Literature DB >> 21053339

Fluorographene: a two-dimensional counterpart of Teflon.

Rahul R Nair1, Wencai Ren, Rashid Jalil, Ibtsam Riaz, Vasyl G Kravets, Liam Britnell, Peter Blake, Fredrik Schedin, Alexander S Mayorov, Shengjun Yuan, Mikhail I Katsnelson, Hui-Ming Cheng, Wlodek Strupinski, Lyubov G Bulusheva, Alexander V Okotrub, Irina V Grigorieva, Alexander N Grigorenko, Kostya S Novoselov, Andre K Geim.   

Abstract

A stoichiometric derivative of graphene with a fluorine atom attached to each carbon is reported. Raman, optical, structural, micromechanical, and transport studies show that the material is qualitatively different from the known graphene-based nonstoichiometric derivatives. Fluorographene is a high-quality insulator (resistivity >10(12) Ω) with an optical gap of 3 eV. It inherits the mechanical strength of graphene, exhibiting a Young's modulus of 100 N m(-1) and sustaining strains of 15%. Fluorographene is inert and stable up to 400 °C even in air, similar to Teflon.

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Year:  2010        PMID: 21053339     DOI: 10.1002/smll.201001555

Source DB:  PubMed          Journal:  Small        ISSN: 1613-6810            Impact factor:   13.281


  66 in total

1.  Odd-electron molecular theory of graphene hydrogenation.

Authors:  Elena F Sheka; Nadezhda A Popova
Journal:  J Mol Model       Date:  2012-03-07       Impact factor: 1.810

2.  Chemically homogeneous and thermally reversible oxidation of epitaxial graphene.

Authors:  Md Zakir Hossain; James E Johns; Kirk H Bevan; Hunter J Karmel; Yu Teng Liang; Shinya Yoshimoto; Kozo Mukai; Tatanori Koitaya; Jun Yoshinobu; Maki Kawai; Amanda M Lear; Larry L Kesmodel; Steven L Tait; Mark C Hersam
Journal:  Nat Chem       Date:  2012-02-19       Impact factor: 24.427

3.  It's still all about graphene.

Authors: 
Journal:  Nat Mater       Date:  2011-01       Impact factor: 43.841

4.  Van der Waals heterostructures.

Authors:  A K Geim; I V Grigorieva
Journal:  Nature       Date:  2013-07-25       Impact factor: 49.962

5.  A roadmap for graphene.

Authors:  K S Novoselov; V I Fal'ko; L Colombo; P R Gellert; M G Schwab; K Kim
Journal:  Nature       Date:  2012-10-11       Impact factor: 49.962

6.  Raman spectroscopy as a versatile tool for studying the properties of graphene.

Authors:  Andrea C Ferrari; Denis M Basko
Journal:  Nat Nanotechnol       Date:  2013-04       Impact factor: 39.213

7.  Tailoring the graphene/silicon carbide interface for monolithic wafer-scale electronics.

Authors:  S Hertel; D Waldmann; J Jobst; A Albert; M Albrecht; S Reshanov; A Schöner; M Krieger; H B Weber
Journal:  Nat Commun       Date:  2012-07-17       Impact factor: 14.919

Review 8.  Atomic covalent functionalization of graphene.

Authors:  James E Johns; Mark C Hersam
Journal:  Acc Chem Res       Date:  2012-10-02       Impact factor: 22.384

9.  Janus graphene from asymmetric two-dimensional chemistry.

Authors:  Liming Zhang; Jingwen Yu; Mingmei Yang; Qin Xie; Hailin Peng; Zhongfan Liu
Journal:  Nat Commun       Date:  2013       Impact factor: 14.919

10.  On the influence of point defects on the structural and electronic properties of graphene-like sheets: a molecular simulation study.

Authors:  Ernesto Chigo Anota; Alejandro Escobedo-Morales; Martin Salazar Villanueva; Odilon Vázquez-Cuchillo; Efrain Rubio Rosas
Journal:  J Mol Model       Date:  2012-10-14       Impact factor: 1.810

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