Literature DB >> 21165465

Simultaneous self-assembly of a cage-like silver(I) complex encapsulating an Ag6 neutral cluster core and carbon dioxide fixation.

Di Sun1, Geng-Geng Luo, Na Zhang, Rong-Bin Huang, Lan-Sun Zheng.   

Abstract

A novel mixed-valent Ag(I)/Ag(0) T(h)-Ag(34) cage was obtained by a one-pot ultrasonic reaction. In the shell of the cage, CO(3)(2-) anion is derived from atmospheric CO(2) and adopts a rare μ(6) bridging mode to link the Ag(I) ions. In the core of the cage, an unprecedented neutral metal cluster with six zero-valent silver atoms is encapsulated.

Entities:  

Year:  2010        PMID： 21165465     DOI： 10.1039/c0cc04391e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Bis[μ(2)-bis-(diphenyl-phosphan-yl)methane-κP:P']bis-(μ(4)-diphenyl-phosphinato-κO:O:O':O')bis-[μ(2)-trifluoro-methane-sulfonato-(0.546/0.454)]-κO:O';κO:O-tetra-silver(I) acetonitrile disolvate.

Authors:  Li-Ping Tang; Chen Jia; Li-Li Huang; Jia-Li Xie
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-07-23

2.  Synthesis and Crystal Structure of the Bioinorganic Complex [Sb(Hedta)]·2H2O.

Authors:  Di Li; Guo-Qing Zhong
Journal:  Bioinorg Chem Appl       Date:  2014-02-13       Impact factor: 7.778

3.  Trapping an octahedral Ag6 kernel in a seven-fold symmetric Ag56 nanowheel.

Authors:  Zhi Wang; Hai-Feng Su; Mohamedally Kurmoo; Chen-Ho Tung; Di Sun; Lan-Sun Zheng
Journal:  Nat Commun       Date:  2018-05-29       Impact factor: 14.919

4.  Carboxylic acid stimulated silver shell isomerism in a triple core-shell Ag84 nanocluster.

Authors:  Zhi Wang; Hao-Tian Sun; Mohamedally Kurmoo; Qing-Yun Liu; Gui-Lin Zhuang; Quan-Qin Zhao; Xing-Po Wang; Chen-Ho Tung; Di Sun
Journal:  Chem Sci       Date:  2019-03-29       Impact factor: 9.825

5.  Unusual fcc-structured Ag10 kernels trapped in Ag70 nanoclusters.

Authors:  Yan-Min Su; Zhi Wang; Gui-Lin Zhuang; Quan-Qin Zhao; Xing-Po Wang; Chen-Ho Tung; Di Sun
Journal:  Chem Sci       Date:  2018-10-18       Impact factor: 9.825

6.  Adaptive coordination assemblies based on a flexible tetraazacyclododecane ligand for promoting carbon dioxide fixation.

Authors:  Shaochuan Li; Caiping Liu; Qihui Chen; Feilong Jiang; Daqiang Yuan; Qing-Fu Sun; Maochun Hong
Journal:  Chem Sci       Date:  2022-07-05       Impact factor: 9.969

7.  Metal-salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides under ambient conditions.

Authors:  Chee Koon Ng; Ren Wei Toh; Ting Ting Lin; He-Kuan Luo; T S Andy Hor; Jie Wu
Journal:  Chem Sci       Date:  2018-11-29       Impact factor: 9.825
  7 in total

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