Literature DB >> 21189018

Stabilization of the heavy methylene analogues, GeH2 and SnH2, within the coordination sphere of a transition metal.

S M Ibrahim Al-Rafia1, Adam C Malcolm, Sean K Liew, Michael J Ferguson, Eric Rivard.   

Abstract

The heavy group 14 methylene analogues, EH2, (E = Ge and Sn) have been stabilized via efficient methods, thus enabling the chemistry of these novel inorganic hydrides to be explored in depth.

Entities:  

Year:  2011        PMID： 21189018     DOI： 10.1021/ja1106223

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Changes in ligating abilities of the singlet and triplet states of normal, abnormal and remote N-heterocyclic carbenes depending on their aromaticities.

Authors:  Resul Sevinçek; Hande Karabıyık; Hasan Karabıyık
Journal:  J Mol Model       Date:  2013-10-25       Impact factor: 1.810

2.  An NHC-Stabilized H2 GeBH2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains.

Authors:  Matthias T Ackermann; Michael Seidl; Fuwei Wen; Michael J Ferguson; Alexey Y Timoshkin; Eric Rivard; Manfred Scheer
Journal:  Chemistry       Date:  2021-11-24       Impact factor: 5.020

3.  Hydridotetrylene [Ar*EH] (E = Ge, Sn, Pb) coordination at tantalum, tungsten, and zirconium.

Authors:  Max Widemann; Sebastian Jeggle; Maximilian Auer; Klaus Eichele; Hartmut Schubert; Christian P Sindlinger; Lars Wesemann
Journal:  Chem Sci       Date:  2022-02-22       Impact factor: 9.825

4.  Synthesis of Low-Valent Dinuclear Group 14 Compounds with Element-Element Bonds by Transylidation.

Authors:  Chandrajeet Mohapatra; Heidar Darmandeh; Henning Steinert; Bert Mallick; Kai-Stephan Feichtner; Viktoria H Gessner
Journal:  Chemistry       Date:  2020-10-19       Impact factor: 5.236
  4 in total

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