Nanoparticle surface as activation site.

The immense surface-to-volume (S/V) ratio in nanoparticles leads to large surface energy density. These high densities play the role of sites for activities that are not triggered in bulk materials. Here we present some examples of such distinctive activities taking place at nanoparticle surfaces. Our first example involves the morphological changes in silkworm (Bombyx mori L.) nuclear polyhedrosis virus (BmNPV) brought about by lipophilic amorphous silica nanoparticles (LASN). Microscopy studies show that nanoparticles severely alter the structure of the virus envelope by a 'deflation' of the viral polyhedron and formation of elongated structures. The second example shows the spatial variation in aggregation potential with temperature, for dodecanethiol-capped Au nanoparticles on an amorphous polystyrene film surface. We find that on increasing the temperature from 32 degrees C to 50 degrees C the aggregating potential becomes almost completely confined to the film surface, whereas going over to 100 degrees C the confining potential is overcome and out-of-plane growth takes place. A tentative and qualitative explanation has been attempted.