Literature DB >> 21183985

Gold catalyzes the Sonogashira coupling reaction without the requirement of palladium impurities.

Avelino Corma1, Raquel Juárez, Mercedes Boronat, Félix Sánchez, Marta Iglesias, Hermenegildo García.   

Abstract

By a combination of kinetic and theoretical studies it is concluded that gold is intrinsically active to perform the Sonogashira coupling reaction between phenylacetylene and iodobenzene. The presence of Pd impurities is not mandatory for catalyst activity.

Entities:  

Year:  2010        PMID： 21183985     DOI： 10.1039/c0cc04564k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles.

Authors:  Lichen Liu; Avelino Corma
Journal:  Chem Rev       Date:  2018-04-16       Impact factor: 60.622

2.  Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes.

Authors:  Dieter Weber; Michel R Gagné
Journal:  Chem Commun (Camb)       Date:  2011-03-31       Impact factor: 6.222

3.  A hexanuclear gold cluster supported by three-center-two-electron bonds and aurophilic interactions.

Authors:  Ekaterina S Smirnova; Antonio M Echavarren
Journal:  Angew Chem Int Ed Engl       Date:  2013-07-15       Impact factor: 15.336

4.  Supercritical water assisted preparation of recyclable gold nanoparticles and their catalytic utility in cross-coupling reactions under sustainable conditions.

Authors:  Abbasriyaludeen Abdul Raheem; Pitchai Thangasamy; Marappan Sathish; Chandrasekar Praveen
Journal:  Nanoscale Adv       Date:  2019-06-27

5.  Dual gold/photoredox-catalyzed C(sp)-H arylation of terminal alkynes with diazonium salts.

Authors:  Adrian Tlahuext-Aca; Matthew N Hopkinson; Basudev Sahoo; Frank Glorius
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

6.  Structural-functional analysis of engineered protein-nanoparticle assemblies using graphene microelectrodes.

Authors:  Jinglei Ping; Katherine W Pulsipher; Ramya Vishnubhotla; Jose A Villegas; Tacey L Hicks; Stephanie Honig; Jeffery G Saven; Ivan J Dmochowski; A T Charlie Johnson
Journal:  Chem Sci       Date:  2017-06-13       Impact factor: 9.825
  6 in total

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