Diacetonitrile-[N,N'-bis-(3,4,5-trimethoxy-benzyl-idene)ethyl-enediamine]copper(I) perchlorate.

In the title compound, [Cu(C(2)H(3)N)(2)(C(22)H(28)N(2)O(6))]ClO(4), the Cu atom is coordinated by two N atoms from one bidentate Schiff base ligand and two N atoms from two acetonitrile groups. The Cu atom adopts a tetra-hedral geometry. The Cu-N(ligand) distances are 2.076 (3) and 2.089 (3) Å, and the Cu-N(acetonitrile) distances are 1.964 (4) and 1.975 (4) Å.

Related literature

For related literature, see: Amirnasr et al. (2006 ▶); Chowdhury et al. (2000 ▶); Dakin et al. (2000 ▶); Khalaji et al. (2007 ▶).

Experimental

Crystal data

[Cu(C2H3N)2(C22H28N2O6)]ClO4

M = 661.56

Triclinic,

a = 9.869 (2) Å

b = 11.903 (3) Å

c = 14.904 (3) Å

α = 80.537 (4)°

β = 71.677 (4)°

γ = 68.285 (4)°

V = 1541.9 (6) Å3

Z = 2

Mo Kα radiation

μ = 0.85 mm−1

T = 294 (2) K

0.24 × 0.22 × 0.18 mm

Data collection

Bruker SMART 1K CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.821, T max = 0.862

8034 measured reflections

5414 independent reflections

3408 reflections with I > 2σ(I)

R int = 0.025

Refinement

R[F 2 > 2σ(F 2)] = 0.050

wR(F 2) = 0.141

S = 1.01

5414 reflections

387 parameters

34 restraints

H-atom parameters constrained

Δρmax = 0.62 e Å−3

Δρmin = −0.37 e Å−3

Data collection: SMART (Bruker, 1997 ▶); cell refinement: SAINT (Bruker, 1997 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997 ▶); molecular graphics: SHELXTL (Bruker, 1997 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536807065919/bt2614sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807065919/bt2614Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu(C2H3N)2(C22H28N2O6)]ClO4	Z = 2
Mr = 661.56	F000 = 688
Triclinic, P1	Dx = 1.425 Mg m−3
a = 9.869 (2) Å	Mo Kα radiation λ = 0.71073 Å
b = 11.903 (3) Å	Cell parameters from 2161 reflections
c = 14.904 (3) Å	θ = 2.3–22.6º
α = 80.537 (4)º	µ = 0.85 mm−1
β = 71.677 (4)º	T = 294 (2) K
γ = 68.285 (4)º	Block, blue
V = 1541.9 (6) Å3	0.24 × 0.22 × 0.18 mm

Bruker SMART 1K CCD area-detector diffractometer	5414 independent reflections
Radiation source: fine-focus sealed tube	3408 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.025
T = 294(2) K	θmax = 25.0º
φ and ω scans	θmin = 1.4º
Absorption correction: multi-scan(SADABS; Sheldrick, 1996)	h = −11→9
Tmin = 0.821, Tmax = 0.862	k = −14→14
8034 measured reflections	l = −17→16

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.050	H-atom parameters constrained
wR(F2) = 0.141	w = 1/[σ2(Fo2) + (0.0591P)2 + 1.2218P] where P = (Fo2 + 2Fc2)/3
S = 1.01	(Δ/σ)max = 0.001
5414 reflections	Δρmax = 0.62 e Å−3
387 parameters	Δρmin = −0.37 e Å−3
34 restraints	Extinction correction: none
Primary atom site location: structure-invariant direct methods

