Literature DB >> 20959940

Magnesium hydride-promoted dearomatisation of pyridine.

Michael S Hill1, Dugald J MacDougall, Mary F Mahon.   

Abstract

Reaction of pyridine with well defined magnesium hydride species results in heterocycle dearomatisation by a hydride transfer which occurs with the formation of magnesium compounds containing 1,2- and 1,4-dihydropyridide anions as the respective kinetic and thermodynamic products.

Entities:  

Year:  2010        PMID： 20959940     DOI： 10.1039/c0dt01246g

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  3 in total

1.  Organocatalytic Synthesis of Methylene-Bridged N-Heterobiaryls.

Authors:  David E Stephens; Vu T Nguyen; Bhuwan Chhetri; Emily R Clark; Hadi D Arman; Oleg V Larionov
Journal:  Org Lett       Date:  2016-11-03       Impact factor: 6.005

Review 2.  s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

Authors:  Marc Magre; Marcin Szewczyk; Magnus Rueping
Journal:  Chem Rev       Date:  2022-03-07       Impact factor: 72.087

3.  Synthesis of a Hexameric Magnesium 4-pyridyl Complex with Cyclohexane-like Ring Structure via Reductive C-N Activation.

Authors:  Samuel R Lawrence; Matthew de Vere-Tucker; Alexandra M Z Slawin; Andreas Stasch
Journal:  Molecules       Date:  2021-11-28       Impact factor: 4.411
  3 in total

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