Nanoporous PdNi Alloy Nanowires As Highly Active Catalysts for the Electro-Oxidation of Formic Acid.

Highly active and durable catalysts for formic acid oxidation are crucial to the development of direct formic acid fuel cell. In this letter, we report the synthesis, characterization, and electrochemical testing of nanoporous Pd(57)Ni(43) alloy nanowires for use as the electrocatalyst towards formic acid oxidation (FAO). These nanowires are prepared by chemically dealloying of Ni from Ni-rich PdNi alloy nanowires, and have high surface area. X-ray diffraction data show that the Pd(57)Ni(43) nanowires have the face-centered cubic crystalline structure of pure Pd, whereas X-ray photoelectron spectroscopy confirm the modification of electronic structure of Pd by electron transfer from Ni to Pd. Electrocatalytic activity of the nanowires towards FAO exceeds that of the state-of-the-art Pd/C. More importantly, the nanowires are highly resistant to deactivation. It is proposed that the high active surface area and modulated surface properties by Ni are responsible for the improvement of activity and durability. Dealloyed nanoporous Pd(57)Ni(43) alloy nanowires are thus proposed as a promising catalyst towards FAO.