(2)···F(6)viii	2.818
N(4)···C(10)vii	3.463 (4)	H(3)···F(5)viii	2.714
N(5)···C(20)ix	3.578 (4)	H(3)···C(7)vii	3.513
N(6)···F(2)x	3.409 (5)	H(3)···C(8)vii	2.863
N(9)···F(1)xi	3.343 (3)	H(3)···C(9)vii	3.195
C(1)···F(5)viii	3.099 (4)	H(3)···H(8)vii	2.744
C(1)···F(6)viii	3.554 (4)	H(3)···H(9)vii	3.303
C(2)···F(5)viii	3.307 (5)	H(3)···H(11)xiii	3.300
C(4)···C(10)vii	3.431 (5)	H(7)···P(1)	3.254
C(7)···F(2)	3.362 (5)	H(7)···F(2)	2.429
C(7)···F(3)	3.256 (6)	H(7)···F(3)	2.489
C(8)···F(3)	3.516 (5)	H(7)···F(6)	3.251
C(8)···F(5)xii	3.316 (5)	H(8)···F(3)	3.030
C(9)···F(1)xii	3.427 (5)	H(8)···F(4)xii	3.148
C(9)···F(4)xii	3.498 (5)	H(8)···F(5)xii	2.657
C(9)···F(5)xii	3.484 (5)	H(8)···H(3)vii	2.744
C(9)···N(2)vii	3.456 (4)	H(8)···H(11)iv	3.536
C(9)···N(3)vii	3.405 (4)	H(9)···P(1)xii	3.358
C(10)···N(4)vii	3.463 (4)	H(9)···F(1)xii	2.530
C(10)···C(4)vii	3.431 (5)	H(9)···F(4)xii	2.797
C(11)···F(5)x	3.345 (5)	H(9)···F(5)xii	2.990
C(12)···F(2)x	3.421 (5)	H(9)···N(2)vii	3.517
C(12)···C(20)ix	3.582 (5)	H(9)···N(3)vii	3.159
C(19)···F(1)vi	3.477 (5)	H(9)···N(4)vii	3.576
C(20)···N(5)ix	3.578 (4)	H(9)···H(3)vii	3.303
C(20)···C(12)ix	3.582 (5)	H(10)···Ag(1)vii	3.386
C(21)···F(3)xi	3.430 (4)	H(10)···N(3)vii	3.595
C(21)···F(4)xi	3.188 (4)	H(10)···N(4)vii	3.127
C(22)···F(4)xi	3.445 (4)	H(10)···C(4)vii	3.253
C(27)···F(2)	3.523 (4)	H(11)···F(3)xi	3.437
C(27)···F(6)	3.533 (5)	H(11)···F(5)x	2.782
C(28)···F(6)	3.403 (4)	H(11)···H(1)xiii	3.006
Ag(1)···H(10)vii	3.386	H(11)···H(3)xiii	3.300
P(1)···H(2)iii	3.460	H(11)···H(8)xi	3.536
P(1)···H(7)	3.254	H(12)···F(2)x	3.320
P(1)···H(9)v	3.358	H(12)···F(5)x	3.221
P(1)···H(19)vi	3.519	H(12)···H(1)xiii	3.271
P(1)···H(22)iv	3.394	H(13)···F(2)x	2.682
P(1)···H(29)ii	3.564	H(13)···F(5)x	3.114
F(1)···H(2)iii	3.084	H(13)···C(19)ix	3.368
F(1)···H(9)v	2.530	H(13)···C(20)ix	3.572
F(1)···H(14)iv	3.340	H(13)···H(19)ix	3.198
F(1)···H(19)vi	2.694	H(13)···H(20)ix	3.530
F(1)···H(20)vi	3.451	H(14)···F(1)xi	3.340
F(1)···H(22)iv	2.857	H(14)···F(3)xi	3.267
F(2)···H(7)	2.429	H(14)···C(19)ix	3.131
F(2)···H(12)i	3.320	H(14)···C(20)ix	3.079
F(2)···H(13)i	2.682	H(14)···H(19)ix	2.783
F(2)···H(27)	2.595	H(14)···H(20)ix	2.670
F(2)···H(29)ii	2.700	H(18)···H(18)vi	3.360
