Literature DB >> 21123878

Bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ(2)N(3),S']palladium(II).

M T H Tarafder1, M A A A A Islam, M B H Howlader, N Guidolin, E Zangrando.   

Abstract

In the title compound, [Pd(C(23)H(29)N(2)OS(2))(2)], the Pd(II) atom displays the expected square-planar coordination geometry. However, the trans configuration, which allows the Pd(II) atom to be located on a crystallographic inversion centre, is unusual with respect to the cis arrangement found in analogous Pd complexes comprising similar N,S-chelating ligands.

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Year:  2010        PMID: 21123878     DOI: 10.1107/S0108270110044008

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]palladium(II).

Authors:  M Sabina Begum; M Belayet Hossain Howlader; M Chanmiya Sheikh; Ryuta Miyatake; Ennio Zangrando
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-02-11
  1 in total

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