Literature DB >> 21155573

Synthesis of enamides via CuI-catalyzed reductive acylation of ketoximes with NaHSO3.

Zheng-Hui Guan1, Zhi-Yuan Zhang, Zhi-Hui Ren, Yao-Yu Wang, Xumu Zhang.   

Abstract

CuI-catalyzed reductive acylation of ketoximes for preparation of enamides was reported. A broad scope of enamides was obtained in high yields with NaHSO(3) used as the terminal reductant.

Entities:  

Year:  2010        PMID： 21155573     DOI： 10.1021/jo1022348

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  1 in total

1.  Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates.

Authors:  Kevin D Hesp; Robert G Bergman; Jonathan A Ellman
Journal:  J Am Chem Soc       Date:  2011-07-08       Impact factor: 15.419
  1 in total

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