F(3)···H(7)	2.489	H(19)···P(1)vi	3.519
F(3)···H(8)	3.030	H(19)···F(1)vi	2.694
F(3)···H(11)iv	3.437	H(19)···F(3)vi	3.062
F(3)···H(14)iv	3.267	H(19)···F(6)vi	2.978
F(3)···H(19)vi	3.062	H(19)···C(12)ix	3.414
F(3)···H(21)iv	3.263	H(19)···H(13)ix	3.198
F(3)···H(22)iv	2.740	H(19)···H(14)ix	2.783
F(3)···H(29)ii	3.293	H(20)···F(1)vi	3.451
F(4)···H(8)v	3.148	H(20)···N(5)ix	3.234
F(4)···H(9)v	2.797	H(20)···N(9)ix	3.312
F(4)···H(21)iv	2.981	H(20)···N(10)ix	3.433
F(4)···H(22)iv	2.777	H(20)···C(12)ix	3.289
F(4)···H(23)iv	2.833	H(20)···C(13)ix	3.502
F(4)···H(29)ii	2.912	H(20)···H(13)ix	3.530
F(5)···H(1)iii	2.901	H(20)···H(14)ix	2.670
F(5)···H(2)iii	2.700	H(21)···F(3)xi	3.263
F(5)···H(3)iii	2.714	H(21)···F(4)xi	2.981
F(5)···H(8)v	2.657	H(21)···F(6)viii	3.582
F(5)···H(9)v	2.990	H(21)···C(28)viii	3.465
F(5)···H(11)i	2.782	H(21)···H(28)viii	2.664
F(5)···H(12)i	3.221	H(21)···H(29)viii	3.563
F(5)···H(13)i	3.114	H(22)···P(1)xi	3.394
F(6)···H(1)iii	3.440	H(22)···F(1)xi	2.857
F(6)···H(2)iii	2.818	H(22)···F(3)xi	2.740
F(6)···H(7)	3.251	H(22)···F(4)xi	2.777
F(6)···H(19)vi	2.978	H(23)···F(4)xi	2.833
F(6)···H(21)iii	3.582	H(24)···F(6)viii	3.374
F(6)···H(24)iii	3.374	H(27)···F(2)	2.595
F(6)···H(27)	2.977	H(27)···F(6)	2.977
F(6)···H(28)	2.703	H(28)···F(6)	2.703
N(2)···H(9)vii	3.517	H(28)···C(21)iii	3.591
N(3)···H(9)vii	3.159	H(28)···H(21)iii	2.664
N(3)···H(10)vii	3.595	H(29)···P(1)xiv	3.564
N(4)···H(9)vii	3.576	H(29)···F(2)xiv	2.700
N(4)···H(10)vii	3.127	H(29)···F(3)xiv	3.293
N(5)···H(20)ix	3.234	H(29)···F(4)xiv	2.912
N(6)···H(30)ix	2.825	H(29)···H(21)iii	3.563
N(7)···H(30)ix	3.136	H(30)···N(6)ix	2.825
N(9)···H(20)ix	3.312	H(30)···N(7)ix	3.136
N(4)—Ag(1)—N(7)i	132.43 (10)	C(23)—C(24)—C(25)	129.9 (2)
N(4)—Ag(1)—N(10)ii	114.02 (10)	C(24)—C(25)—C(26)	119.7 (3)
N(7)i—Ag(1)—N(10)ii	113.51 (10)	C(24)—C(25)—C(30)	122.2 (3)
F(1)—P(1)—F(2)	179.70 (15)	C(26)—C(25)—C(30)	118.1 (4)
F(1)—P(1)—F(3)	89.34 (18)	C(25)—C(26)—C(27)	120.3 (3)
F(1)—P(1)—F(4)	89.67 (14)	C(26)—C(27)—C(28)	120.3 (3)
F(1)—P(1)—F(5)	90.68 (16)	C(27)—C(28)—C(29)	120.6 (4)
F(1)—P(1)—F(6)	90.20 (15)	C(28)—C(29)—C(30)	120.4 (4)
F(2)—P(1)—F(3)	90.39 (17)	C(25)—C(30)—C(29)	120.2 (3)
F(2)—P(1)—F(4)	90.20 (15)	N(1)—C(1)—H(1)	108.9
