Literature DB >> 21047077

Planar quinary cluster inside a fullerene cage: synthesis and structural characterizations of Sc(3)NC@C(80)-I(h).

Tai-Shan Wang1, Lai Feng, Jing-Yi Wu, Wei Xu, Jun-Feng Xiang, Kai Tan, Yi-Han Ma, Jun-Peng Zheng, Li Jiang, Xin Lu, Chun-Ying Shu, Chun-Ru Wang.   

Abstract

The endohedral fullerene Sc(3)NC@C(80)-I(h) has been synthesized and characterized; it has an unprecedented planar quinary cluster in a fullerene cage. It is also the first chemical compound in which the presence of an unprecedented (NC)(3-) trianion has been disclosed. The fascinating intramolecular dynamics in Sc(3)NC@C(80)-I(h) enables the whole molecule to display high polarity and promising ferroelectricity. This finding inspires the possibility that such a planar quinary cluster may be useful in constructing many other endohedral fullerenes.

Entities:  

Year:  2010        PMID： 21047077     DOI： 10.1021/ja107843b

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

1.  Theoretical study on monometallic cyanide cluster fullerenes MCN@C74 (M=Y, Tb).

Authors:  Xu Gao; Li-Juan Zhao; Dong-Lai Wang
Journal:  J Mol Model       Date:  2015-10-30       Impact factor: 1.810

2.  Theoretical study on aluminum carbide endohedral fullerene-Al4C@C80.

Authors:  Qi Liang Lu; Wen Jun Song; Jun Wei Meng; Jian Guo Wan
Journal:  J Mol Model       Date:  2012-11-17       Impact factor: 1.810

3.  Self-driven carbon atom implantation into fullerene embedding metal-carbon cluster.

Authors:  Runnan Guan; Zuo-Chang Chen; Jing Huang; Han-Rui Tian; Jinpeng Xin; Si-Wei Ying; Muqing Chen; Qianyan Zhang; Qunxiang Li; Su-Yuan Xie; Lan-Sun Zheng; Shangfeng Yang
Journal:  Proc Natl Acad Sci U S A       Date:  2022-09-19       Impact factor: 12.779

4.  Sc3CH@C80: selective (13)C enrichment of the central carbon atom.

Authors:  Katrin Junghans; Marco Rosenkranz; Alexey A Popov
Journal:  Chem Commun (Camb)       Date:  2016-05-05       Impact factor: 6.222

5.  Triangular Monometallic Cyanide Cluster Entrapped in Carbon Cage with Geometry-Dependent Molecular Magnetism.

Authors:  Fupin Liu; Cong-Li Gao; Qingming Deng; Xianjun Zhu; Aram Kostanyan; Rasmus Westerström; Song Wang; Yuan-Zhi Tan; Jun Tao; Su-Yuan Xie; Alexey A Popov; Thomas Greber; Shangfeng Yang
Journal:  J Am Chem Soc       Date:  2016-10-31       Impact factor: 15.419

6.  Methane as a Selectivity Booster in the Arc-Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single-Molecule Magnet Dy2TiC@C80 and Its Congener Dy2TiC2@C80.

Authors:  Katrin Junghans; Christin Schlesier; Aram Kostanyan; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Sandra Schiemenz; Rasmus Westerström; Thomas Greber; Bernd Büchner; Alexey A Popov
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-09       Impact factor: 15.336

7.  Transformation of doped graphite into cluster-encapsulated fullerene cages.

Authors:  Marc Mulet-Gas; Laura Abella; Maira R Cerón; Edison Castro; Alan G Marshall; Antonio Rodríguez-Fortea; Luis Echegoyen; Josep M Poblet; Paul W Dunk
Journal:  Nat Commun       Date:  2017-10-31       Impact factor: 14.919

8.  Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy-Oxide Clusterfullerene Dy2O@C82.

Authors:  Wei Yang; Georgios Velkos; Fupin Liu; Svetlana M Sudarkova; Yaofeng Wang; Jiaxin Zhuang; Hanning Zhang; Xiang Li; Xingxing Zhang; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov; Ning Chen
Journal:  Adv Sci (Weinh)       Date:  2019-08-15       Impact factor: 16.806

9.  An improbable monometallic cluster entrapped in a popular fullerene cage: YCN@C(s)(6)-C82.

Authors:  Shangfeng Yang; Chuanbao Chen; Fupin Liu; Yunpeng Xie; Fengyu Li; Mingzhi Jiao; Mitsuaki Suzuki; Tao Wei; Song Wang; Zhongfang Chen; Xing Lu; Takeshi Akasaka
Journal:  Sci Rep       Date:  2013       Impact factor: 4.379

10.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236
  10 in total

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