Literature DB >> 20963218

A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes.

Pierrick Nun1, Sylvain Gaillard, Albert Poater, Luigi Cavallo, Steven P Nolan.   

Abstract

Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(I) species generated in situ after reaction between [(IPr)AuOH] and HBF(4)·OEt(2). This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate.

Entities:  

Year:  2010        PMID： 20963218     DOI： 10.1039/c0ob00758g

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  4 in total

1.  Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity.

Authors:  Ruth Dorel; Antonio M Echavarren
Journal:  Chem Rev       Date:  2015-04-06       Impact factor: 60.622

2.  Versatile deprotonated NHC: C,N-bridged dinuclear iridium and rhodium complexes.

Authors:  Albert Poater
Journal:  Beilstein J Org Chem       Date:  2016-01-22       Impact factor: 2.883

3.  Mechanism of the Transmetalation of Organosilanes to Gold.

Authors:  Laura Falivene; David J Nelson; Stéphanie Dupuy; Steven P Nolan; Albert Poater; Luigi Cavallo
Journal:  ChemistryOpen       Date:  2015-09-10       Impact factor: 2.911

4.  Cascade Transformations of 1-R-Ethynyl-9,10-anthraquinones with Amidines: Expanding Access to Isoaporphinoid Alkaloids.

Authors:  Sergey Francevich Vasilevsky; Ol'ga Leonidovna Krivenko; Irina Vasilievna Sorokina; Dmitry Sergeevich Baev; Tatyana Genrikhovna Tolstikova; Igor V Alabugin
Journal:  Molecules       Date:  2021-11-15       Impact factor: 4.411
  4 in total

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