Literature DB >> 21103470

High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework.

Arpan Hazra1, Prakash Kanoo, Tapas Kumar Maji.   

Abstract

A bimetallic pillared-layer coordination framework {[Mn(3)(bipy)(3)(H(2)O)(4)][Cr(CN)(6)](2)·2(bipy)·4(H(2)O)}(n) has been constructed using a cyanometallate anion ([Cr(CN)(6)](3-)) and an organic linker (4,4'-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol(-1)) and shows guest dependent magnetic modulation.

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Year:  2010        PMID: 21103470     DOI: 10.1039/c0cc02490b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Diaqua-bis-(2-oxo-2H-chromene-3-carboxyl-ato-κO,O)manganese(II).

Authors:  Yue Cui; Qian Gao; Huan-Huan Wang; Lin Wang; Ya-Bo Xie
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-05-07
  1 in total

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