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cu1	0.16626 (7)	0.63549 (5)	0.25396 (4)	0.0508 (2)
O1	0.3716 (4)	0.9169 (3)	0.3552 (2)	0.0588 (9)
O2	0.5608 (4)	0.8412 (3)	0.4633 (2)	0.0591 (9)
O3	0.7220 (4)	0.6058 (3)	0.4854 (2)	0.0602 (9)
O4	−0.3452 (4)	0.5705 (3)	0.0206 (2)	0.0612 (9)
O5	−0.4326 (3)	0.8102 (3)	0.0469 (2)	0.0612 (9)
O6	−0.3194 (4)	0.8895 (3)	0.1522 (2)	0.0575 (8)
N1	0.3752 (4)	0.5043 (3)	0.2585 (2)	0.0410 (8)
N2	0.1072 (4)	0.4906 (3)	0.2395 (2)	0.0419 (8)
N3	0.0368 (5)	0.7333 (4)	0.3633 (3)	0.0572 (10)
N4	0.1843 (5)	0.7587 (4)	0.1488 (3)	0.0563 (10)
C1	0.4243 (5)	0.7104 (4)	0.3181 (3)	0.0429 (10)
H1	0.3572	0.7356	0.2809	0.051*
C2	0.4436 (5)	0.7945 (4)	0.3627 (3)	0.0430 (10)
C3	0.5417 (5)	0.7562 (4)	0.4204 (3)	0.0454 (11)
C4	0.6249 (5)	0.6343 (4)	0.4300 (3)	0.0445 (11)
C5	0.6075 (5)	0.5508 (4)	0.3837 (3)	0.0413 (10)
H5	0.6643	0.4692	0.3890	0.050*
C6	0.5055 (4)	0.5889 (4)	0.3293 (3)	0.0390 (10)
C7	0.4868 (5)	0.4930 (4)	0.2891 (3)	0.0414 (10)
H7	0.5627	0.4175	0.2856	0.050*
C8	0.2938 (6)	0.9615 (4)	0.2841 (4)	0.0693 (15)
H8A	0.3606	0.9302	0.2245	0.104*
H8B	0.2611	1.0483	0.2792	0.104*
H8C	0.2070	0.9359	0.3006	0.104*
C9	0.4800 (7)	0.8526 (5)	0.5606 (3)	0.0781 (17)
H9A	0.3737	0.8725	0.5678	0.117*
H9B	0.4954	0.9156	0.5847	0.117*
H9C	0.5162	0.7774	0.5952	0.117*
C10	0.8171 (5)	0.4835 (5)	0.4891 (4)	0.0629 (14)
H10A	0.7560	0.4330	0.5154	0.094*
H10B	0.8822	0.4742	0.5280	0.094*
H10C	0.8778	0.4601	0.4263	0.094*
C11	0.3764 (5)	0.3933 (4)	0.2262 (3)	0.0454 (11)
H11A	0.4520	0.3231	0.2462	0.054*
H11B	0.4017	0.3972	0.1576	0.054*
C12	0.2208 (5)	0.3823 (4)	0.2684 (3)	0.0484 (11)
