| Literature DB >> 20936813 |
Shuji Akai1, Ryosuke Hanada, Noboru Fujiwara, Yasuyuki Kita, Masahiro Egi.
Abstract
The combination of vanadium-oxo compounds (3 or 4) with a lipase produced the regio- and enantioconvergent transformation of racemic allyl alcohols (1 or 2) into optically active allyl esters. In this system, the vanadium compounds catalyzed the continuous racemization of the alcohols along with the transposition of the hydroxyl group, while the lipase effected the chemo- and enantioselective esterification to achieve the dynamic kinetic resolution.Entities:
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Year: 2010 PMID： 20936813 DOI： 10.1021/ol102053a
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005