Literature DB >> 20976330

Tandem isomerisation-metathesis catalytic processes of linear olefins in ionic liquid biphasic system.

Crestina S Consorti1, Guilherme L P Aydos, Jairton Dupont.   

Abstract

trans-3-Hexene is converted to heavier linear olefins by a tandem Ru-catalysed biphasic isomerisation/metathesis sequence. The difference in olefin metathesis and isomerisation rates is modulated by keeping the ionophilic metathesis catalyst in an ionic phase whilst the isomerisation catalyst is in another organic non-polar phase.

Entities:  

Year:  2010        PMID: 20976330     DOI: 10.1039/c0cc03891a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

Review 1.  Remote functionalization through alkene isomerization.

Authors:  Alexandre Vasseur; Jeffrey Bruffaerts; Ilan Marek
Journal:  Nat Chem       Date:  2016-03       Impact factor: 24.427

2.  One-pot isomerization-cross metathesis-reduction (ICMR) synthesis of lipophilic tetrapeptides.

Authors:  Mouhamad Jida; Cecilia Betti; Peter W Schiller; Dirk Tourwé; Steven Ballet
Journal:  ACS Comb Sci       Date:  2014-06-18       Impact factor: 3.784

Review 3.  Charge-tagged ligands: useful tools for immobilising complexes and detecting reaction species during catalysis.

Authors:  Jones Limberger; Bárbara C Leal; Adriano L Monteiro; Jairton Dupont
Journal:  Chem Sci       Date:  2014-08-06       Impact factor: 9.825

4.  Biofuel by isomerizing metathesis of rapeseed oil esters with (bio)ethylene for use in contemporary diesel engines.

Authors:  Kai F Pfister; Sabrina Baader; Mathias Baader; Silvia Berndt; Lukas J Goossen
Journal:  Sci Adv       Date:  2017-06-16       Impact factor: 14.136

5.  Ru-Catalyzed Estragole Isomerization under Homogeneous and Ionic Liquid Biphasic Conditions.

Authors:  Bárbara C Leal; Guilherme L P Aydos; Paulo A Netz; Jairton Dupont
Journal:  ACS Omega       Date:  2017-03-23
  5 in total

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