H12A	0.2186	0.3107	0.2466	0.058*
H12B	0.1979	0.3744	0.3368	0.058*
C13	0.0175 (5)	0.4718 (4)	0.2024 (3)	0.0438 (10)
H13	0.0289	0.3915	0.1986	0.053*
C14	−0.1009 (5)	0.5636 (4)	0.1656 (3)	0.0415 (10)
C15	−0.1659 (5)	0.5225 (4)	0.1129 (3)	0.0463 (11)
H15	−0.1354	0.4401	0.1048	0.056*
C16	−0.2752 (5)	0.6037 (4)	0.0728 (3)	0.0459 (11)
C17	−0.3221 (5)	0.7267 (4)	0.0850 (3)	0.0472 (11)
C18	−0.2617 (5)	0.7676 (4)	0.1413 (3)	0.0439 (10)
C19	−0.1508 (5)	0.6868 (4)	0.1807 (3)	0.0437 (10)
H19	−0.1096	0.7144	0.2172	0.052*
C20	−0.3010 (6)	0.4441 (5)	0.0093 (4)	0.0627 (14)
H20A	−0.1954	0.4137	−0.0245	0.094*
H20B	−0.3603	0.4312	−0.0255	0.094*
H20C	−0.3174	0.4024	0.0705	0.094*
C21	−0.3830 (7)	0.8362 (5)	−0.0515 (4)	0.0844 (18)
H21A	−0.2835	0.8417	−0.0672	0.127*
H21B	−0.4521	0.9118	−0.0688	0.127*
H21C	−0.3797	0.7728	−0.0854	0.127*
C22	−0.2715 (6)	0.9347 (4)	0.2153 (4)	0.0640 (14)
H22A	−0.2970	0.8969	0.2774	0.096*
H22B	−0.3215	1.0207	0.2179	0.096*
H22C	−0.1636	0.9168	0.1932	0.096*
C23	0.1908 (6)	0.8331 (5)	0.0939 (4)	0.0683 (15)
C24	0.1990 (9)	0.9299 (7)	0.0201 (6)	0.140 (3)
H24A	0.1483	0.9267	−0.0244	0.211*
H24B	0.3034	0.9196	−0.0121	0.211*
H24C	0.1507	1.0069	0.0484	0.211*
C25	−0.0322 (6)	0.7962 (5)	0.4216 (4)	0.0623 (13)
C26	−0.1195 (9)	0.8770 (7)	0.4981 (5)	0.122 (3)
H26A	−0.0530	0.8831	0.5308	0.183*
H26B	−0.1941	0.8458	0.5415	0.183*
H26C	−0.1694	0.9558	0.4728	0.183*
Cl1	0.90012 (16)	0.16995 (12)	0.24864 (12)	0.0791 (5)
O7	0.7647 (5)	0.2159 (4)	0.2193 (4)	0.1252 (17)
O8	0.8825 (8)	0.2455 (5)	0.3203 (4)	0.171 (2)
O9	0.9177 (5)	0.0509 (3)	0.2878 (4)	0.1263 (18)
O10	1.0251 (6)	0.1770 (5)	0.1751 (4)	0.181 (3)

