| Literature DB >> 21138315 |
Brent E Dial1, Roger D Rasberry, Brooke N Bullock, Mark D Smith, Perry J Pellechia, Salvatore Profeta, Ken D Shimizu.
Abstract
A molecular rotor was designed in which the rate of rotation is accelerated by guest complexation. The binding of an acetate guest to the urea groups lowers the barrier of the adjacent C(aryl)-N(imide) bond by 2 to 4 kcal/mol. This behavior is in contrast to most molecular rotors in which guest complexation slows rotation.Entities:
Year: 2010 PMID： 21138315 DOI： 10.1021/ol102659n
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005