Literature DB >> 21128629

1,1-carboboration of 1-alkynes: a conceptual alternative to the hydroboration reaction.

Chao Chen1, Tanja Voss, Roland Fröhlich, Gerald Kehr, Gerhard Erker.   

Abstract

Strongly electrophilic boranes R-B(C(6)F(5))(2) react readily with a variety of 1-alkynes by means of a 1,1-carboboration reaction to yield alkenylborane products, which can subsequently be used as reagents in metal catalyzed cross-coupling reactions.

Entities:  

Year:  2010        PMID： 21128629     DOI： 10.1021/ol102544x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

1.  Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications.

Authors:  Simon Krautwald; Máté J Bezdek; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2017-03-01       Impact factor: 15.419

2.  Borane-induced ring closure reaction of oligomethylene-linked bis-allenes.

Authors:  Xin Tao; Karel Škoch; Constantin G Daniliuc; Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2019-12-18       Impact factor: 9.825

3.  Reactions of biologically inspired hydride sources with B(C6F5)3.

Authors:  Lewis C Wilkins; Nicolò Santi; Louis Y P Luk; Rebecca L Melen
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

4.  Advanced 1,1-carboboration reactions with pentafluorophenylboranes.

Authors:  Gerald Kehr; Gerhard Erker
Journal:  Chem Sci       Date:  2015-10-08       Impact factor: 9.825

5.  Divergent Elementoboration: 1,3-Haloboration versus 1,1-Carboboration of Propargyl Esters.

Authors:  Lewis C Wilkins; Yashar Soltani; James R Lawson; Ben Slater; Rebecca L Melen
Journal:  Chemistry       Date:  2018-04-27       Impact factor: 5.236

6.  Piers' Borane-Induced Tetramerization of Arylacetylenes.

Authors:  Max Hasenbeck; Tizian Müller; Arthur Averdunk; Jonathan Becker; Urs Gellrich
Journal:  Chemistry       Date:  2021-12-28       Impact factor: 5.020

7.  1,2-Carboboration of Arylallenes by In Situ Generated Alkenylboranes for the Synthesis of 1,4-Dienes.

Authors:  Arthur Averdunk; Max Hasenbeck; Tizian Müller; Jonathan Becker; Urs Gellrich
Journal:  Chemistry       Date:  2022-04-21       Impact factor: 5.020

Review 8.  The Impact of Boron Hybridisation on Photocatalytic Processes.

Authors:  Alessandro Marotta; Callum E Adams; John J Molloy
Journal:  Angew Chem Int Ed Engl       Date:  2022-08-10       Impact factor: 16.823
  8 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.