| Literature DB >> 21190366 |
Iris Sancho-Sanz1, Delia Miguel, Alba Millán, Rosa E Estévez, Juan L Oller-López, Enrique Álvarez-Manzaneda, Rafael Robles, Juan M Cuerva, José Justicia.
Abstract
A mild, highly regio- and stereoselective method for the crotylation of aldehydes and ketones mediated/catalyzed by titanocene(III) is described. Optimized conditions permit the selective generation of γ-adducts in high yields together with high stereoselectivity, with a predominance of anti stereoisomers.Entities:
Year: 2010 PMID： 21190366 DOI： 10.1021/jo102269d
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354