| Literature DB >> 20961049 |
Peter Dröse1, Cristian G Hrib, Frank T Edelmann.
Abstract
Carboranylamidinate anions are readily accessible via addition of N,N'-dialkylcarbodiimides to lithio-ortho-carborane. They represent a novel difunctional boron-rich ligand system for main group and transition elements (Li, Sn, Cr). Initial structural investigations revealed an unexpected N,C-coordination mode instead of N,N'-chelation.Entities:
Year: 2010 PMID： 20961049 DOI： 10.1021/ja108051u
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419