F(2)—P(1)—F(5)	89.59 (15)	N(1)—C(1)—H(2)	107.9
F(2)—P(1)—F(6)	89.93 (14)	C(2)—C(1)—H(1)	109.2
F(3)—P(1)—F(4)	90.18 (14)	C(2)—C(1)—H(2)	107.1
F(3)—P(1)—F(5)	179.69 (15)	H(1)—C(1)—H(2)	109.5
F(3)—P(1)—F(6)	90.13 (15)	N(2)—C(2)—H(3)	109.0
F(4)—P(1)—F(5)	89.51 (13)	N(2)—C(2)—H(4)	109.0
F(4)—P(1)—F(6)	179.66 (16)	C(1)—C(2)—H(3)	109.2
F(5)—P(1)—F(6)	90.17 (14)	C(1)—C(2)—H(4)	108.3
C(1)—N(1)—C(11)	110.0 (3)	H(3)—C(2)—H(4)	109.5
C(1)—N(1)—C(21)	109.5 (3)	N(2)—C(3)—H(5)	127.7
C(11)—N(1)—C(21)	109.9 (2)	C(4)—C(3)—H(5)	126.8
N(3)—N(2)—C(2)	120.7 (3)	C(5)—C(6)—H(6)	119.2
N(3)—N(2)—C(3)	112.2 (3)	C(7)—C(6)—H(6)	119.4
C(2)—N(2)—C(3)	126.8 (3)	C(6)—C(7)—H(7)	120.3
N(2)—N(3)—N(4)	106.0 (3)	C(8)—C(7)—H(7)	119.7
Ag(1)—N(4)—N(3)	120.1 (2)	C(7)—C(8)—H(8)	120.1
Ag(1)—N(4)—C(4)	128.3 (2)	C(9)—C(8)—H(8)	120.4
N(3)—N(4)—C(4)	109.8 (3)	C(8)—C(9)—H(9)	119.5
N(6)—N(5)—C(12)	119.4 (3)	C(10)—C(9)—H(9)	120.5
N(6)—N(5)—C(13)	110.4 (3)	C(5)—C(10)—H(10)	118.8
C(12)—N(5)—C(13)	130.1 (3)	C(9)—C(10)—H(10)	119.5
N(5)—N(6)—N(7)	106.9 (3)	N(1)—C(11)—H(11)	109.2
Ag(1)x—N(7)—N(6)	118.6 (2)	N(1)—C(11)—H(12)	107.9
Ag(1)x—N(7)—C(14)	131.2 (3)	C(12)—C(11)—H(11)	108.6
N(6)—N(7)—C(14)	110.0 (3)	C(12)—C(11)—H(12)	108.0
N(9)—N(8)—C(22)	119.7 (3)	H(11)—C(11)—H(12)	109.5
N(9)—N(8)—C(23)	111.0 (3)	N(5)—C(12)—H(13)	108.4
C(22)—N(8)—C(23)	129.3 (2)	N(5)—C(12)—H(14)	108.7
N(8)—N(9)—N(10)	106.6 (2)	C(11)—C(12)—H(13)	108.8
Ag(1)xiv—N(10)—N(9)	108.43 (17)	C(11)—C(12)—H(14)	108.2
Ag(1)xiv—N(10)—C(24)	142.8 (2)	H(13)—C(12)—H(14)	109.5
N(9)—N(10)—C(24)	108.4 (2)	N(5)—C(13)—H(15)	126.8
N(1)—C(1)—C(2)	114.2 (3)	C(14)—C(13)—H(15)	126.5
N(2)—C(2)—C(1)	111.9 (3)	C(15)—C(16)—H(16)	119.6
N(2)—C(3)—C(4)	105.5 (3)	C(17)—C(16)—H(16)	120.2
N(4)—C(4)—C(3)	106.4 (4)	C(16)—C(17)—H(17)	120.0
N(4)—C(4)—C(5)	123.0 (3)	C(18)—C(17)—H(17)	120.1
C(3)—C(4)—C(5)	130.5 (3)	C(17)—C(18)—H(18)	119.8
C(4)—C(5)—C(6)	122.2 (3)	C(19)—C(18)—H(18)	119.5
C(4)—C(5)—C(10)	120.4 (3)	C(18)—C(19)—H(19)	120.1
C(6)—C(5)—C(10)	117.3 (4)	C(20)—C(19)—H(19)	119.9
C(5)—C(6)—C(7)	121.4 (4)	C(15)—C(20)—H(20)	119.7
C(6)—C(7)—C(8)	120.0 (4)	C(19)—C(20)—H(20)	120.2
C(7)—C(8)—C(9)	119.5 (4)	N(1)—C(21)—H(21)	109.8
C(8)—C(9)—C(10)	120.0 (4)	N(1)—C(21)—H(22)	107.4
