Literature DB >> 20981393

Iridium(III) molecular catalysts for water oxidation: the simpler the faster.

Arianna Savini1, Gianfranco Bellachioma, Gianluca Ciancaleoni, Cristiano Zuccaccia, Daniele Zuccaccia, Alceo Macchioni.   

Abstract

We report on three Ir(iii) molecular catalysts for water oxidation: 1, [Cp*Ir(ppy)Cl]; 2, [Cp*Ir(bzpy)NO(3)]; 3, [Cp*Ir(H(2)O)(3)](NO(3))(2). 2 and 3 are water-soluble and show a long-term activity ca. 2 and 3 times higher than 1. It is remarkable that 3, having the simplest structure, is the catalyst with the highest activity.

Entities:  

Year:  2010        PMID： 20981393     DOI： 10.1039/c0cc03801f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands.

Authors:  Jonathan Graeupner; Timothy P Brewster; James D Blakemore; Nathan D Schley; Julianne M Thomsen; Gary W Brudvig; Nilay Hazari; Robert H Crabtree
Journal:  Organometallics       Date:  2012-10-20       Impact factor: 3.876

2.  Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution.

Authors:  Jonathan Graeupner; Ulrich Hintermair; Daria L Huang; Julianne M Thomsen; Mike Takase; Jesús Campos; Sara M Hashmi; Menachem Elimelech; Gary W Brudvig; Robert H Crabtree
Journal:  Organometallics       Date:  2013-10-14       Impact factor: 3.876

3.  On the Homogeneity of a Cobalt-Based Water Oxidation Catalyst.

Authors:  Daan den Boer; Quentin Siberie; Maxime A Siegler; Thimo H Ferber; Dominik C Moritz; Jan P Hofmann; Dennis G H Hetterscheid
Journal:  ACS Catal       Date:  2022-04-04       Impact factor: 13.700

4.  Aromatic alkyne insertion into six-membered cyclometalated pyridine complexes of iridium: different insertion modes and structurally novel products.

Authors:  Xiaodan Chu; Shaowei Zhang; Zhuo Wang; Tongyu Li; Bolin Zhu
Journal:  RSC Adv       Date:  2018-02-14       Impact factor: 3.361

5.  Spectroelectrochemistry of Water Oxidation Kinetics in Molecular versus Heterogeneous Oxide Iridium Electrocatalysts.

Authors:  Carlota Bozal-Ginesta; Reshma R Rao; Camilo A Mesa; Yuanxing Wang; Yanyan Zhao; Gongfang Hu; Daniel Antón-García; Ifan E L Stephens; Erwin Reisner; Gary W Brudvig; Dunwei Wang; James R Durrant
Journal:  J Am Chem Soc       Date:  2022-05-05       Impact factor: 16.383

Review 6.  Ligands modification strategies for mononuclear water splitting catalysts.

Authors:  Lei Wang; Lijuan Wang
Journal:  Front Chem       Date:  2022-09-27       Impact factor: 5.545

Review 7.  Organoiridium complexes: anticancer agents and catalysts.

Authors:  Zhe Liu; Peter J Sadler
Journal:  Acc Chem Res       Date:  2014-02-20       Impact factor: 22.384

Review 8.  Charge migration and charge transfer in molecular systems.

Authors:  Hans Jakob Wörner; Christopher A Arrell; Natalie Banerji; Andrea Cannizzo; Majed Chergui; Akshaya K Das; Peter Hamm; Ursula Keller; Peter M Kraus; Elisa Liberatore; Pablo Lopez-Tarifa; Matteo Lucchini; Markus Meuwly; Chris Milne; Jacques-E Moser; Ursula Rothlisberger; Grigory Smolentsev; Joël Teuscher; Jeroen A van Bokhoven; Oliver Wenger
Journal:  Struct Dyn       Date:  2017-12-27       Impact factor: 2.920
  8 in total

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