| Literature DB >> 21105729 |
Kazuo Tanaka1, Fumiyasu Ishiguro, Yoshiki Chujo.
Abstract
We report the synthesis of a stable room-temperature ionic liquid consisting of an octacarboxy polyhedral oligomeric silsesquioxane (POSS) anion and an imidazolium cation. The introduction of the POSS moiety enhances the thermal stability and reduces the melting temperature. From an evaluation of the thermodynamic parameters during the melting, it was found that the rigidity and cubic structure of POSS can contribute to the enhancement of these thermal properties.Entities:
Year: 2010 PMID: 21105729 DOI: 10.1021/ja105631j
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419