C(5)—C(10)—C(9)	121.7 (4)	C(22)—C(21)—H(21)	110.3
N(1)—C(11)—C(12)	113.5 (3)	C(22)—C(21)—H(22)	107.3
N(5)—C(12)—C(11)	113.2 (3)	H(21)—C(21)—H(22)	109.5
N(5)—C(13)—C(14)	106.7 (3)	N(8)—C(22)—H(23)	109.0
N(7)—C(14)—C(13)	106.0 (4)	N(8)—C(22)—H(24)	109.4
N(7)—C(14)—C(15)	122.4 (3)	C(21)—C(22)—H(23)	109.0
C(13)—C(14)—C(15)	131.6 (3)	C(21)—C(22)—H(24)	108.3
C(14)—C(15)—C(16)	119.7 (4)	H(23)—C(22)—H(24)	109.5
C(14)—C(15)—C(20)	121.2 (3)	N(8)—C(23)—H(25)	126.8
C(16)—C(15)—C(20)	119.0 (4)	C(24)—C(23)—H(25)	127.2
C(15)—C(16)—C(17)	120.2 (4)	C(25)—C(26)—H(26)	119.6
C(16)—C(17)—C(18)	119.9 (4)	C(27)—C(26)—H(26)	120.1
C(17)—C(18)—C(19)	120.7 (5)	C(26)—C(27)—H(27)	119.6
C(18)—C(19)—C(20)	120.0 (4)	C(28)—C(27)—H(27)	120.1
C(15)—C(20)—C(19)	120.1 (3)	C(27)—C(28)—H(28)	119.5
N(1)—C(21)—C(22)	112.4 (3)	C(29)—C(28)—H(28)	120.0
N(8)—C(22)—C(21)	111.5 (3)	C(28)—C(29)—H(29)	119.8
N(8)—C(23)—C(24)	106.1 (2)	C(30)—C(29)—H(29)	119.8
N(10)—C(24)—C(23)	107.9 (3)	C(25)—C(30)—H(30)	119.3
N(10)—C(24)—C(25)	122.2 (3)	C(29)—C(30)—H(30)	120.5
N(4)—Ag(1)—N(7)i—N(6)i	104.7 (2)	Ag(1)xiv—N(10)—C(24)—C(23)	−170.2 (3)
N(4)—Ag(1)—N(7)i—C(14)i	−68.5 (3)	Ag(1)xiv—N(10)—C(24)—C(25)	8.7 (5)
N(7)i—Ag(1)—N(4)—N(3)	96.6 (2)	N(9)—N(10)—C(24)—C(23)	1.4 (3)
N(7)i—Ag(1)—N(4)—C(4)	−100.5 (3)	N(9)—N(10)—C(24)—C(25)	−179.6 (3)
N(4)—Ag(1)—N(10)ii—N(9)ii	66.5 (2)	N(1)—C(1)—C(2)—N(2)	−70.9 (4)
N(4)—Ag(1)—N(10)ii—C(24)ii	−105.2 (3)	N(2)—C(3)—C(4)—N(4)	0.2 (3)
N(10)ii—Ag(1)—N(4)—N(3)	−80.8 (2)	N(2)—C(3)—C(4)—C(5)	−178.9 (3)
N(10)ii—Ag(1)—N(4)—C(4)	82.1 (3)	N(4)—C(4)—C(5)—C(6)	20.4 (5)
N(7)i—Ag(1)—N(10)ii—N(9)ii	−111.4 (2)	N(4)—C(4)—C(5)—C(10)	−161.5 (3)
N(7)i—Ag(1)—N(10)ii—C(24)ii	76.9 (4)	C(3)—C(4)—C(5)—C(6)	−160.5 (3)
N(10)ii—Ag(1)—N(7)i—N(6)i	−77.9 (2)	C(3)—C(4)—C(5)—C(10)	17.6 (5)
N(10)ii—Ag(1)—N(7)i—C(14)i	108.9 (3)	C(4)—C(5)—C(6)—C(7)	178.8 (3)
C(1)—N(1)—C(11)—C(12)	162.9 (3)	C(4)—C(5)—C(10)—C(9)	−178.0 (3)
C(11)—N(1)—C(1)—C(2)	−80.9 (4)	C(6)—C(5)—C(10)—C(9)	0.2 (4)
C(1)—N(1)—C(21)—C(22)	−79.6 (4)	C(10)—C(5)—C(6)—C(7)	0.6 (5)
C(21)—N(1)—C(1)—C(2)	158.2 (3)	C(5)—C(6)—C(7)—C(8)	−1.3 (5)
C(11)—N(1)—C(21)—C(22)	159.5 (3)	C(6)—C(7)—C(8)—C(9)	1.1 (5)
C(21)—N(1)—C(11)—C(12)	−76.5 (4)	C(7)—C(8)—C(9)—C(10)	−0.3 (5)
