Literature DB >> 20957250

New insights into the acid mediated disproportionation of pentavalent uranyl.

Victor Mougel1, Biplab Biswas, Jacques Pécaut, Marinella Mazzanti.   

Abstract

The reaction of benzoic acid with the uranyl(V) complex [(UO(2)Py(5))(KI(2)Py(2))] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(IV) benzoate cluster, a bis-benzoate complex of uranyl(VI) and water.

Entities:  

Year:  2010        PMID： 20957250     DOI： 10.1039/c0cc03443f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier.

Authors:  Victor Mougel; Lucile Chatelain; Jacques Pécaut; Roberto Caciuffo; Eric Colineau; Jean-Christophe Griveau; Marinella Mazzanti
Journal:  Nat Chem       Date:  2012-11-11       Impact factor: 24.427

2.  The effect of iron binding on uranyl(v) stability.

Authors:  Radmila Faizova; Sarah White; Rosario Scopelliti; Marinella Mazzanti
Journal:  Chem Sci       Date:  2018-08-14       Impact factor: 9.825

3.  Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)2 followed by the formation of molecular poly-oxo cluster {U14} containing hemimellitate uranium(iv).

Authors:  Maxime Dufaye; Nicolas P Martin; Sylvain Duval; Christophe Volkringer; Atsushi Ikeda-Ohno; Thierry Loiseau
Journal:  RSC Adv       Date:  2019-07-23       Impact factor: 4.036

4.  Formation of a new type of uranium(iv) poly-oxo cluster {U38} based on a controlled release of water via esterification reaction.

Authors:  Nicolas P Martin; Christophe Volkringer; Natacha Henry; Xavier Trivelli; Grégory Stoclet; Atsushi Ikeda-Ohno; Thierry Loiseau
Journal:  Chem Sci       Date:  2018-05-09       Impact factor: 9.825
  4 in total

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