	U11	U22	U33	U12	U13	U23
Cu1	0.0576 (4)	0.0406 (3)	0.0556 (4)	−0.0112 (3)	−0.0229 (3)	−0.0059 (3)
O1	0.073 (2)	0.0404 (18)	0.062 (2)	−0.0110 (16)	−0.0250 (18)	−0.0062 (15)
O2	0.086 (2)	0.061 (2)	0.0467 (19)	−0.0406 (18)	−0.0180 (18)	−0.0074 (16)
O3	0.070 (2)	0.061 (2)	0.065 (2)	−0.0230 (18)	−0.0396 (19)	−0.0019 (17)
O4	0.060 (2)	0.067 (2)	0.069 (2)	−0.0138 (17)	−0.0355 (18)	−0.0186 (17)
O5	0.0487 (19)	0.072 (2)	0.053 (2)	−0.0032 (17)	−0.0211 (17)	−0.0051 (17)
O6	0.064 (2)	0.0464 (19)	0.062 (2)	−0.0118 (16)	−0.0244 (18)	−0.0060 (16)
N1	0.046 (2)	0.041 (2)	0.041 (2)	−0.0138 (16)	−0.0177 (17)	−0.0072 (16)
N2	0.046 (2)	0.040 (2)	0.045 (2)	−0.0157 (17)	−0.0179 (18)	−0.0002 (16)
N3	0.062 (3)	0.053 (2)	0.054 (3)	−0.012 (2)	−0.017 (2)	−0.009 (2)
N4	0.062 (3)	0.051 (2)	0.057 (3)	−0.019 (2)	−0.021 (2)	−0.001 (2)
C1	0.041 (2)	0.047 (3)	0.043 (3)	−0.016 (2)	−0.017 (2)	0.000 (2)
C2	0.044 (2)	0.039 (2)	0.043 (3)	−0.014 (2)	−0.007 (2)	−0.0030 (19)
C3	0.059 (3)	0.050 (3)	0.035 (2)	−0.030 (2)	−0.011 (2)	−0.002 (2)
C4	0.048 (3)	0.053 (3)	0.039 (2)	−0.024 (2)	−0.015 (2)	0.003 (2)
C5	0.040 (2)	0.039 (2)	0.046 (3)	−0.0119 (19)	−0.017 (2)	−0.0001 (19)
C6	0.037 (2)	0.043 (2)	0.036 (2)	−0.0124 (19)	−0.009 (2)	−0.0067 (19)
C7	0.040 (2)	0.037 (2)	0.045 (3)	−0.0072 (19)	−0.013 (2)	−0.0063 (19)
C8	0.078 (4)	0.043 (3)	0.079 (4)	−0.005 (3)	−0.034 (3)	0.005 (3)
C9	0.112 (5)	0.076 (4)	0.052 (3)	−0.038 (4)	−0.016 (3)	−0.018 (3)
C10	0.050 (3)	0.081 (4)	0.057 (3)	−0.013 (3)	−0.024 (3)	−0.005 (3)
C11	0.047 (3)	0.041 (2)	0.051 (3)	−0.010 (2)	−0.020 (2)	−0.010 (2)
C12	0.059 (3)	0.038 (2)	0.056 (3)	−0.014 (2)	−0.031 (2)	0.001 (2)
C13	0.047 (3)	0.041 (2)	0.049 (3)	−0.020 (2)	−0.015 (2)	−0.003 (2)
C14	0.039 (2)	0.046 (3)	0.042 (2)	−0.016 (2)	−0.012 (2)	−0.002 (2)
C15	0.042 (3)	0.051 (3)	0.050 (3)	−0.016 (2)	−0.014 (2)	−0.008 (2)
C16	0.040 (3)	0.062 (3)	0.039 (2)	−0.018 (2)	−0.011 (2)	−0.012 (2)
C17	0.040 (3)	0.059 (3)	0.038 (2)	−0.011 (2)	−0.010 (2)	−0.006 (2)
C18	0.042 (3)	0.046 (3)	0.040 (2)	−0.013 (2)	−0.006 (2)	−0.007 (2)
C19	0.046 (3)	0.050 (3)	0.040 (2)	−0.020 (2)	−0.011 (2)	−0.006 (2)
C20	0.066 (3)	0.073 (4)	0.063 (3)	−0.028 (3)	−0.026 (3)	−0.017 (3)
C21	0.091 (4)	0.086 (4)	0.054 (4)	−0.005 (3)	−0.024 (3)	0.006 (3)
C22	0.079 (4)	0.051 (3)	0.067 (3)	−0.023 (3)	−0.020 (3)	−0.011 (3)
C23	0.058 (3)	0.074 (4)	0.072 (4)	−0.026 (3)	−0.020 (3)	0.013 (3)
C24	0.127 (7)	0.140 (7)	0.138 (7)	−0.061 (6)	−0.040 (6)	0.082 (6)
C25	0.064 (3)	0.059 (3)	0.061 (3)	−0.015 (3)	−0.018 (3)	−0.008 (3)
C26	0.122 (6)	0.130 (6)	0.088 (5)	−0.010 (5)	−0.003 (4)	−0.061 (5)
Cl1	0.0556 (8)	0.0482 (8)	0.1228 (13)	−0.0165 (6)	−0.0139 (9)	0.0000 (8)
O7	0.096 (3)	0.092 (3)	0.170 (5)	−0.005 (3)	−0.056 (3)	0.015 (3)
O8	0.241 (6)	0.128 (4)	0.180 (5)	−0.090 (4)	−0.064 (5)	−0.029 (4)
O9	0.115 (4)	0.062 (3)	0.216 (5)	−0.036 (3)	−0.077 (4)	0.029 (3)
O10	0.120 (4)	0.152 (5)	0.209 (6)	−0.055 (4)	0.053 (4)	−0.015 (4)