N(3)—N(2)—C(2)—C(1)	−39.0 (4)	C(8)—C(9)—C(10)—C(5)	−0.3 (5)
C(2)—N(2)—N(3)—N(4)	−173.8 (2)	N(1)—C(11)—C(12)—N(5)	−71.1 (4)
N(3)—N(2)—C(3)—C(4)	−0.4 (4)	N(5)—C(13)—C(14)—N(7)	−0.0 (3)
C(3)—N(2)—N(3)—N(4)	0.4 (3)	N(5)—C(13)—C(14)—C(15)	−179.0 (3)
C(2)—N(2)—C(3)—C(4)	173.3 (3)	N(7)—C(14)—C(15)—C(16)	157.3 (3)
C(3)—N(2)—C(2)—C(1)	147.8 (3)	N(7)—C(14)—C(15)—C(20)	−21.3 (5)
N(2)—N(3)—N(4)—Ag(1)	165.6 (2)	C(13)—C(14)—C(15)—C(16)	−23.9 (6)
N(2)—N(3)—N(4)—C(4)	−0.2 (3)	C(13)—C(14)—C(15)—C(20)	157.5 (4)
Ag(1)—N(4)—C(4)—C(3)	−164.4 (2)	C(14)—C(15)—C(16)—C(17)	−180.0 (3)
Ag(1)—N(4)—C(4)—C(5)	14.9 (4)	C(14)—C(15)—C(20)—C(19)	178.9 (3)
N(3)—N(4)—C(4)—C(3)	−0.0 (3)	C(16)—C(15)—C(20)—C(19)	0.2 (5)
N(3)—N(4)—C(4)—C(5)	179.2 (3)	C(20)—C(15)—C(16)—C(17)	−1.3 (6)
N(6)—N(5)—C(12)—C(11)	−117.3 (3)	C(15)—C(16)—C(17)—C(18)	2.1 (6)
C(12)—N(5)—N(6)—N(7)	−177.2 (2)	C(16)—C(17)—C(18)—C(19)	−1.7 (6)
N(6)—N(5)—C(13)—C(14)	−0.1 (3)	C(17)—C(18)—C(19)—C(20)	0.6 (6)
C(13)—N(5)—N(6)—N(7)	0.1 (3)	C(18)—C(19)—C(20)—C(15)	0.2 (5)
C(12)—N(5)—C(13)—C(14)	176.9 (3)	N(1)—C(21)—C(22)—N(8)	−63.9 (3)
C(13)—N(5)—C(12)—C(11)	66.0 (5)	N(8)—C(23)—C(24)—N(10)	−1.4 (4)
N(5)—N(6)—N(7)—Ag(1)x	−174.7 (2)	N(8)—C(23)—C(24)—C(25)	179.7 (3)
N(5)—N(6)—N(7)—C(14)	−0.1 (3)	N(10)—C(24)—C(25)—C(26)	−172.5 (3)
Ag(1)x—N(7)—C(14)—C(13)	173.7 (2)	N(10)—C(24)—C(25)—C(30)	9.1 (5)
Ag(1)x—N(7)—C(14)—C(15)	−7.2 (5)	C(23)—C(24)—C(25)—C(26)	6.2 (6)
N(6)—N(7)—C(14)—C(13)	0.1 (3)	C(23)—C(24)—C(25)—C(30)	−172.2 (4)
N(6)—N(7)—C(14)—C(15)	179.2 (3)	C(24)—C(25)—C(26)—C(27)	−176.0 (3)
N(9)—N(8)—C(22)—C(21)	−49.6 (4)	C(24)—C(25)—C(30)—C(29)	177.9 (4)
C(22)—N(8)—N(9)—N(10)	−178.8 (2)	C(26)—C(25)—C(30)—C(29)	−0.5 (6)
N(9)—N(8)—C(23)—C(24)	0.9 (4)	C(30)—C(25)—C(26)—C(27)	2.4 (5)
C(23)—N(8)—N(9)—N(10)	−0.0 (3)	C(25)—C(26)—C(27)—C(28)	−2.5 (6)
C(22)—N(8)—C(23)—C(24)	179.5 (3)	C(26)—C(27)—C(28)—C(29)	0.7 (6)
C(23)—N(8)—C(22)—C(21)	131.9 (3)	C(27)—C(28)—C(29)—C(30)	1.3 (7)
N(8)—N(9)—N(10)—Ag(1)xiv	173.8 (2)	C(28)—C(29)—C(30)—C(25)	−1.3 (7)
N(8)—N(9)—N(10)—C(24)	−0.9 (3)

Ag1—N4	2.208 (2)
Ag1—N7i	2.210 (3)
Ag1—N10ii	2.268 (2)

N4—Ag1—N7i	132.43 (10)
N4—Ag1—N10ii	114.02 (10)
N7i—Ag1—N10ii	113.51 (10)

Symmetry codes: (i) ; (ii) .