Literature DB >> 21090672

Ga(OTf)3-catalyzed direct substitution of alcohols with sulfur nucleophiles.

Xinping Han1, Jimmy Wu.   

Abstract

It is reported that Ga(OTf)(3) catalyzes the direct displacement of alcohols with sulfur nucleophiles. The products are versatile intermediates that can be utilized in carbon-carbon, carbon-sulfur bond formation or used in modified Julia olefination reactions. The only byproduct generated is water.

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Year:  2010        PMID： 21090672     DOI： 10.1021/ol102565b

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Selective synthesis of thioethers in the presence of a transition-metal-free solid Lewis acid.

Authors:  Federica Santoro; Matteo Mariani; Federica Zaccheria; Rinaldo Psaro; Nicoletta Ravasio
Journal:  Beilstein J Org Chem       Date:  2016-12-06       Impact factor: 2.883

2.  Lithium-Catalyzed Thiol Alkylation with Tertiary and Secondary Alcohols: Synthesis of 3-Sulfanyl-Oxetanes as Bioisosteres.

Authors:  Rosemary A Croft; James J Mousseau; Chulho Choi; James A Bull
Journal:  Chemistry       Date:  2017-12-20       Impact factor: 5.236

3.  Benzyl thioether formation merging copper catalysis.

Authors:  Bing Xu; Ying Lin; Yang Ye; Li Xu; Tian Xie; Xiang-Yang Ye
Journal:  RSC Adv       Date:  2021-12-23       Impact factor: 3.361

4.  B(C6F5)3 catalyzed direct nucleophilic substitution of benzylic alcohols: an effective method of constructing C-O, C-S and C-C bonds from benzylic alcohols.

Authors:  Shan-Shui Meng; Qian Wang; Gong-Bin Huang; Li-Rong Lin; Jun-Ling Zhao; Albert S C Chan
Journal:  RSC Adv       Date:  2018-09-03       Impact factor: 3.361
  4 in total

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