Cu1—N3	1.964 (4)	C10—H10B	0.9600
Cu1—N4	1.975 (4)	C10—H10C	0.9600
Cu1—N2	2.076 (3)	C11—C12	1.511 (6)
Cu1—N1	2.089 (3)	C11—H11A	0.9700
O1—C2	1.367 (5)	C11—H11B	0.9700
O1—C8	1.422 (5)	C12—H12A	0.9700
O2—C3	1.377 (5)	C12—H12B	0.9700
O2—C9	1.420 (6)	C13—C14	1.456 (6)
O3—C4	1.372 (5)	C13—H13	0.9300
O3—C10	1.414 (6)	C14—C15	1.394 (6)
O4—C16	1.372 (5)	C14—C19	1.395 (6)
O4—C20	1.425 (5)	C15—C16	1.378 (6)
O5—C17	1.379 (5)	C15—H15	0.9300
O5—C21	1.413 (6)	C16—C17	1.386 (6)
O6—C18	1.366 (5)	C17—C18	1.400 (6)
O6—C22	1.426 (5)	C18—C19	1.382 (6)
N1—C7	1.274 (5)	C19—H19	0.9300
N1—C11	1.475 (5)	C20—H20A	0.9600
N2—C13	1.277 (5)	C20—H20B	0.9600
N2—C12	1.468 (5)	C20—H20C	0.9600
N3—C25	1.115 (6)	C21—H21A	0.9600
N4—C23	1.108 (6)	C21—H21B	0.9600
C1—C6	1.382 (6)	C21—H21C	0.9600
C1—C2	1.385 (6)	C22—H22A	0.9600
C1—H1	0.9300	C22—H22B	0.9600
C2—C3	1.398 (6)	C22—H22C	0.9600
C3—C4	1.387 (6)	C23—C24	1.463 (8)
C4—C5	1.385 (6)	C24—H24A	0.9600
C5—C6	1.390 (5)	C24—H24B	0.9600
C5—H5	0.9300	C24—H24C	0.9600
C6—C7	1.465 (5)	C25—C26	1.449 (8)
C7—H7	0.9300	C26—H26A	0.9600
C8—H8A	0.9600	C26—H26B	0.9600
C8—H8B	0.9600	C26—H26C	0.9600
C8—H8C	0.9600	Cl1—O10	1.387 (4)
C9—H9A	0.9600	Cl1—O9	1.410 (4)
C9—H9B	0.9600	Cl1—O7	1.422 (4)
C9—H9C	0.9600	Cl1—O8	1.436 (4)
C10—H10A	0.9600
N3—Cu1—N4	103.04 (16)	N2—C12—C11	109.3 (3)
N3—Cu1—N2	115.70 (15)	N2—C12—H12A	109.8
N4—Cu1—N2	120.15 (14)	C11—C12—H12A	109.8
N3—Cu1—N1	120.65 (14)	N2—C12—H12B	109.8
N4—Cu1—N1	112.89 (15)	C11—C12—H12B	109.8
N2—Cu1—N1	84.97 (13)	H12A—C12—H12B	108.3
C2—O1—C8	117.0 (3)	N2—C13—C14	126.6 (4)
C3—O2—C9	114.4 (4)	N2—C13—H13	116.7
C4—O3—C10	116.4 (3)	C14—C13—H13	116.7
C16—O4—C20	116.7 (4)	C15—C14—C19	119.9 (4)
C17—O5—C21	114.5 (4)	C15—C14—C13	116.3 (4)
C18—O6—C22	117.5 (4)	C19—C14—C13	123.8 (4)
C7—N1—C11	115.9 (3)	C16—C15—C14	120.1 (4)
C7—N1—Cu1	137.8 (3)	C16—C15—H15	119.9
C11—N1—Cu1	105.8 (2)	C14—C15—H15	119.9
