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Literature DB >> 20944852

Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation.

Kexuan Huang¹, Xiaowei Zhang, Thomas J Emge, Guohua Hou, Bonan Cao, Xumu Zhang.

Abstract

A novel three hindered quadrant bisphosphine ligand has been synthesized. The ligand shows excellent enantioselectivities and reactivities for rhodium-catalyzed hydrogenations of various functionalized olefins.

Entities: Chemical

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Year: 2010 PMID： 20944852 DOI： 10.1039/c0cc02620d

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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1 in total

1. Ferrocenyl chiral bisphosphorus ligands for highly enantioselective asymmetric hydrogenation via noncovalent ion pair interaction.

Authors: Caiyou Chen; Heng Wang; Zhefan Zhang; Shicheng Jin; Songwei Wen; Jianjian Ji; Lung Wa Chung; Xiu-Qin Dong; Xumu Zhang
Journal: Chem Sci Date: 2016-06-30 Impact factor: 9.825

1 in total