Literature DB >> 21155565

Radical cyclizations terminated by Ir-catalyzed hydrogen atom transfer.

Andreas Gansäuer1, Matthias Otte, Lei Shi.   

Abstract

A system for coupling catalytic radical cyclization and Ir-catalyzed hydrogen atom transfer (HAT) is described. It is essential that the HAT catalyst activates H(2) quickly and is not a hydrogenation catalyst. Vaska's complex was found to fulfill both purposes efficiently.

Entities:  

Year:  2010        PMID： 21155565     DOI： 10.1021/ja109362m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Nickel-catalyzed regiodivergent opening of epoxides with aryl halides: co-catalysis controls regioselectivity.

Authors:  Yang Zhao; Daniel J Weix
Journal:  J Am Chem Soc       Date:  2013-12-16       Impact factor: 15.419

2.  Enantioselective cross-coupling of meso-epoxides with aryl halides.

Authors:  Yang Zhao; Daniel J Weix
Journal:  J Am Chem Soc       Date:  2015-03-02       Impact factor: 15.419

3.  Catalytic Synthesis of 1H-2-Benzoxocins: Cobalt(III)-Carbene Radical Approach to 8-Membered Heterocyclic Enol Ethers.

Authors:  Minghui Zhou; Lukas A Wolzak; Zirui Li; Felix J de Zwart; Simon Mathew; Bas de Bruin
Journal:  J Am Chem Soc       Date:  2021-11-21       Impact factor: 15.419

4.  Titanocene(III)-Catalyzed Precision Deuteration of Epoxides.

Authors:  Dina Schwarz G Henriques; Elena Rojo-Wiechel; Sven Klare; Regine Mika; Sebastian Höthker; Jonathan H Schacht; Niklas Schmickler; Andreas Gansäuer
Journal:  Angew Chem Int Ed Engl       Date:  2021-12-21       Impact factor: 16.823

Review 5.  New advances in titanium-mediated free radical reactions.

Authors:  Bianca Rossi; Simona Prosperini; Nadia Pastori; Angelo Clerici; Carlo Punta
Journal:  Molecules       Date:  2012-12-11       Impact factor: 4.411
  5 in total

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