C13—N2—C12	116.2 (3)	O4—C16—C15	123.6 (4)
C13—N2—Cu1	137.6 (3)	O4—C16—C17	115.9 (4)
C12—N2—Cu1	105.3 (2)	C15—C16—C17	120.4 (4)
C25—N3—Cu1	174.3 (4)	O5—C17—C16	121.9 (4)
C23—N4—Cu1	175.7 (4)	O5—C17—C18	118.5 (4)
C6—C1—C2	119.5 (4)	C16—C17—C18	119.5 (4)
C6—C1—H1	120.2	O6—C18—C19	124.5 (4)
C2—C1—H1	120.2	O6—C18—C17	115.2 (4)
O1—C2—C1	124.6 (4)	C19—C18—C17	120.3 (4)
O1—C2—C3	115.3 (4)	C18—C19—C14	119.7 (4)
C1—C2—C3	120.1 (4)	C18—C19—H19	120.2
O2—C3—C4	120.6 (4)	C14—C19—H19	120.2
O2—C3—C2	119.3 (4)	O4—C20—H20A	109.5
C4—C3—C2	120.0 (4)	O4—C20—H20B	109.5
O3—C4—C5	124.6 (4)	H20A—C20—H20B	109.5
O3—C4—C3	115.8 (4)	O4—C20—H20C	109.5
C5—C4—C3	119.6 (4)	H20A—C20—H20C	109.5
C4—C5—C6	120.2 (4)	H20B—C20—H20C	109.5
C4—C5—H5	119.9	O5—C21—H21A	109.5
C6—C5—H5	119.9	O5—C21—H21B	109.5
C1—C6—C5	120.5 (4)	H21A—C21—H21B	109.5
C1—C6—C7	123.4 (4)	O5—C21—H21C	109.5
C5—C6—C7	116.0 (4)	H21A—C21—H21C	109.5
N1—C7—C6	125.5 (4)	H21B—C21—H21C	109.5
N1—C7—H7	117.2	O6—C22—H22A	109.5
C6—C7—H7	117.2	O6—C22—H22B	109.5
O1—C8—H8A	109.5	H22A—C22—H22B	109.5
O1—C8—H8B	109.5	O6—C22—H22C	109.5
H8A—C8—H8B	109.5	H22A—C22—H22C	109.5
O1—C8—H8C	109.5	H22B—C22—H22C	109.5
H8A—C8—H8C	109.5	N4—C23—C24	178.9 (7)
H8B—C8—H8C	109.5	C23—C24—H24A	109.5
O2—C9—H9A	109.5	C23—C24—H24B	109.5
O2—C9—H9B	109.5	H24A—C24—H24B	109.5
H9A—C9—H9B	109.5	C23—C24—H24C	109.5
O2—C9—H9C	109.5	H24A—C24—H24C	109.5
H9A—C9—H9C	109.5	H24B—C24—H24C	109.5
H9B—C9—H9C	109.5	N3—C25—C26	178.9 (6)
O3—C10—H10A	109.5	C25—C26—H26A	109.5
O3—C10—H10B	109.5	C25—C26—H26B	109.5
H10A—C10—H10B	109.5	H26A—C26—H26B	109.5
O3—C10—H10C	109.5	C25—C26—H26C	109.5
H10A—C10—H10C	109.5	H26A—C26—H26C	109.5
H10B—C10—H10C	109.5	H26B—C26—H26C	109.5
N1—C11—C12	108.6 (3)	O10—Cl1—O9	112.7 (3)
N1—C11—H11A	110.0	O10—Cl1—O7	111.7 (4)
C12—C11—H11A	110.0	O9—Cl1—O7	108.6 (3)
N1—C11—H11B	110.0	O10—Cl1—O8	106.8 (4)
C12—C11—H11B	110.0	O9—Cl1—O8	109.3 (3)
