| Literature DB >> 20979412 |
Chriss E McDonald1, Jeremy D Ramsey, David G Sampsell, Julie A Butler, Michael R Cecchini.
Abstract
The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of tripyrrolidinophosphoric acid triamide (TPPA) is presented. Kinetic studies indicate that the SmI(2)/TPPA complex possesses reactivity greater than the complex formed between samarium diiodide and 4 equiv of HMPA. Examples of the use of SmI(2)/TPPA in synthesis are presented.Entities:
Year: 2010 PMID： 20979412 DOI： 10.1021/ol102040s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005