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Literature DB >> 21038922

Chromatography in a single metal-organic framework (MOF) crystal.

Shuangbing Han¹, Yanhu Wei, Cory Valente, István Lagzi, Jeremiah J Gassensmith, Ali Coskun, J Fraser Stoddart, Bartosz A Grzybowski.

Abstract

Millimeter-sized single MOF-5 crystals are used as "chromatographic columns" to effectively separate mixtures of organic dyes. Remarkably, owing to the nanoscopic pore dimensions and the molecular-level interactions between the migrating molecules and the MOF scaffold, the separations occur over a distance of only a few hundred micrometers which is unambiguously confirmed by fluorescence confocal microscopy.

Entities: Chemical

Year: 2010 PMID： 21038922 DOI： 10.1021/ja1074322

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

11 in total

1. A carbon paste electrode modified with a metal-organic framework of type MIL-101(Fe) for voltammetric determination of citric acid.

Authors: Hamed Valizadeh; Javad Tashkhourian; Abdolkarim Abbaspour
Journal: Mikrochim Acta Date: 2019-06-18 Impact factor: 5.833

2. Ultrasensitive detection of toxic cations through changes in the tunnelling current across films of striped nanoparticles.

Authors: Eun Seon Cho; Jiwon Kim; Baudilio Tejerina; Thomas M Hermans; Hao Jiang; Hideyuki Nakanishi; Miao Yu; Alexander Z Patashinski; Sharon C Glotzer; Francesco Stellacci; Bartosz A Grzybowski
Journal: Nat Mater Date: 2012-09-09 Impact factor: 43.841

Review 3. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

Authors: Timothy R Cook; Yao-Rong Zheng; Peter J Stang
Journal: Chem Rev Date: 2012-11-02 Impact factor: 60.622

Chromatography in a single metal-organic framework (MOF) crystal.

1. A carbon paste electrode modified with a metal-organic framework of type MIL-101(Fe) for voltammetric determination of citric acid.

2. Ultrasensitive detection of toxic cations through changes in the tunnelling current across films of striped nanoparticles.

Review 3. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

4. Fluoroarene Separations in Metal-Organic Frameworks with Two Proximal Mg²⁺ Coordination Sites.

5. Tunable chiral metal organic frameworks toward visible light-driven asymmetric catalysis.

6. Precise Control of Molecular Self-Diffusion in Isoreticular and Multivariate Metal-Organic Frameworks.

Review 7. Beyond Frameworks: Structuring Reticular Materials across Nano-, Meso-, and Bulk Regimes.

8. Room temperature synthesis of a luminescent crystalline Cu-BTC coordination polymer and metal-organic framework.

9. Millimeter-Scale Zn(3-ptz)₂ Metal-Organic Framework Single Crystals: Self-Assembly Mechanism and Growth Kinetics.

10. Separation and liquid chromatography using a single carbon nanotube.