H11A—C11—H11B	108.4	O7—Cl1—O8	107.5 (3)
N3—Cu1—N1—C7	−40.7 (5)	C4—C5—C6—C7	−175.5 (4)
N4—Cu1—N1—C7	81.7 (5)	C11—N1—C7—C6	−176.6 (4)
N2—Cu1—N1—C7	−157.7 (4)	Cu1—N1—C7—C6	−6.1 (7)
N3—Cu1—N1—C11	130.4 (3)	C1—C6—C7—N1	−16.5 (7)
N4—Cu1—N1—C11	−107.2 (3)	C5—C6—C7—N1	161.2 (4)
N2—Cu1—N1—C11	13.5 (3)	C7—N1—C11—C12	133.0 (4)
N3—Cu1—N2—C13	86.2 (5)	Cu1—N1—C11—C12	−40.4 (4)
N4—Cu1—N2—C13	−38.5 (5)	C13—N2—C12—C11	128.1 (4)
N1—Cu1—N2—C13	−152.1 (5)	Cu1—N2—C12—C11	−43.2 (4)
N3—Cu1—N2—C12	−105.5 (3)	N1—C11—C12—N2	58.1 (4)
N4—Cu1—N2—C12	129.8 (3)	C12—N2—C13—C14	−177.9 (4)
N1—Cu1—N2—C12	16.2 (3)	Cu1—N2—C13—C14	−10.5 (7)
N4—Cu1—N3—C25	−27 (4)	N2—C13—C14—C15	168.6 (4)
N2—Cu1—N3—C25	−160 (4)	N2—C13—C14—C19	−11.8 (7)
N1—Cu1—N3—C25	100 (4)	C19—C14—C15—C16	2.5 (6)
N3—Cu1—N4—C23	13 (6)	C13—C14—C15—C16	−177.9 (4)
N2—Cu1—N4—C23	143 (6)	C20—O4—C16—C15	0.7 (6)
N1—Cu1—N4—C23	−119 (6)	C20—O4—C16—C17	−178.5 (4)
C8—O1—C2—C1	−11.7 (6)	C14—C15—C16—O4	−179.6 (4)
C8—O1—C2—C3	168.5 (4)	C14—C15—C16—C17	−0.4 (7)
C6—C1—C2—O1	178.7 (4)	C21—O5—C17—C16	−76.3 (6)
C6—C1—C2—C3	−1.6 (6)	C21—O5—C17—C18	106.9 (5)
C9—O2—C3—C4	−81.4 (5)	O4—C16—C17—O5	0.1 (6)
C9—O2—C3—C2	102.2 (5)	C15—C16—C17—O5	−179.1 (4)
O1—C2—C3—O2	−1.0 (6)	O4—C16—C17—C18	176.9 (4)
C1—C2—C3—O2	179.2 (4)	C15—C16—C17—C18	−2.4 (7)
O1—C2—C3—C4	−177.5 (4)	C22—O6—C18—C19	−5.9 (6)
C1—C2—C3—C4	2.8 (6)	C22—O6—C18—C17	174.7 (4)
C10—O3—C4—C5	4.6 (6)	O5—C17—C18—O6	−0.6 (6)
C10—O3—C4—C3	−174.6 (4)	C16—C17—C18—O6	−177.4 (4)
O2—C3—C4—O3	1.4 (6)	O5—C17—C18—C19	180.0 (4)
C2—C3—C4—O3	177.8 (4)	C16—C17—C18—C19	3.2 (6)
O2—C3—C4—C5	−177.9 (4)	O6—C18—C19—C14	179.5 (4)
C2—C3—C4—C5	−1.4 (6)	C17—C18—C19—C14	−1.1 (6)
O3—C4—C5—C6	179.8 (4)	C15—C14—C19—C18	−1.7 (6)
C3—C4—C5—C6	−1.1 (6)	C13—C14—C19—C18	178.7 (4)
C2—C1—C6—C5	−0.9 (6)	Cu1—N4—C23—C24	−151 (34)
C2—C1—C6—C7	176.6 (4)	Cu1—N3—C25—C26	−87 (36)
C4—C5—C6—C1	2.3 (6)